Chemistry 5th semester paper 1st Notes.pdf

By:- Sumit Kumar yadav

101. Yadav_sumit
Vadav_surit
PageNo.
surmjt
Date
ieactushlithium metalatlanstemperdweinabyByo
Caubonynctonand.atbrdtocatkonatnitogenatmocphe
Vadasuit
ALouoT
R-X+iA
nlkylhalicle
Ftmcgpheta
>R-l+LIX
Ooganolithium
Lthium
blde
QByhalogenuection&schangemetal>Csgandithiumtht
epaepayedalaeettyAoiomlithiumgnalkylhal'de
Canbepapaedbyanatertnaye mettbodCaleal
eysut
haloqenatom methlGxchange oneNe0YSympli
metatom
R-X+Buli RLi+Bux )Butylhalide
Oganmetthiem
Vadav
Compouod
Theeqllbexiumisshifted toxghtdyectonitR
icSupejo4toPytlingtabiitynegatdechaiqedi-e
usu
qNenbelou9.
CeHScH=cHtchg-cHocHcHoxX
SodavsN
25/ it
cH-cO
Yad
su
stauctue> hizsimpleAlkyluteagentilthium
teagent
Axistmanilyashexamerinhyaocaxbonalo solutag
tnethe tetscimejcshuctuteayecuallyoominant
it
NdohexaneH
(RUiLcAgqacgade
ethex Hexanen
RL)A
Yadav
nit
Tetsame
Vadav_

102. Yadav_sumit
Vadav
sumit
Page No,
Date
Chemicatteaction>thium 12orgeelectapashie
4han
ada
magoisiumAheCutbonltbiurmbondimeonie
DdCouibon mognisumas4heiesult ogabahium
adavgit
Cempoundzaemceoeacthethangignaiduieaqent
Yadsu
sumit
Depaotention>eyllthiumdepootonetpactohatae
moxeaedthanbuten
Sumit
>RH4Buli R-LitBu-H
AIkane Btane
Vadav
sit
adavit
Anisole
Radav
rnit
adavit
Yaz
sumi
BuLi
FluLen2ene
+BuL
Bu
Buli
Ptridne
HucleophilicgdaltlonMeacinn
doAldyhydeandKeone
Egi=
HRt
tgut
R-c-R
Yadavit
Vadavmit
Nucleaphillc ueactionuoith
OL
H-¢-R
H30
H-cRtlioH)
RAteohot
C-R'LJoH
3plcoho
Vadavsur

103. Yadav_surnit
ReactHon>uoith
ormaldehydeuith
onstanodhium
Note>
sganolithiumaediartederlatanadRengent
Tmp
adav_su
Yadav_sumit
uchilecnatd
oieqqert aletonlghlyhided
Surmt
Caubons oanpound,thecgnoltbium eactthe
EiuchCompoundgivdngnmalatoduct
PageNo.
surait
Yat
sunit
g
Hcho Rli
H-c
Kedav
nit
>Noteact'on
Yadauit
Nadav
Notmalpoduct
clcobol
Yad
sumi
agu_su
Kdav
s
R
H-¢
Yay_su
Yadaurit
Vat
sumi
tLioH
alcchol
Yadav
mit
Yadasumit
Yadavnit

104. Yadav_sumit
deu_surm
Vadav
surmit
PageNo.
Date
Nucleopbilíc.substtHdlonuctonofsp3
Hbaidized
Qatkans
00u2uaitbthoSeCompound utoichhavenucleoebt
qoupa2Iingqtoup
adav
fonGxample>'cl,Ba,
OTg,OBa,00TE.
Vadav
it
HaC-cHsCHaOT2
Bu-li
Hac-CMgCia
+LioTS.
Hgc-cMaCHBr
Haot
Vodo
Yadaurit
LIBY
Reationuaith oxnange oxg (2memtaaneing)
OtyoqDeqiNetuoMeAction utth nganolithium
occuHattheesstha0endeed
becauz osggoolithiu behavaa2
poxldecotbon
Patsumit
>HeC-cHe-CH-oH
Vada
nit
p Heot
Kdav
su
H30
Yadanit
Trsans,paoduct
au
sumi
Yadavsmit
adaumit
Yadavt

