Metal carbonyl clusters

Metal carbonyl clusters self created notes for M.Sc. and B.Sc. Students

1. Comet ++ cor ben yf
comparada med kölioenn “tte © don zero valant
Hamilim tobe Auch Ni {cs
Exoonple:= 1: NiCCO > 9° >-ubshedinl — derma

© Petcode — dep! — Higenql iparidel up

[=nS +ec=0- + =M<De = ]
no ee
TS y

y PA

Ticas, aro complex copada of treuaitin metals with carbon sanacsdlene|
sb An bd 4 melo) carbonyls the first belivcer th geld

Zip abit) 6f co wit! an empty mel) d

Juuttis in à 9 bond: betüseen te metal dt carben of CO
Hure dematim lone pain. dem carbon inks a vacant

d-akitsl of ta a «Ehio ais also colted back
donstion_or ding: tha second overlap tale
{the field meter dolido an campa and
ochita! sf to Co y

Rak Resulting an additimal À bord _betisean the meta) €
Same co mobile

moe due 6 Hblity die 70 bend forms
(0 danate ez te “Metal Cm) from Xp abit of apto
aatthondiy <P* obit)
Au nated are € oleficiext.
2: Accept lona fair gf elschm -

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2. (9: elechn sale 8 applis
6 thy al

ma: adn alo ez of Inekal tom Arte mod
co Ligands (mole) à (Beclockions.”

lance e € domated lay

the muta tom ote |

9 Paz gs ne dates e =08
SO = Sue = jee

neige = 1040 = (80 E
lance His melan.der 6 felts (907 vale

3. bordo ta pu
are kumn as mola? clusters » e Fe
LA meta) Austern à à
Aloma thot ate dérctl
metal metal bonds “These can bo devide in
Lo Corben? Chutes , + Halde type Chartres

edude ment) cathouy? anima © hydsite
Tha dulainolip tion tha ne Ape “of
fect that ons

em 2 popalive charges
Carbon? Lama alt toe med mai by the ast fers meras
Ag the Sack of the ri A bait, ral seach

vizy fe, co, Mire a, fd, Os Ltr, tt

Glsymsed fuctors of carhoul cha t= pla
I taste ars Ho0/ factors an

es

lla

ve a ft bel do acidalion slats -2n cab churtons the
= SE ng en 4 mia) dem jp dor C-1,0,4): The mélals
loa 1 enangian ff _clemicai. ie hig à slt oli

E hens presto 1 sendy de fan du? me

ta dit air of debit. a ue

oe Sand fodder
| [hres thot te size of dl orbital in iodo prepartional E

O AE RN En

4. a qfectine vues claiges At She cffectise oubli à ail
Laker place stat of vabl clusters increase but! excessive
OserLabbiny Cie: endbuelim) lecienso dhe Alabilik Que to tals
Flora very llo cage un not foverrabte Yor met chast feet

Classification ef conbory? chute :
x E 5 4 es the cbemyt clustónd con bo
classified Inte felinos sine types
w GNCE) Mucha carbo! chatos
@ ÁNCO Lor melon carkmyl chats
U LER Nudenit, hang! Clusters -— Cone)
= are othe the cum in ishich
number metal atin is small Cupl ~4 atom web) vefe 07 4+
Tue où also kwon as di, di. 07 Abm muelas carkngl elustirs
Amplis. which ore een

U à ushich toe wel! ota

Carbonyl e
Esemple= MnsCOe , feLo),, Silla, Rhaccda, 03,000), ote

co

co
Col)

Urea mated atoms

CA] dus M= Ru, Ge lo

Euch al sex
FR No I Fe
PIN [Hite A
ES Umsaa) Loco chien)

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5. (9) High Nuclarily Carbonyl Cl
$

cl lich Me med of neto) atar io +
Han fine metas) ishich ote bonded directty
eg Regie, Ky, CO aly A MA CCT

{such oil clusters have lacas acoil

Thuee melo) carbo

anolhen.

