19
6.4 Disadvantages
6.4.1 Lifespan
The biggest technical problem for OLEDs was the limited lifetime of the
organic materials. One 2008 technical report on an OLED TV panel found that
"After 1,000 hours the blue luminance degraded by 12%, the red by 7% and
the green by 8%."
[67]
In particular, blue OLEDs historically have had a
lifetime of around 14,000 hours to half original brightness (five years at 8
hours a day) when used for flat-panel displays. This is lower than the typical
lifetime of LCD, LED or PDP technology. Each currently is rated for about
25,000–40,000 hours to half brightness, depending on manufacturer and
model.
[68][69]
Degradation occurs because of the accumulation of nonradiative
recombination centers and luminescence quenchers in the emissive zone. It is
said that the chemical breakdown in the semiconductors occurs in four steps:
1) recombination of charge carriers through the absorption of UV light, 2)
hemolytic dissociation, 3) subsequent radical addition reactions that form π
radicals, and 4) disproportionation between two radicals resulting in hydrogen-
atom transfer reactions.
[70]
However, some manufacturers' displays aim to
increase the lifespan of OLED displays, pushing their expected life past that of
LCD displays by improving light outcoupling, thus achieving the same
brightness at a lower drive current.
[71][72]
In 2007, experimental OLEDs were
created which can sustain 400 cd/m
2
of luminance for over 198,000 hours for
green OLEDs and 62,000 hours for blue OLEDs.
[73]
6.4.2 Color balance
Additionally, as the OLED material used to produce blue light degrades
significantly more rapidly than the materials that produce other colors, blue
light output will decrease relative to the other colors of light. This variation in
the differential color output will change the color balance of the display and is
much more noticeable than a decrease in overall luminance.
[74]
This can be
avoided partially by adjusting color balance, but this may require advanced
control circuits and interaction with the user, which is unacceptable for some
users. More commonly, though, manufacturers optimize the size of the R, G
and B subpixels to reduce the current density through the subpixel in order to
equalize lifetime at full luminance. For example, a blue subpixel may be 100%