105. Yadavsurmit
Unitd
pape-2 Vadav_sumit
PageNo.
Date
rdav
sumit,
Atatetuoocthexodyrmansczmustbeiotemal
aally
EullenialthkhajeSepatallyequlketumuthathned
detheymndymanic2 Syatem.
adav_sun
Vadasumit
Yadav
s
sdau_su
sumit
Lezconside3thenocymanic2 sydem, A,B,ccaptin
abox.)and BHesepaated bsyinculater ueilfondeding
uali2placedoeteen@ and®.Ttuanbeahzeel
Vada
xchangeo Hecttakegpiaeinbetbeen
and(8) Imen24hed andO hchuSKBeprcdalhy
intbemal equiLenumuoh al8ointhemal
equllbedurm.
Vads
OFisstlausodthemodnamic£
Acosdingtothi2lauohe
4o4adheatonetgyscqualtoSumotheiotesalene1gy
AotaluonnkthebytheSyotem
Ag=awtou
dedlst
du
alozkeddone notadhemocyminSytem.
fhstlau)othexmodyminaonsiquentangv
enertgy
Vadav
it
Dsecondlauothesmodypamic2>
Nadg
VadOHot heat>
tonsfey
-totd
entop
Yacy_suTheeAxlstusefullthamodnomiç2is entany
vodav
Vadav_sumi

106. Madav_sumit
Yadav
sumit
Date
Redav_s
Vadav
it
isoneequliber<jumstatesn
anotheull
gointheolnection
thatcouZegtho
Cotopy')thesystem
pu24heeinment
toinayoMe
oniooaiable
pastpossidbletovemalncoo2en1
eneeysiablepoce82.
unit
Reyesible(Sp'eS)
constant
Yadav
mit
IAHNeSibesps)
javwnit
3Thiadlou)o4hesmododmic2>
Endanpy a poucstali2(0)agtheleopetane
isolao
Daposach
hpituleoKauinoan
Sytem
Yadt
smit
Yath
suni
Yatsuit
TypesoSystenn
Opensystem>beseizgxchangetrooundipg.
Hecteneygyaguoellq2mete
2eSyster>Theyes xcbdnge onlkHeateneigyy
notmater
jsolatedsystomTheesofxchanage eneng siueg
mate
Dtadeodthemodymanic>
rnit
Olstateudction (au2ed) fosiaple,Tentea
eneiqPyetc
yesateftshiop
Dath functao>(AiotuBedl> foxxamplevoman
Hectenengy tc.
ay_suni
getuty.afesystern
DxtanisiyeAuopadey
Yadav
nit
matet erQrample
etc.
Yadav_su
TAl2dependGnquanhtNeO
mas,Nolume,capicl
adav
sumit

107. Vadav
sumit
DTodensjvepaopedy>Hdae2notdependonquantHe
roho2eHeat
adau
sumit
>ystemAeeenetgfoumoroundoa
Roxoda
IH
Aonmloddor
voltensiye
Date
SxtensiNe=iotersiedenlslty
Typesopioes>isothesemal
Hocess-Atcontaot)
Vaday
eusumit
JSocblonc=oa
Aolume
ev_sus
sur
Vats
sumit
Qadav
aav_sus
Yadav
it
adav
loy
adav_s
srit
Vadav
Yadavrit
Yadait
Vadav_su