nue

A Large ro
elateol J RENE
Easy raisect carbon cluolers canitainins carbon am, Chere art
nde os Carbide sy! charts: =
Ru ceo. E co |, he ECC) de

Écomper= RsCCO SC,

buchus E |

6. *

Many Nihide carbonyl lies are lon in which ate
aporloted ir the slucla
4) [tu Nc)
commen sodas kr tha Agile { Niliido anbot
aston
ñ + NS — Tiere] + Aco + Na
ES ENT + spe eco ——> ZUR, NCCO) ]
| + sec

betas of Hf, 54 As ore E ltd
ce CsI, (Rh; Pc)", pes cc] +

LPSC]

|

7. 2 wmefals that have leg
high. vuclting 4 boiling patito, Shas
ta) chi? 9
Greats tarada y
Cg meta tutide custo
The Met Chats have fellasing Lagar
a Linucheer chusta

Fr The best Kass, dicton natal elta
lat us age hase He general a [Reoxg ms =
| Men x2 LET T. Nes ete
They may Le pepered Ly the reduction of porblenste im sith Hy |
a RD ei ei

Re > Ele]

“These chats poenen Ue tirs Lgical Cluster.
© they have shot Reh Cruchar distance) af 2 aon? Compared with
Rei ke Jin 6 479 4° in buble metal. |
Fe passos eclipsed confarmebion hich seem de be robles.
E af y Line Me. pone of the vandavalt rie cf 2 Mladic

li E lechos Signatu

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8. @©

Ko)

Aloma me thar He exprientally obsaved distance blue 2 E
arm alack % the Turm gate Re atoms, ont wald lave expected
a less ae canal Sloggered confirmation de bo poe Aahhe

ad

en apt

de
eclipred

A possible explanation for beth Ha above meitimed

[eae
observation :—

D: he day, os pet, abital dead, ke cola) atoms baii
% ge «dp iA Gtitalo on each Raratem
These à accomelate Le” donated by the 40 im

och te each ke

D Ge Se AEE GS ere ised te give dio
Iybudumb orbitals on each ke-atm a de habido obits)
(ORE ain oma rae ry tee ee

ell à weeding 4 0 cut) mail bt]
Ode ps Ea E

| aril this da sopresa as u E dp Lui
| z e ETES

dp hide bondig vraleculer artis

ho CAS

the tio hybsid vo von bondi meuler orbita) me =
ci

9. Sr The dec abitel of
athe Same. Xe phone "I
each. Glande gite 7er C
Simibasby She dye états 4
Lo el
gine Aja Cbording 1 Ay

En dey hits 4 Sta ter

pepe! As sh %
Couittbsoncting) rmálecalaro

ad

the ectipsed Jan
wr ora yi SCH

ee a RENE ch tte eclipred form 5
| Tesch] are ee OL0 ar

©
| dun Di ae? mal abit) af eclipsed fom Cet cto)

along yacht direitos om rt sos)

2, Clarnding ) mo orbits) ef ecliprech fam E ce do 4
li mi le de ate mat ho rd
l ot

the omnia ef chy orbital on Lo atoms
the Abu ae +

10. avientotinn of ot of ke in Reale © +3 Ÿ howe ein thy anion
has dl eofigtilin ha den 20 tue Re lama world cupie for, anf
38 Culte) trie molecular orbitad. Turc o Hy the quardaupde lone
‘a 2) Laitinen the Re ademas This explain booth the obscrveltions
040 rrertémed above +

be: He shot Re-fe distance ¢ He evidance eclipsed pio, rly
fe Pac] y

Some otters Ainuclear compounds ane wel -

O Re aC ACOO)X, © Meteo
ex 77

xi — Rx LE

Lo “3 NN
ER ae ee

(a) Trinuchenn Halide fype chun ose Hype f chiles Loue a gue
wha Mt] Kerr. 1.8 me

