MONOLITHIC IC PROCESSES A monolithic integrated circuit (IC) is a set of circuitry on a single semiconductor plate or chip rather than built of separate elements as a discrete circuit is.
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MONOLITHIC IC PROCESSES
Monolithic IC MONO = single stone and LITHIC = lithography. Means writing on the stone ( stone implies semiconductor material) IC means : Integrated circuit ( combination of various components to form circuit on single substrate) It is one in which all circuit components are fabricated in a block of silicon crystal, which is referred as chip or die. Interconnections between the components within the chip are made by means of metallization. The individual components of IC are not separable from the circuit.
Monolithic IC Fabrication of monolithic IC can be divided into two parts: Material Preparation: Purification of silicon Crystal growth Crystal Slicing and Wafer Preparation Basic IC Fabrication Process: Oxidation Ion Implantation Chemical vapor deposition (CVD) Metallization Lithography Packaging
Wafer Preparation The starting material is very high purity silicon. It is grown as a single crystal ingot that appears as solid cylinder (steel gray colour) having 10 to 30 cm diameter and about 1 meter length. This ingot is sliced to produce wafers 10 to 30 cm diameter and 400 to 600 µm thick. Wafers are polished using chemical and mechanical polishing
Oxidation Si l i c o n r ea c ti n g w ith o x y g en t o f or m SiO 2 . The oxygen used in the reaction is introduced either as high purity gas or as a water vapour. T o spee d u p the o xi d a tio n , the w a f e r s a r e he a t ed t o the 100 ◦ t o 1200 ◦ .
Ion Implantation Method to introduce dopants into silicon Ion implanter produces dopants in ion form, accelerates them by an electric field and allows them to strike the silicon wafer surface. The dopants become embedded in the silicon This process is used when accurate control of the dopant is essential for device operation.
Chemical Vapour Deposition (CVD) Process by which gases are chemically reacted to form a solid on a substrate. This process is used to deposit SiO 2 on a Si substrate. Advantage of a CVD layer is that the oxide deposits at a faster rate and at lower temperature. A special case of CVD is epitaxy Silicon layer can be deposited on the wafer. Such epitaxial layer is of crystalline form. Epitaxy takes place at higher temperature.
Metallization The purpose is to interconnect the various components of IC (transistors, diodes, capacitors, resistors) to form desired circuit. The process involves deposition of aluminium metal over those surface areas where interconnection is desired. Also, it is used to produce bonding pads around the periphery of the chip for the bonding of wire leads from the package to the chip.
Lithography Lithography defines the surface geometry of the components. Photo lithography It imposes limit in the size reduction process. Fine line lithography High resolution (more component density). It in c lud e s following pro c e s s e s: ele c tron b e am li t h o gra p h y , X - ray lithography and ion-beam lithography.
P a c k a g i n g Each chip may contain 10 to 10^9 transistors. Chips are separated from each other by dicing, and the good chips(dies) are mounted in packages (headers). Fine gold wires are used to interconnect the pins of the packages to the bonding pads (metallized contact areas) on the die. Finally, the package is sealed under vacuum in an inert temperature.
1. Refining and Growth of Silicon Crystals
Crystal Structure and Growing
Czochralski Process
Crystal Growth Apparatus
2. Silicon Wafer Preparation
3 . DIFFUSION OF DOPANT IMPURITIES
Substitutional Diffusion:
Interstitial Diffusion
Diffusion System
Working explanation
4. Ion Implantation
Ion Implantation System
Annealing after implantation
Advantages of Ion Implantation
5. Photolithography When a sample of crystalline silicon layer acts as a barrier to the diffusion of impurities. i s cov e r e d with S iO 2, t he o x ide So the impurities separated from the surface of the silicon by a layer of oxide do not diffuse into the silicon during high temperature processing. The selective removal of the oxide in the desired area is performed with photolithography. Area over which diffusions are effective are defined by the oxide layer (which inhibits diffusion) with ’windows’ cut in it, through which diffusion can take place. The windows are produced by the photolithographic process
The type of radiation is transmitted through the ”clear” parts of the mask. Types of Lithography Photolithography Electron Beam Lithography X-ray Lithography Ion Beam Lithography
Photolithography Process Steps Photoresist Application (Spinning) A drop of light sensitive liquid called photoresist is applied to the center of the oxidized silicon wafer that is held down by a vacuum chuck. The wafer is then accelerated rapidly to a rotational velocity in the range of 3000 to 7000 rpm for some 30 to 60 seconds. This action spreads the solution in a thin, nearly uniform coat and spins off the liquid. The th i c k ne s s is obta i ned in the ra n ge of 5 000 to 10 00 A ◦ . Typical photoresist used is Kodak Thin Film Resist (KTFR)
2.Prebake The silicon wafers coated with photoresist are now put into an oven at about 80◦ C for about 30 to 60 min to drive off solvents in the photoresist and to harden it into a semisolid film. Alignment and Exposure The coated wafer is now placed in an apparatus called mask aligner in very close proximity (about 25 to 125 µm) to a photomask. A highly collimated ultraviolet light is then turned on and the areas of the silicon wafer that are not covered by the opaque areas of the photomask are exposed to ultraviolet radiation for 3 to 10 sec
Diagram
4. Development Two Types of Photoresist exists: Negative Photoresist and Positive Photoresist For Positive Photoresist, the resist is exposed with UV light wherever the underlying material is to be removed. Negative photoresist behave in opposite manner. Exposure to the UV light causes the negative resist to become polymerized and more difficult to dissolve. The negative resist remains on the surface wherever it is exposed, and the developer solution removes only the unexposed portions.