108. Yadav_suit
adav
sumit
Uait-3 LAJdehyde andKetone
PageNo.
Date
Yadag
AlalehydecndKeloneLalhaecalledCatbonlecomound
becauzetheSamelceo)Tunciopguoup.
odovit
heygeneial moleculan onmula(cpHsg)dnel epxesen
asbelo.
Vactsumit
R-c-H
R--R
Yacts
sui
Bothayeunctionisomeeachcther
RHCpatation
Ftomalchloide>
(RosSouend
Redftion)
acn
surmit
pdBso4
Tncompe)
R-cttHo
poison Aldebyde
Kedav_s
cispalsan
Note>Tathi2uicoctonprsicialaweductonocwtbecauzei2uly
UHeduztionoccwttconetedintoalcoho,Dotco
Laldehyde,ie-pduzebaidm(PaSo4)a2
palgoDcaay
Reductisroacdchloaideohepecence
adav_suN
atpal!
pallidumsphete(pdseaSo4)toAldehydeia KnosngA
RosSmuned Heducion
Vadzgumit
pdBasD4 –Theceualyst
pauticaly
thedeactvated
an
poisonbytheaddiHonof1iHleoagancSulphe
quillne 4oqbanddarthesiedueio o aldehydeto
lav
it
alcahol
edav_su
Yatsumi
Macbanism>
quline
adavit
Sumit
Yadav
sit
Yadav_surmit

109. Vadav_sumib
adav
surmit
Rc-
Nadavqumit
Synadditlon
Vadav_sumit
RC
0
Podeusumb
HH
PageNo.
Dats)
sumi
-He
adav
surm
Acldchloaidcanbeal2odebyde
adaus
LthiunotoutwtyButalAlmuniumhydHged)
O=c-cl 0=C-H
Aldehde
C-c=0
Benzodidehyde
Yadav
it
edav
No2
p.nimchloobenzeldeh-yde
No2
Yadavit
adav
git
p-nitobenzyldeyde
Thizuegent1TB.AMedugezonlyccylehledeintoq
Aldehydetheye
iznoeffactNitoqiaup
Vadav
FHOm
nitale
Wadav
s
Hlcycyoidet>
Yadavit
Yacsumit
Vadav
qit
Vadasumit
at
su
Yadav
mit
Yadav_su

110. Yado
sumit
Yadavit
Woxk o
Fouia
Expanlon>
gdS FPXA
Yadav
n
OdlpYAXdl
IA-FXdL.
W=p-dp)XAxdl
Date
Jo
gusuri
pdy
Pasaysunit
sumi
Vat
sumi
Nadavit
Yadav
V
Yadarmit
Q R (foronemale
sun
Vadarrit
avsun
smit
Kadav
Yadav
mit
dodtdudNo.
dedu
vado
Rada
uit
Yadasumit
Vadav_su
edav
Yadav
sumit

111. Vadav_sumit
Yadav
surmit
PageNo.
Date
Yadrit
Heatcapity>The
dmDuntoHect
teauiaealto
incieae
e(T)ofthestengthiscalled
Heat
Capity
Vadav
davs
Fotgasous
substanceHect
Coupicity
aliÍdedia
OHeat
apicityatconstent-Nolume)
Vato
sumit
Heatcqpicityad2presse cp
OFLOmAstlau)themodymnicg
Yada
mit
toxconstant
lume,dp=0
YadsumitThenequen
becomeg
2du
4
putng
hetotumeoeetetetn
e
Hat
su
Noua.aqato
omTStlau)4heocknarmoe
4pdV
tdu enthap
Weko0u)thatH=
U+Pd
O-4FH'EdV+
pdat
constapte
Subcituting dolueat=
dH=dVpdv
etheDOdmanica
yadav
thenebemme cpdi
Yadav
s
dP
Yadav
sumi

112. Yadav_sumit
Vadav
sumit
Page No.
Date
elaionbetweonCpand >
aosumit
Cp-cV d
P
FuontbecyHuUctconstz)
Vadav.
dH=du+
d
puttinetheNolueeg-iney-9
Yads
sumit
dH clupdu
dTp LdTJpdr
Qdav_st
LetUT)
dingendeget
Yadav
rit
d
adavit
Modagumit
dT
Thi2eq-3)isaplcakle Solia iqdanol.gase:o
14
DPlecientiag uoHhotespeat Daconttestue
Vadav
Substanq Nalve
(5)equaloneq
Yadav_t
Yadav
sum