Sudan | Recto Shen ar
u

x

> aka Se Ro-Re ditbnee de this du
fee | on cruel dur 35 share Shan the
Cs SPA es diene in de metal he bone dos

E 2 bäueen te Re at 4:

le = Be ton. appenns de be
ala oct with a nu f ligando (1) da give Lac

ue ld as, dine in HA % gie [og yo pa a

[Res ea) edt one SO

in Tho welkcule io Siglo bernd (RR à present Hot «thy Up shank be

He prarqelic pale: Ohi bei ame, iy elt tes

11. Expt. N

Aa cock to alo a deb onda $id natyblows Re 6
— Se db cha tte bord Mate Rife o tot
lip Atlin Shan the bord dongle fe
lie indicatir tre abone LA
Teka)» ola

(25 pre) im

=m ; Ta dinichoar alles.
Fr Co). dimerisos do give à teDrauichonr mila) elurters 14,CoA)a:
ae en tados Han tony há Coridaad es

| umatanited . ib Aclirated foSa is MyCorlıe to hich mis

bends are proscuf de may Le Len
OU, CO _ —— © 00, Client doble bond
Rn yoo,

Lives the dinde mata) chute io mo, Cy)” contain
(a= Me gaben da gie a Ltiamaclen mite) cles (Mo, Uco

I Mer ARS Matta]

E A, Sa
the buin y Hom GANE

Era]? sal ae
ME Tne fan voce mg ef Mo dent form PE Ge

pe. trent ara alternate Aile triple
Beer nig te ‘ee in

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12. Sud ige & cluster - une chutes ort of
ort) LO Mer)”
ee ee
(Max 1 tap Aix Me als form olahudım Asch are colita
fey Beh” ims ligada), mem exch que ef the ottahedinn - he
odabedios so copped by a LUsk Coridgig ) alr it may < 2
hammer of Molt, pie: "Meche botte to sms [ Modas an Hi
core ocidtim Ante À Moin +2. tus LG elecbimic configuailin 544°

Esopo Mosas]” Shuctine o bolas

Ene] dl cxfiguntion

y, ¿[Mesa 5 oftın example d Ha à
EN Le cluster 3

there ore traue Mo-Mo body in the Moce) ectahedion
À tee ore Cox 4=24) yelance 07 form these 19 Me h
m CME)" Harefere each Mor Mo bond weisen te- pair 4e
Hu ate normed Avge band.

ype

Je
+ Zinlle ions —

“There ode alto known as Naked clusters er clusteastcithed
= la = a PH Dovaltinn metodo Ci glp lock ebuvord)
5 clissolve vr dipad amiveria wth perence le alo wala (er
hosmesttes gue Mighty calor ans Auch as sd ELA jit
ase called o Zus ders. Auch BES."
uch ie lors al Kunst os Zoe Naked chat
“Kase ims Show O good coalition bal etactumie. ductos + je
as prudicted by wacle!s ruler fer Listas Ht come once FE
re of!

13. AAN
fs}, a

a
ae =.

[ii —ei

=, thew ase bie five typ Llc lberands
ar devido 3 in pest drug mob) seal
BH unibs <a bolas

4 Caso = (Ent)
4: Nido = @ HJ
3: Arochno = nti

Biz bh
gts te sea onto nl im toc Chang it

AS m He bas sf there shone etectians + es
bo 7 eh shade Se hence —it homie 8H) mail
De ey
LE fellas orale Bb) hear Gly) à _Kdo .

14. © Woy > Ph slew 4e 3

CIE

@ (Pos, P=
ome” 4 (Bot

To Pind voler À € pol
es
RER ne

er: CAD
ae (br He recto

Herce tee pair 14 32 126 pair
RO if cage pot Jin) D 2 magie Hem old ze
@ # die (Anser ue) is x positive) then subbach 2

ont

Qe TS ca > Get)» wie SG? = ee

2)
paa) à
(Es Pone = 6» 5+) 9 We
40 hu e close boone

A A cle. une Yay +

Eee a wide ie

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