Fig: Positive and negative photoresist
5. Postbake After development and rinsing the wafers are usually given a postbake in an oven at a temperature of about 150◦ C for about 30 to 60 min to toughen further the remaining resist on the wafer. 6. Oxide Etching The remaining resist is hardened and acts as a convenient mask through which the oxide layer can be etched away to expose areas of semiconductor underneath. These exposed areas are ready for impurity diffusion. 7. Photoresist Stripping The remaining resist is finally removed or stripped off with a mixture of sulphuric acid and hydrogen peroxide and with the help of abrasion process. Finally a step of washing and drying completes the required window in the oxide layer.
6. Fine Line Lithography: Diffraction effect for UV rays. Electron Beam Lithography Better resolution. It is due to small wavelengths of the 10 - 50 KeV electrons. X Ray Lithography. If the wavelength is very small, optical materials become opaque because of the fundamental absorption. Ion beam Lithography. Higher resolution than electron beam lithography.
7. E t c h i n g : For etching of oxide, the wafers immersed in or sprayed with a hydrofluoric (HF) acid solution. The wafers are exposed to the etching solution long enough to remove SiO 2 completely in the areas of the wafer that are not covered by the photoresist. The duration of oxide etching should be carefully controlled so that all of the oxide present only in the photoresist window is removed.
Wet Etching and Dry Etching: Wet etching involves dipping the wafer into a liquid bath containing a chemical that will dissolve only the SiO 2 material and none of the surrounding material. The etching chemical must not react the resist. A measure of the amount of undercutting is called the etch bias, which is defined as
Dry Etching : Low pressure gas discharges are used. Different types Plasma Etching. Reactive ion beam (RIE) etching. Sputtering Ion beam etching Reactive ion beam etching
Plasma : It is an ionized gas with nearly equal amounts of positive and negative charged particles. A weakly ionized plasma, called ”glow discharge” -Significant density of neutral particles (more than 90% in most etchers). It consists of charged particles that can be influenced by applied electric field (E) and magnetic (H) fields. 8 . Epitaxy : Epitaxy is a process to grow a single crystal layer ( from vapor phase) on a single crystal substrate. If the grown layer and the substrate are of exactly the same material, the process is called homoepitaxy. If they are different, the process is called heteroepitaxy.
Uses of Epitaxy: To enhance the performance of discrete bipolar transistors. T o p r epa r e c omp o u n d sem i c o n d uc t o r m a t er i als s uc h as G aAs, I n P , AlGaAS, InGaASp, CdSe and HgCdTe. To prepare LEDs, semiconductor lasers, heterojunction bipolar transistors (HBT), modulation doped field effect transistors(MODFET) and the long wavelength infrared detectors.
Vapour Phase Epitaxy (VPE):
Epitaxial Reactors:
Epitaxial Reactors:
Epitaxial Growth Process:
9. Chemical Vapour Deposition (CVD): CVD is a process by which gases or vapours are chemically reacted, leading to the formation of a solid on a substrate. CVD is defined as the formation of non-volatile solid film on a substrate by the reaction of vapour phase chemicals ( Reactants) that contain the required constituents. It is used to deposit dielectric and polysilicon films in fabrication of ICs. Advantage: Oxide deposit at faster rate and process requires much lower temperature.
CVD steps: T ra n sp o rt o f re a cting g a seo u s s p eci e s t o subst r ate surface. Absorption of species on substrate surface. Hetero g en e ous surf a ce re a ct i on cat a lyz e d b y t h e substrate surface. Desorption of gaseous reactions by products Transport of reaction byproducts away from substrate surface
CVD methods and Reactors: CVD Methods Atmospheric Pressure CVD (APCVD) Low Pressure CVD (LPCVD) Plasma Enhanced CVD (PECVD) CVD Reactors Four methods of heating the wafer exists - Resistance heating, rf induction heating, plasma heating and heating by photon energy. When both wafers as reaction chambers become hot, as happens in resistance heating, the designs are known as hot wall reactors. In case of rf induction heating or infrared heating the chamber walls may not be appreciably heated, so reactors heated by these methods are called cold wall reactors.
10. Metallization : Final step in the wafer processing sequences. Metallization is the process by which the components of ICs are interconnected by aluminium conductor. This process produces a thin film metal layer that will serve as the required conductor pattern for the interconnection of the various components on the chip. Another use of metallization is to produce metallized areas called bonding pads around the periphery of the chip to produce metallized areas for the bonding of wire leads from the package to the chip. Bonding pads are 100µm × 100µm square. Bonding wires are typically 25µm diameter gold wires. Aluminium is the most commonly used material.
Deposition Apparatus: High V acu u m cha m b e r for metallization process.