113. Vadav_sumit
Vadav
Srut
Vaday
surmit
|Date
puttiogheNalueo-equtioo(2in
adavs
Yad
sumit
cp-cv=d
dT
Vada
sumit
dT
Cp-c=
Yadav
mit
Yada
suyhit
pdu
_sum
Vadamit
Cp-cv=Pldu
dTp
attonetHeloc0
eau_su
Cp-cN=
cp-cV=R
Yados
suit
Vat
suni
Jilelelau)> ThizJausthiziachGrgeintenaenen
izchanae
odldeal
geisasthoAumeatconstntizto)
MathemaicoLdu=0
cv
es'zhamanefled>ThebaboieatheHeaqx2
usAL2.thoxtlqinestgatedby(T)ncolabalion
oith
byaiysng
basee2affosgeunNent(1852-1862).
hThad1et4oliscoveyothephenanmenon
12calec
Tule hamaneect hi2maybestatoo
fage2dndenhighert on2antates2eisalos
A
Yadt
sui
puee
it2
coolngefec
heomete
ligatd(Tempenalntan
Vadav
sunit

114. Vadavsumit
Padav
sumit
CHgt/A HcH
Date
edav_su
adav_su
Vadav
cmttCN
p
adav
Comand containing bctherlando
-ett
2-AdaitionoSodiumbisulphite
Vodagumit
yodotN
enahyduna
qu0up1
NaHSo2
Na
S0
Sog
Vadavt
Nadavt
yadau
HooNo
Vat
sumi
av_su
Ho-s
Vadav
sit
Vada
sumit
32AddiHonoaeohol> altahalqivezAddihionuaith
CbonleCompoundinthepaeserceo
Vadav
s
AddHlan Raoduc
taialyst.
actd42Ael
Yadoyau
nell
Yadav
sumit

115. Vadav
sumiy
Yadau_sumit
Vadav_sumit
PageNo.
Catelytnbybaze>Additlano
Date
doshit
loCalbohslCompoundaiebemicchal,hemicatal
malecuiczo4ctlohs
tyada
hemicatal
Padqu_surnit
Vatsumid
OH
yhdav
sit
Wedav_sut
Hemjdceta
Yadav
Vadavnit
adav
Yadai
Vadagumit
Yada)
RçoR
Yads
sumit
Catalysedbyacid
(rieaiketal)
Addittane
2melecale£o4an
dlcohol
e Acetal o Rate
vadt
RC-RtRo
R
1
-R
©-RKetal
HemiKetel
Yadav
sumit

116. odav_sumit
Yadav
sumit
PageNo.
Date
Va
Note>Acetalapd ketalCanbeyeccelll4 hydualced alao
QodkotoneuiespeclinallybyanaOu2ive,Gtgshoe
StableAouad2 baze2 PueHotb12
acelalaneketaleueuldu2etoxmolecin
adarunit
theCabonylguoupinmain teacton.
edav_sit
su
RCX
Retal
R-c-X+2RoH
bofoi ttootecletton
Base
edav
su
Aldal-cordensoton
Roacton gumit
hentoomoleculeof andldehydeOske-tone Conwic
Contan
e-hydogen Meoctuahbazeundemiletondition
ap hdioxyAdehyde(Aldal)zfOm1Scalled
Aldol–ondensaion
Reaction.
Yadav
RCH
suni
2cH2-H
Yada
adav
it
120
hydaxy
Ado
Camboraíon
Yadagumit
(aldol)
Wadav
Yadav
sumit

