Raoult’s law
Molarity (M)
M =
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P = PA = P
°
A XA
�
°
?????? − �
�
°
??????
= ??????
PA = partial vapour pressure of A
PB = partial vapour pressure of B
P°A = Vapour pressure of pure A
P°B = Vapour pressure of pure B
Depression of freezing point
ΔTf = Kf m
Kb = ebulliscopic constant
Kf = cryoscopic constant
C = Molarity
R = rate constant
T = temperature
Osmotic pressure (π)
π = CRT
Van’t Hoff factor (i)
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i =
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i =
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??????������� ����� ����
i =
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��. �� ����� ������ �����??????��??????��/�??????����??????��??????��
Modified form of Colligative properties
1
2
�
°
??????
ΔTb = ?????? Kb m
�
°
??????− �
= ?????? ??????
PA = partial vapour pressure of A
PB = partial vapour pressure of B
P°A = Vapour pressure of pure A
P°B = Vapour pressure of pure B
Elevation of boiling point
ΔTb = Kb m
Degree of Disassociation
α =
?????? − ??????
� − ??????
Degree of association
?????? − ??????
α =
�
??????
− ??????
n = number of ions