Reversible electrodes with respect to hydrogen ion
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May 16, 2022
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About This Presentation
Reversible electrodes with respect to hydrogen ion..A reversible hydrogen electrode (RHE) is a
Reference electrode
......A reversible hydrogen electrode (RHE) is a reference electrode, more specifically a subtype of the standard hydrogen electrodes, for electrochemical processes. Unlike the standa...
Reversible electrodes with respect to hydrogen ion..A reversible hydrogen electrode (RHE) is a
Reference electrode
......A reversible hydrogen electrode (RHE) is a reference electrode, more specifically a subtype of the standard hydrogen electrodes, for electrochemical processes. Unlike the standard hydrogen electrode, its measured potential does change with the pH, so it can be directly used in the electrolyte.
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Added: May 16, 2022
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Slide Content
Name: Mishuk Biswas Student electrode reversible with respect to h + ion
electrodes reversible with respect to h + ion R eversible hydrogen electrode Quinhydrone electrode Glass electrode Since they act both anode as well as cathode , they are called reversible electrodes
reference electrode An electrode having an accurately maintained potential ; It is used as a reference for measurement by other electrodes. IDEAL REFERENCE ELECTRODE R eversible and obeys the Nernst equation Exhibits a potential that is constant with time Little hysteresis with temperature cycling
reversible hydrogen electrode A reversible hydrogen electrode ( RHE ) is a Reference electrode Since it can act both anode as well as cathode , it is called a reversible electrode H + ( aq )+ ⇌ (g)
standard hydrogen electrode Conditions Pressure : 1atm H + ion conc. : 1M Temperatur e: 25 o C Potential E = 0 volt .
r eversible hydrogen electrode 2H + ( aq )+ ⇌ (g) Nerns t equation for this cell:
r eversible hydrogen electrode 2H + ( aq )+ ⇌ (g)
design of a RHE
indicator electrode potential depends on the activity of ions being titrated or estimated used to sense the presence or change in concentration of the oxidized and reduced forms of a redox couple
GLASS ELECTRODE Glass electrodes are commonly used for pH measurements 2H + ( aq )+ ⇌ (g) Nerns t equation for this cell:
QUINHYDRONE ELECTRODE E o = 0.699 V Nerns t equation for this reaction can be written as
A pplication s RHE is the basic guide for the reporting of the potential of half-cells It is a type of gas electrode and has been commonly used as a reference electrode Glass electrodes are commonly used for pH measurements Quinhydrone is used in potentiometric titration
acknowledgement https:// pubs.acs.org/doi/10.1021/acscatal.0c02046 https:// en.wikipedia.org/wiki/Reversible_hydrogen_electrode https://www.toppr.com/ask/en-bd/question/what-is-standard-hydrogen-electrode/ https ://www.researchgate.net/publication/307883774_Construction_of_a_Novel_Reversible_Hydrogen_Electrode_RHE Thank You