Basicity of heterocyclics pdf

notes on the basicity of heterocyclic compounds...
heterocyclic compounds for graduates, comparison of the relative basicity of pyridine, piperidine and pyrrole...

1. An explanation about the Basic character of piperidine, pyridine and
pyrrole (pKb= 2.9 pKb= 8.8 and pKb= 13.6 respectively)
By- Saurav K. Rawat (Rawat DA Greatt)

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2. Heterocyclic Chemistry
Basicity of pyridine, piperidine and pyrrole
Comparedtoanalogousaliphaticamines,pyridineislessbasic
thisisduetothenitrogenatominpyridineissp2hybridized
(moreelectronegative)andthelonepairofelectronsoccupiesan
sp2orbitalthusitisheldmoretightlybythenucleusthanthe
lonepairofelectroninaliphaticamineswithsp3hybridizedN
atomandthelonepairofelectronsoccupiesansp3orbital(less
electronegative).





An explanation about the Basic character of piperidine, pyridine and
pyrrole (pKb= 2.9 pKb= 8.8 and pKb= 13.6 respectively)
By- Saurav K. Rawat (Rawat DA Greatt)

For more info. Contact me at [email protected]/[email protected]
Download my power point presentations at www.slideshare.net/rawatdagreatt
For videos subscribe to my youtube channel-
www.youtube.com/user/rawatdagreatt
Follow me on twitter @RawatDAgreatt
Catch me on Facebook/ google+/linkedIn

3. An explanation about the Basic character of piperidine, pyridine and
pyrrole (pKb= 2.9 pKb= 8.8 and pKb= 13.6 respectively)
By- Saurav K. Rawat (Rawat DA Greatt)

For more info. Contact me at [email protected]/[email protected]
Download my power point presentations at www.slideshare.net/rawatdagreatt
For videos subscribe to my youtube channel-
www.youtube.com/user/rawatdagreatt
Follow me on twitter @RawatDAgreatt
Catch me on Facebook/ google+/linkedIn