Mc murry coupling reaction

Mcmurry Coupling Reaction

1. Mc-Murry Coupling Reaction

2. Mc-Murry Coupling

3. Mechanism

4. Stereochemistry- Produces mixtures of ( E )- and ( Z )-isomers, with the ( E )-isomer predominating.

5. C oordination of the aryl groups to the titanium center occurs.

6. Applications:

7. References- http:// organicreactions.org/index.php?title=McMurry_coupling http:// www.scripps.edu/baran/images/grpmtgpdf/Young_Mar_09.pdf https:// www.sciencedirect.com/science/article/pii/S0040403900771851 Named organic reactions 2ed 2005 - Laue & Plagens