Co ordination compound.pptx chemistry coordination compound

chemistry

1. PAPER II

2. Aromaticity

3. Anti-aromaticity

4. Annulenes

5. Azulenes

6. Tropolones

7. Fulvenes

8. Sydnones

9. General methods (both kinetic and non-kinetic) of study of mechanisms or organic reactions

10. Isotopies

11. Mathod cross-over experiment

12. Intermediate trapping

13. Stereochemistry

14. Energy of activation

15. Thermodynamic control and kinetic control of reactions.

16. Generation

17. Geometry

18. Stability and reactions of carbonium ions and carbanions

19. Free radicals

20. Carbenes

21. Benzynes and nitrenes

22. SN 1, SN 2, and SN 1, mechanisms

23. Neighbouring groups participation

24. Electrophilic and nucleophilic reactions of aromatic compounds including heterocyclic compounds

25. Pyrrole

26. Furan

27. Thiophene and indole.

28. E1, E2 and E1cb mechanisms

29. Orientation in E2reactions— Saytzeff and Hoffmann

30. Pyrolytic syn elimination

31. Acetate pyrolysis

32. Chugaev and Cope eliminations.

33. Electrophilic addition to C=C and C=_C

34. Nucleophilic addition to C=O,C_=N

35. Conjugated olefins and carbonyls.

36. Pinacol-pinacolone rearrangement

37. Hoffmann rearrangement

38. Beckmann rearrangement

39. Baeyer- Villiger rearrangement

40. Favorskii rearrangement

41. Fries rearrangement

42. Claisen rearrangement

43. Cope rearrangement

44. Stevens and Wagner— Meerwein rearrangements.

45. Aldol condensation

46. Claisen condensation

47. Dieckmann reaction

48. Perkin

49. Knoevenagel

50. Witting

51. Clemmensen

52. Wolff- Kishner

53. Cannizzaro and von Richter reactions

54. Stobbe

55. Benzoin and acyloin condensations

56. Fischer indole synthesis

57. Skraup synthesis

58. Bischler-Napieralski

59. Sandmeyer

60. Reimer- Tiemann

61. Reformatsky reactions.

62. Classification and examples;

63. Woodward-Hoffmann rules

64. electrocyclic reactions

65. Cycloaddition reactions [2+2 and 4+2]

66. Sigmatropic shifts [1, 3; 3, 3 and 1, 5]

67. FMO approach.

68. Organic polymerspolyethylene ,

69. Polystyrene

70. Polyvinyl chloride

71. Teflon

72. Nylon

73. Terylene

74. Synthetic and natural rubber.

75. Structure of proteins

76. DNA

77. RNA.

78. OsO4,

79. HlO4

80. CrO3

81. Pb( OAc )4

82. SeO2

83. NBS

84. B2H6

85. Na-Liquid NH3

86. LiAIH4

87. NaBH4

88. N- BuLi ,

89. MCPBA.

90. Photochemical reactions of simple organic compounds,

91. Excited and ground states

92. Singlet and triplet states

93. Norrish-Type I

94. Norrish-Type II reactions.

95. Principle and applications in structure elucidation

96. Diatomic molecules;

97. Isotopic substitution

98. Rotational constants.

99. Diatomic molecules,

100. Linear triatomic molecules,

101. Specific frequencies of functional groups in polyatomic molecules.

102. Singlet and triplet states

103. N-transition

104. Application to conjugated double bonds

105. Application to conjugated carbonyl

106. Woodward- Fieser rules;

107. Charge transfer spectra.

108. Basic principle

109. Chemical shift

110. Spin-spin interaction

111. Coupling constants.

112. Parent peak

113. Base peak

114. Metastable peak

115. McLafferty rearrangement.