Properties of nanomaterials GERUGANTI NIKSHITHA B.TECH(ELECTRICAL ENGINEERING),GNITS,HYD.
The properties of nanomaterials depend upon : Size For example: copper nanoparticles smaller than 50nm are super hard Materials and do not exhibit the properties of mallaebility or ductility of bulk copper
The different types of properties shown by nanomaterials are:
Physical properties of nanomaterials By reducing the size of the particle the surface to volume ratio increases. This changes the surface pressure ,resulting in decrease in the interatomic spacing . The change in inter atomic spacing and large surface to volume ratio have a combined effect on material properties such as,
Melting point: The melting point decreases with size and at very small sizes the decrease is faster
Chemical properties
Chemical properties In small positively charged clusters of Ni, Pd and Pt can absorb up to eight hydrogen atoms per metal atom The number of absorbed atoms increases with decrease in cluster size This shows that small particles are very useful in hydrogen storage devices in metals
Quantum well, wire,dot
Electrical properties
Electrical properties In the figure we see that due quantum confinement the energy levels narrow down and become discrete when we move from bulk to dot Tn nanomaterials the electrical conductivity increases with reduction in particle size
Optical properties Depending on the particle size ,different colors are seen for example gold nano spheres of 100nm appear orange in colour while 50 nm nanospheres appear green in colour Particles can be made to emit or absorb a specific wavelength by controlling their size This Photo by Unknown author is licensed under CC BY-SA .
Magnetic properties Nano materials show high coercivity and magnetization values These values increase with decrease in the grain size and an increase in the specific surface area of the grains The magnetic moment of Co particles of approx 2nm exhibited 20% higher value than that of bulk Nano particles of even non- magnetic solids are found to be magnetic
Mechanical properties If the grains are nanoscale in size ,the interface within the material greatly increases, which enhances the strength For example: nanocrystalline nickel is as strong hardened steel Decreasing hardness with decreasing grain size in the nanoscale grain regime Superplastic behaviour of ceramic