117. Vadav_sumit
wwhenacidisu2ecascataystlheoCSlding Aldolaet
dchydsadeAoqidUnsctaiaed oldehiyde.
aloss Aldol_ConzendensctÍonHegcton
Vadav_sumit
PageNo.
Date
Hadav_su
Vat
sumit
Yadagumit
Yodav
Vadowsqumit
Yadausnit
adavh
edav_su
eysum
Vad_su
edav_se
usun
asumi
Vadasurmit
Yad
sunit
Vadtosumit
Vadarmit
Vadav
it
edav_s
Qadav
edav

118. Yadau_
surnit
Yadav
surmit
PageNo.
Date
Radav
sumit
Yadt
sumit
Tbeotisorreiment>Incade
ioündexcHon
hecp
arpesunaent
uibe
stmpie ndea
acinpteEpeiment
opote2tluqDemend.
A8i21ongquibuti2
tringinsalalian
so
alingConclilan4hi.gubi2fraledauh
pictononhetoosteanpolc2pluq
pistargod
plug G)atcooslant(Phlethe
Vat
sumid
aponezplug
G)Theqa2(omingaata ie2plug
i)poshthepistontoQutlIOXd
bepse23oshthelef4sldeandkopConctanta2
Valuepoeeazthalnndheidhdsidehe
Vada
Rece Solsokeptathefoule Value(2
Pisto2
--p!andSxtesnduuokontheg2anthe*po
ThenetuoonkdonebyHhei
Yodav
Jalset
ButthepHoce2
PoNo-PN
Ba-ContaiNedidabalc
TheeIeouSnoErchange2oheatbetôeenaeu
au_su
at&xpeuanofntenna)eneng
thedeclec2e o
inteinoenesaya8falou
Yadav
nit
DE Ei-E
wheeE=denotintenalene1ce inhe(aidialstete
Vadav
En=12theiotesnal
enigyo4hefioialstate
ghot hedeuecAeinndeDaleng
muchbenetuTYdonehel
Yadav
su
Vadav_sumit

119. FoHomeqOand
PageNo.
Data
Hcu
tadak
QulHHo
Detuien Hepceetfalloe-euleethnonpuocE22isbeen
CaeuedputatConstant erdhalap
lug
lezthemon coeffichent->
po
REDMINOTE10SSUMITVADAV

120. Padav
su
Houeng:
ophooperiodism.affectslooxng.
Ophotoperioclismis&xpressedbytheiovolvenentol-ibbegcllic
Vadav_surmit
Voday
acdanthesin
Floigenisq-Hypothcltcalhoxmone
ploigentheourywaspotoposedbyahdickhycn
OHoigen syotheslzisioducedbyAH
PageNo.
Date
OFlaulernjngisaffecedby-DaytengthI Lighiintenslk
Sugit
Wioten plantaneanExampleo-shoxtdayplant
Langdayplantuitthanioterpupted
1ongdaylengthsho
Floeng
a
Yadosumit
adav
Kadav
nit
VadavNt
adav
git
Qadav_
s
edavssur
7av
mit,
Vadtosurit
Yadamit
adavit
Vadav
it
surmi
Vasumi
Vadavit

121. Yadav_sumit
Nadav
sui
Kedav_st
adavit
adav
it
Vadarit
Vadav
sumit
Date
PageNo.
Pooynit
Opayaminessimalaie Geiouthoiniaciplanl,Laiawiha
etted6xplanls.
Dpolyaminejs/aeDlamioo roanepubsescioe
Spenroidina
DAotbocyjanioSyolheszsbypolyamioes-patomoed.
hemainprecwso opolyarnioels-ou4nithine
QTpaoteaseinpolyaminesleuels- Tnbibit2ethyleneactiale
Dpolyomine oxidase,ciaoine oxidaseshelpio
polyamine biosynthesiz
DprpkioteonNesionsateaceleiateby
RedParHLHed
Aphyiochome molecalezhas- 2.Subunits
Kadav
it
DTheactivestateodphytochyomeis-pV
phychomecanbeisolaedby Iimmunocbemical
Radlommunoassayspecbnphotometu
XEach
monomemophytochomehas=onechiomaphme
Dithionite aHeducíogagent,indank
Accelealez pfxpxcooNeHSon
Seeddosman4 Yadasumit
Oceed
dujngdozmancyshou)=LauSTespiatHoo
Oandpamiasehelp
ineiosynthesiz oyshsach
TheisstsiePoygeminatoois-emetaenceplumuleoxd
Npidsoccuingloseedaesatonated uoshalealedfatoca
OThechelcomponent oseedlis
Canbohydrateg poecia
Lipld
zein(acomponeotomalzeseedis)
ARpotei
SDThePirnstStaqeo
qesmincHonis--Thetaekingo
doxman
uI)Lpidsioseeddre
sioncedin-nteHcellular oLLbodie
Yads
suri
Yada
sumit
Yadav
st
Vadav
sur

