Agitaion and mixing

Agitaion and mixing

1. Agitation A nd Mixing

2. Agitation and Mixing Many operations depend upon effective agitation and mixing of components Agitation: induced motion of a material Mixing: random distribution of two initially separate phases A single homogeneous material such as water in a tank can be agitated but not mixed until another material is added to tank

3. Agitation and mixing agitation is a means whereby mixing of phases can be accomplished and by which mass and heat transfer can be enhanced between phases or with external surfaces Mixing is concerned with all combinations of phases of which the most frequently occurring ones are GASES WITH GASES GASES INTO LIQUIDS: DISPERSION. GASES WITH GRANULAR SOLIDS: FLUIDIZATION, PNEUMATIC CONVEYING; DRYING LIQUIDS INTO GASES: SPRAYING. LIQUIDS WITH LIQUIDS: DISSOLUTION, EMULSIFICATION, DISPERSION LIQUIDS WITH GRANULAR SOLIDS: SUSPENSION. PASTES WITH EACH OTHER AND WITH SOLIDS. SOLIDS WITH SOLIDS: MIXING OF POWDERS.

4. Agitation and Mixing interaction of gases, liquids, and solids also may take place Example: hydrogenation of liquids in the presence of a slurred solid catalyst where the gas must be dispersed as bubbles and the solid particles must be kept in suspension

5. Purpose of Agitation Suspending solid particles in a liquid Blending miscible liquids e.g. methanol-water Dispersing a gas through a liquid in the form of small bubbles Dispersing a second liquid, immiscible with first to form an emulsion or suspension of fine drops Promoting heat transfer between liquid and a coil or jacket.

6. Agitated Vessels Round bottom to eliminate corners where fluid cannot penetrate Impeller is mounted on a shaft Shaft driven by a motor Baffles to reduce tangential motion of fluid

7. Design of an Agitated Vessel

8. Impellers 2 types Generate currents parallel with the axis of impeller shaft  Axial-flow impeller Generate currents in a radial or tangential direction Radial flow impellers Axial flow impellers impose basically bulk motion, and are used in homogenization processes Radial flow impellers impose shear stress to the fluid, and are used to mix immiscible liquids Axial is in left and Radial is in right side.

9. High Efficiency Impellers High efficiency impellers are d esigned to produce more uniform axial flow and better mixing It Reduces power requirements In high efficiency impellers, blades are sometimes folded to decrease the blade angle near tip It is used to mix low to moderate viscosity liquids but not for very viscous liquids or dispersing gases.

10. Impellers for highly viscous liquids Helical ribbon impeller Having diameter almost equal to inside dia of tank Promotes liquid motion all the way to the tank wall with very viscous liquids Anchor Impeller Creates no vertical motion Less effective than helical Promotes better heat transfer May have scrapers to remove liquid from tank wall Anchor Helical R ibbon

11. 3 types are used based upon low-to-moderate viscosity liquids Propellers Turbines High efficiency impellers

12. Propeller Axial flow, high speed impeller is used for liquids of low viscosity Its rotation forces liquid downward until deflected by the floor vessel Propeller blades cut or shear the liquid Produces a helix in the fluid

13. Propeller One revolution will move the liquid longitudinally a fixed distance depending upon angle of inclination of impeller blades Ration of distance to propeller diameter is called pitch of impeller. (square pitch=1) 2 or more propellers may be used on a single shaft; directing liquid in same direction

14. Turbines Disk Turbine like straight blade turbine creates zones of high shear rate Dispersing a gas in a liquid Pitched blade turbine is used when good overall circulation is important

15. Straight blade turbine impeller Straight blade force liquid radially and tangentially with no vertical movement. Current moves outward to vessel wall and then either upward or downward Also called paddles

16. Flow patterns in Agitated Vessels Depends upon Type of impeller Characteristics of the liquid ( esp viscosity) Size and proportions of the tank, baffles and the impeller

17. Liquid velocity at any point has 3 components Radial – perpendicular to the shaft of impeller Longitudinal – parallel with shaft Tangential or rotational – tangent to a circular path around the shaft. Radial and longitudinal comp are useful in mixing When the shaft is vertical and centrally located; tangential component is disadvantageous – creates a vortex 3 velocity components

18. Vortex formation and its disadvantages If solid particles are present, they will be thrown at the outside by centrifugal force; and move downward and to the centre of the tank at bottom Instead of mixing; (reverse) concentration occurs Relative velocity b/w blades and liquid is reduced Hence power that can be absorbed by the liquid is limited

19. Prevention of Swirling (Vortex) In small tanks, impeller can be mounted off centre In large tanks, agitator may be mounted in the side of the tank with an angle with the radius Installing baffles in large tanks (2,3 or 4)

20. Flow patterns in agitated vessels– Axial flow impellers When swirling or spinning is stopped; flow patterns depends on the type of impeller Propeller agitators drive the liquid down to the bottom of the tank, where stream spreads radially in all directions toward the wall and flows upward along the wall and returns to the suction of the propeller from top. For keeping solid particles in suspensions Axial flow impellers change their flow pattern from axial flow at low liq viscosity to radial at high viscosity.

21. Flow patterns in agitated vessels– flat blade turbines Flat blade turbines give good radial flow Stream moves at the wall and divides One portion flows downward along the wall and back to the center of the impeller from below Another portion flows upward toward the surface and back to impeller from above

22. Flow patterns in agitated vessels

23. Flow patterns in agitated vessels In unbaffled tank there are strong tangential flows and vortex formation at moderate stirrer speeds With baffles, vertical flows are increased and rapid mixing of liquid. 2 or more impellers can be mounted on single shaft for a long vertical cylindrical tank Lowest impeller is usually a radial flow impeller (straight blade turbine); the upper is axial flow Lowest impeller is about one impeller diameter above the bottom of the tank.

24. Mixing and Blending mixing is putting things together. Blending is the combination of things in a unified smoothed manner mixing is the combining of a number of dry ingredients which when combined with a liquid is blended to achieve a uniform (usually) processed product

25. Mixing and Blending Mixing is more difficult operation than agitation Criteria depends upon the experimenter Often good mixing is visual Color change of an acid base indicator Solid-liquid mixtures Rate of decay of concentration or temperature fluctuations; variation in the analysis of small samples taken from various parts of the mix

26. Blending of Miscible liquids Miscible liquids are blended in small process vessels by propellers, turbines or high efficiency impellers In large storage tank, the agitator may turned on only to blend the stratified layers of liquid that are formed as the tank is being filled Stratified blending is often very slow

27. Blending in Process Vessels Impeller in process vessel produces high velocity stream Liquid is well mixed in the region close to impeller because of intense turbulence There is probably little mixing in the direction of flow The fluid completes a circulation loop and returns to the eye of the impeller where vigorous mixing again occurs Calculations show that complete mixing (99%) is achieved if contents are circulated about 5 times

28. Blending

29. Rate of Mixing– Circulation rates For efficient mixing, volume of fluid circulated by impeller must be great enough to sweep out the entire vessel in a reasonable time The velocity of the stream leaving the impeller must be enough to carry the currents to the remotest parts of the tank Circulation rate is not the only factor; turbulence in moving stream is often very imp Turbulence results properly directed currents and large velocity gradients in the liquid

30. Rate of Mixing– Circulation rates Circulation and turbulence both consume energy Flow rate and power dissipation increase with stirrer speed However selection of the type and size of impeller influences the relative values of flow rate and power dissipation Large impellers moving at medium speed promote flow Smaller impellers at high speed are used where intense turbulence is required.