Reversible electrodes with respect to hydrogen ion

817 views 15 slides May 16, 2022
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About This Presentation

Reversible electrodes with respect to hydrogen ion..A reversible hydrogen electrode (RHE) is a
Reference electrode
......A reversible hydrogen electrode (RHE) is a reference electrode, more specifically a subtype of the standard hydrogen electrodes, for electrochemical processes. Unlike the standa...


Slide Content

Name: Mishuk Biswas Student electrode reversible with respect to h + ion

electrodes reversible with respect to h + ion R eversible hydrogen electrode Quinhydrone electrode Glass electrode Since  they act both anode as well as cathode , they are called reversible electrodes

reference electrode An electrode having an accurately maintained potential ; It is used as a reference for measurement by other electrodes. IDEAL REFERENCE ELECTRODE R eversible and obeys the Nernst equation Exhibits a potential that is constant with time Little hysteresis with temperature cycling

reversible hydrogen electrode A  reversible hydrogen electrode  ( RHE ) is a Reference electrode Since  it can act both anode as well as cathode , it is called a reversible electrode H + ( aq )+ ⇌ (g)  

standard hydrogen electrode Conditions Pressure : 1atm H + ion conc. : 1M Temperatur e: 25 o C Potential E = 0 volt .

r eversible hydrogen electrode 2H + ( aq )+ ⇌ (g)     Nerns t equation for this cell:

r eversible hydrogen electrode 2H + ( aq )+ ⇌ (g)    

design of a RHE

indicator electrode potential depends on the activity of ions being titrated or estimated used to sense the presence or change in concentration of the oxidized and reduced forms of a redox couple

GLASS ELECTRODE Glass electrodes are commonly used for pH measurements 2H + ( aq )+ ⇌ (g)   Nerns t equation for this cell:    

QUINHYDRONE ELECTRODE E o = 0.699 V Nerns t equation for this reaction can be written as  

QUINHYDRONE ELECTRODE Acidic Condition Quinhydrone – cathode Calomel – anode Acidic Condition Quinhydrone – anode Calomel – cathode

A pplication s RHE is the basic guide for the reporting of the potential of half-cells It is a type of gas electrode and has been commonly used as a reference electrode Glass electrodes are commonly used for  pH measurements Quinhydrone is used in potentiometric titration

acknowledgement https:// pubs.acs.org/doi/10.1021/acscatal.0c02046 https:// en.wikipedia.org/wiki/Reversible_hydrogen_electrode https://www.toppr.com/ask/en-bd/question/what-is-standard-hydrogen-electrode/ https ://www.researchgate.net/publication/307883774_Construction_of_a_Novel_Reversible_Hydrogen_Electrode_RHE Thank You

FAQ SLIDE 2H + ( aq )+ ⇌ (g)   O + ⇌ (g) +