122. D\dine
ibod
ipid
PageNo.
Date
vioettn
ischeminlly
KnnonASEElaminopucineAcytokioiospoxomote ox,ganfocnataointicuecaltueoseed
cdosman
isausedby
todogcnous
ahscisicacid
Exogenous dbscicteacid
A
Absclsic acidUptakepacobyTen
medieledmembane
pcmeabitit
Abscsieacid
CauseSenesconce
nodabsíclanStonatal eosing
robibittona
secdlingandbud
gaoudih
AAbscisic
gcicdusasthstisalaledfouom-CaHonaalt
5Regulation stomatal closioglnvahtes–o
tions
OAbscisic acidcanteotoaplantushen3abectedfocoayskee
Inoedse.
Aelosynthesi2aybsciseacidoccunsfrcom
Mevalonic acid Catotenoidoxidaoo
Synthosl2Rsomalneadyexistng oreste.
OTobibitHonaysterm,utoctelongaionisshocaby
Auxia ethylene
aminoactdethoyvinglgycine
obibit2theenzymesAcSyothdse
oThepimaty precuSToethyleneis
Methionpine
DAudo:ethylenepoduchon
Tnduce
62)Auxinand_ethylenebothCause
TnhibitHao
oepicogloshypocotyls
(2CAM s scdegnsylmetbionine
44
AccSyntbasegteityinhibito shal
Inbibitethyleneproducton
REDMINOTE10S|SUMITYADAV

123. ete
Axins
oHedgeae
madeusingthepropesty
oyauxins
Apical
dominaoce
OThesideotheplant
facing
liqbt.
coniains
Loderjcoocentsaliaoauxins
DAxiais
syntbesizedio
shoolapex
QThepesence
oaUxinLoA.sPisstdemonstsaledby
chales
DatatiO
Conmeal,maltbuooe.
ArlashaebeeoisolatedPAoM
IDdole3dceticacid
OAA(uxin)isalsoKoounds
Auxinsajeaqaoup.oy
chemica2uohichaye
Sameinonigin
LGibbaelins
OGibbeella foikoiSa Funqi
OGbbeyellinsayeusedPo-preeotonoseneScence
Tnducden olnuoerngmobelisakonoffoodgmintnalin
Seeds
Dtibbellicacdshouasa
staucsqalsimlautyuith
StesoldhosmonesV
OTIlbou0abautAqpesodoiibbeellioghNebeenideotied.
OSenescenceCanbe
pseyentedby
DAnt
subbtnelliose-
eioacth
xeandant2
ae
rooutth
mseed
doxmancyCanbeeasily
bokenbythe
applicaianefCyiokinin.s
AD)
qtokinigaCause-cell
diisian
&xapansions
colyleit
andA
leaveg
Delayinsencescence Allo
thezeUSeof
yiokInins
fosSeed
gesnilpatenosabsttte
Red'
liqnttsectment
Cytokinins
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REDMINOTE10S|SUMIT_VADAV

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REDMINOTE10S|SUMIT_VADAV

125. Date
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REDMILNOTE10SSUMIT_YADAV

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REDMINOE'0SdisUMI VADAV

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REDMINOTE10S|SUMIT_VADAU

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