INTRODUCTION The fire hazards associated with materials, products, and assemblies used in buildings and other structures have long been a subject of concern and regulation. The hazards of flammable gases and flammable and combustible liquids are widely recognized and regulated with respect to their production, transportation, and utilization. Historically, combustible materials used as part of a building’s construction have been regulated more so than the furnishings and contents brought into buildings, but in recent years the fire hazards and risks associated with furnishings and contents have come under increased scrutiny as the contribution of these products to fires becomes more widely recognized. Evaluation of the fire hazards of materials is complicated, because so many variables can influence the process. These variables include material properties and configurations, environmental conditions, and enclosure effects. Consequently, the fire hazards associated with different materials depend not only on their chemical and physical properties, but also on their applications. -Uncontrolled fires present hazards to life and property due to release of smoke, toxic and corrosive compounds, and release of heat in all fire stages (pre-ignition, ignition, fire growth and flame spread, steady state, and decay). The non-thermal and thermal hazards are created primarily due to the use of products made of combustible materials (both natural and synthetic). These products are used in a variety of ways in residential, private, government, industrial, transportation, and manufacturing applications. Consequently, numerous fire scenarios need to be considered for testing of products MATERIALS CHARACTERISTICS Various products are constructed from natural and synthetic materials containing carbon, hydrogen, oxygen, nitrogen, sulphur, and halogen atoms that are attached to each other by a variety of chemical bonds in the structure. The fire resistance of the materials and products is identified in terms of the ease or difficulty with which materials or products undergo a transformation through the following processes when exposed to heat: • softening and melting • decomposition, vaporization, and charring • ignition • flame spread and fire growth • release of heat • release of smoke, toxic, and corrosive compounds