4
Atomic Model
Inthe18thand19thcenturies,manyscientistsattemptedto
explainthestructureoftheatomwiththehelpofatomicmodels.
Eachofthesemodelshadtheirownmeritsanddemeritsandwere
pivotaltothedevelopmentofthemodernatomicmodel.The
mostnotablecontributionstothefieldwerebythescientistsJohn
Dalton,J.J.Thomson,ErnestRutherford,NielsBohr&James
Chadwick.
Dalton’sAtomicTheory:
The idea of atomic theory was revived by John Dalton (1766-1844)
2,000 years after Democritus first proposed about it.
In1800,JohnDaltonperformedaseriesofexperimentsshowing
thematterconsistsoflumpyparticlescalled“atoms”.
His Findings led to the formulation of what is commonly known as
“Dalton’s Atomic Theory”.
DaltonformulatedhistheorybasedonAntoineLavoiser’s(1743-
1794)lawofconservationofmassandJosephProust’s(1754-
1826)lawofdefiniteproportion.
AccordingtothepostulatesproposedbyDalton,theatomic
structurecomprisedatoms,thesmallestparticleresponsiblefor
thechemicalreactionstooccur.
John Dalton
5
Dalton’s Atomic Model & Postulates
TheEnglishchemistJohnDaltonsuggestedthatallmatteris
madeupofatoms,whichwereindivisibleandindestructible.He
alsostatedthatalltheatomsofanelementwereexactlythe
same,buttheatomsofdifferentelementsdifferinsizeandmass.
The following are the postulates of his theory:
Every matter is made up of atoms.
Atoms are indivisible.
Specific elements have only one type of atoms in them.
Each atom has its own constant mass that varies from element to
element.
Atoms undergo rearrangement during a chemical reaction.
Atoms can neither be created nor be destroyed but can be
transformed from one form to another.
Dalton’satomictheorysuccessfullyexplainedtheLawsof
chemicalreactions,namely,theLawofconservationofmass,Law
ofconstantproperties,LawofmultipleproportionsandLawof
reciprocalproportions.
However,duringhistime,(1800s),somescientistsstilldidnot
believethattherewasanindivisibleatomfoundinallMatter.
7
Rutherford Atomic Model
Rutherford,astudentofJ.J.Thomsonmodifiedtheatomic
structurewiththediscoveryofanothersubatomicparticlecalled
“Nucleus”.Hisatomicmodelisbasedonthe“Alpharay
scatteringexperiment.”
ItwasErnestRutherford(1871-1937)whocoinedtheterm
“proton”forthepositivelychargedparticleinanatom
Rutherford’sStructureofAtom:
Basedontheexperimentandconclusions,Rutherfordproposed
hisownatomicstructurewhichisasfollows.
Thenucleusisatthecenterofanatom,wheremostofthecharge
andmassareconcentrated.
Atomicstructureisspherical.
Electronsrevolvearoundthenucleusinacircularorbit,similarto
thewayplanetsorbitthesun.
The electrons move around the nucleus, the protons found inside
the nucleus are positively charged.
The number of protons is equal to the number of electrons.
Later he postulated the existence of a neutral particle in the
nucleus to make up for, he calculated mass efficiency in the atom
studied.
Rutherford
8
NielsBohr & James Chadwick Model
NielsBohr’sPlanetaryModel
The electrons move around the nucleus in fixed orbit & electron in
a particular orbit has constant energy.
An electron can absorb energy and move to a higher energy orbit
of larger radius.
Anexcitedelectroncanfallbacktoitsoriginalorbitbyemitting
energyasradiation.
JamesChadwick’sModel
The“Neutron”wasdiscoveredbyJamesChadwickintheyear
1932.
Jamesatomicmodelisknownasthequantummechanical
modeloftheatom.In1932,JamesChadwickbombarded
berylliumatomswithalphaparticles.Anunknownradiationwas
produced.Chadwickinterpretedthisradiationasbeingcomposed
ofparticleswithaneutralelectricalchargeandtheapproximate
massofaproton.
Accordingtohim,thenucleusofanatomcontains
“Neutrons”,electricallyneutralparticleswithamasssimilartothat
ofproton.
Thecontinuedeffortsofthescientistsledtothediscoveryof
subatomicparticles.Thethreeprimarysubatomicparticlesthat
constituteanatomareElectron,Proton&Neutron.
NielsBohr
J.Chadwick