Electrocatalysis Accelerating Electrochemical Reactions with Electrocatalysts
Introduction • Branch of catalysis focused on electrochemical reactions. • Uses electrocatalysts to speed up reactions. • Plays a key role in energy conversion (fuel cells, water splitting, CO₂ reduction).
Principle 1 – Activation Energy & Voltage • Every reaction needs activation energy. • In electrochemistry → linked to electrode potential (voltage). • Electrocatalyst lowers activation energy → reduces overpotential.
Principle 2 – Electron Transfer • Core of electrochemical reactions = electron transfer. • Example: Water Splitting - Cathode (reduction): H₂O → H₂ - Anode (oxidation): H₂O → O₂ • Electrocatalyst provides a favorable surface for faster transfer.
Summary • Electrocatalysts reduce energy demand & increase reaction rates. • Key factors: 1. Lowering activation energy 2. Facilitating electron transfer 3. Optimizing surface interactions • Crucial for green energy technologies.