TOPIC NO.- 8 SOLID SOLUTION STRENGHENING NAME- PAREKH JAYESH M. ROLL NO. - 388
Why strengthening of metal is required? As pure metal are inherently weak due to presence of dislocation . So, We can enhance the mechanical properties by eliminating dislocation. So, by introducing some mechanism that prohibits the mobility of dislocations, that are called Strengthing mechanism. Methods F or Strengthening Of Metal Strain hardening Grain boundary strengthening Solid solution strengthening Precipitation hardening
Solid Solution When the atoms of base metal (solvent) and the alloying elements (solute) completely dissolve in each other and become an integral part of the solid phase of alloy, the resulting phase is called a Solid Solution. Types of Solid Solution: Interstitial solid solution Substitutional solid solution
Interstitial Solid Solution Solute atoms are much smaller than solvent atoms, so they occupy interstitial position in solvent lattice. Carbon ,nitrogen ,hydrogen ,oxygen and boron are the element which commonly form interstitial solid solution.
Substitutional Solid Solution Solute atoms sizes are roughly similar to solvent atoms. Due to similar size solute atoms occupy vacant site in solvent atoms. Copper and zinc, copper and nickel, are the example of substitutional solid solution .
Hume Rothery’s Rule Hume rothery studied a number of alloy systems and formulated condition that favour extensive substitutional solid solubility. Three conditions of Hume Rothery’s rule The size difference between solute and solvent atoms must be less than 15% The crystal structure of metal must be same. The electronegativity difference between the metal must be small. Strengthening Mechanisms Depends O n , Difference in size between solute and solvent atoms A mount of solute added, N ature of distortion produced by solute atoms.
How This Parameter Affect Strengthening Mechanisms. As the size difference between solute and solvent atoms increases , the intensity of stress field around solute atom increases and resistance to dislocation is increases, so strength of metal is also increases. A large concentration of solute atoms are added it means more frequent obstacles to dislocation. The strength increases in proportion of C ½, where c is a concentration of solute atoms. The nature of distortion produced by solute atoms are also important. Spherical distortion produced by Substituional solute atoms. Non spherical distortion produced by interstitial solute atoms . Non spherical distortion produced maximum effect i.e. it increases yield strength . .
Results of Solid Solution Strengthening
Effect of solute alloy additions on stress-strain curve