Explain the difference between phase and state of matter. Ex.pdf

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About This Presentation

Explain the difference between \"phase\" and \"state of matter\". Explain the terms solidus,
liquidus, and solvus.
Solution
A phase of matter is uniform with respect to its physical and chemical properties. Matter
undergoes phase transitions to change from one phase to another. T...


Slide Content

Explain the difference between \"phase\" and \"state of matter\". Explain the terms solidus,
liquidus, and solvus.

Solution

A phase of matter is uniform with respect to its physical and chemical properties. Matter
undergoes phase transitions to change from one phase to another. The primary phases of matter
are solids, liquids, gases, and plasma.
States of Matter
States of matter are solids, liquids, gases, and plasma. Under extreme conditions, other states
exist, such as s Bose–Einstein condensates and neutron-degenerate matter. The state is the form
taken by matter at a given temperature and pressure.
At room temperature and pressure, the state of a piece of dry ice (carbon dioxide) would be solid
and gas phases. At 0 °C, the state of water can be the solid, liquid, and/or gas phase. The state of
water in a glass is the liquid phase
1.States of matter” is a more specific and precise term than “phases of matter.”
2.State of matter is the state of a particular compound in a physical system whereas phase is a
set of states within such a system.
3.Phases of matter can refer to the types of molecular motion.
4.Phases of matter can refer to a certain region in space.

2)
the solidus is the locus of temperatures (a curve on a phase diagram) below which a given
substance is completely solid (crystallized). The solidus is applied, among else, to metal alloys,
ceramics, and natural rocks and minerals.
The solidus quantifies the temperature at which melting of a substance begins, but the substance
is not necessarily melted completely, i.e., the solidus is not necessarily a melting point. For this
distinction, the solidus may be contrasted to the liquidus. The solidus is always less than or equal
to the liquidus, but they need not coincide. If a gap exists between the solidus and liquidus it is
called the freezing range, and within that gap, the substance consists of a mixture of solid and
liquid phases (like a slurry). Such is the case, for example, with the olivine (forsterite-fayalite)
system.
liquidus
The liquidus temperature, TL or Tliq specifies the temperature above which a material is
completely liquid,[1] and the maximum temperature at which crystals can co-exist with the melt
in thermodynamic equilibrium. It is mostly used for impure substances (mixtures) such as

glasses, alloys and rocks.
Above the liquidus temperature the material is homogeneous and liquid at equilibrium. Below
the liquidus temperature, more and more crystals will form in the melt if one waits a sufficiently
long time, depending on the material. Alternately, homogeneous glasses can be obtained through
sufficiently fast cooling, i.e., through kinetic inhibition of the crystallization process.
solvus is a line (binary system) or surface (ternary system) on a phase diagram which separates a
homogeneous solid solution from a field of several phases which may form by exsolution or
incongruent melting. The line determines a solid solubility limit which changes as a function of
temperature.[1] It is a locus of points on the equilibrium diagram. An example is the formation of
perthite when an alkali feldspar is cooled down. It defines the limit of solid solubility in an
equilibrium diagram.
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