Derivation Of Schrodinger wave equation Using postulates of Quantum mechanics
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Added: Dec 03, 2020
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Mr. Rahul Chauhan Faculty, Chemistry Department UIT, BU Bhopal Quantum Chemistry
Derivation of Schrodinger Equation With the postulates of Quantum mechanics, it is possible to drive the Schrodinger Eqn. in a very simple manner. Consider an electron in an atom. Its total Energy E is given by (1)
This Classical expression of the quantity E can be converted to the corresponding quantum mechanical operator for energy by the following replacements. And
(2) Or (3) Now according to Quantum Postulates (4)