BOILER EXTERNAL INTERNAL TREATMENT Of Palm oil Mill

HeruPramudya2 21 views 62 slides Mar 11, 2025
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About This Presentation

Boiler


Slide Content

MOHD IKHSAN YAACOB
BOILER BOILER
EXTERNALEXTERNAL
&&
INTERNAL INTERNAL
TREATMENTTREATMENT

MOHD IKHSAN YAACOB

INTRODUCTION AND PURPOSE ToINTRODUCTION AND PURPOSE To

understand fundamentals of water understand fundamentals of water
treatment, as well as the system in POMtreatment, as well as the system in POM

To be aware of treatment requirement and To be aware of treatment requirement and
prevent problems to boilerprevent problems to boiler
BOILER EXTERNAL & INTERNAL TREATMENTBOILER EXTERNAL & INTERNAL TREATMENT

MOHD IKHSAN YAACOB

Water treatment in POM Water treatment in POM
1.1.External treatmentExternal treatment

ClarifierClarifier

FilterFilter

SoftenerSoftener

DeaeratorDeaerator
2.2.Internal treatmentInternal treatment

Chemical treatment in boiler and Chemical treatment in boiler and
condensate systemcondensate system
BOILER EXTERNAL & INTERNAL TREATMENTBOILER EXTERNAL & INTERNAL TREATMENT

MOHD IKHSAN YAACOB
Water treatment in POMWater treatment in POM
River
Water pump
Clarifier
Filter
Softener
De-aerator
Feed
Water
Tank

MOHD IKHSAN YAACOB
Water treatment in POMWater treatment in POM

External treatment is so crucial as…External treatment is so crucial as…

It is most critical part of the total boiler It is most critical part of the total boiler
system with respect to maintaining boiler system with respect to maintaining boiler
cleanliness.cleanliness.

It is to produce water of acceptable quality It is to produce water of acceptable quality
for use in the boilerfor use in the boiler

MOHD IKHSAN YAACOB
ClarifierClarifier

MOHD IKHSAN YAACOB
ClarifierClarifier

To remove the settable To remove the settable
and suspended solidsand suspended solids

To provide liquid-solids To provide liquid-solids
separation with addition separation with addition
of coagulant and of coagulant and
flocculantsflocculants

To achieve TSS 10ppm To achieve TSS 10ppm
or lessor less

Typical type in POM-up Typical type in POM-up
flow and sludge flow and sludge
recirculation, water recirculation, water
retention time at 2 retention time at 2
hours and rise rate at hours and rise rate at
2m2m
33
/hr/hr

MOHD IKHSAN YAACOB
Step 1: pH adjustmentStep 1: pH adjustment

If pH less than 6, use soda ash(Na2CO3)/ If pH less than 6, use soda ash(Na2CO3)/
caustic soda(NaOH)/ lime (Ca(OH)2/ caustic soda(NaOH)/ lime (Ca(OH)2/
pottasium hydroxide(KOH)pottasium hydroxide(KOH)

If pH more than 8, use acid (HCI, H2SO4)If pH more than 8, use acid (HCI, H2SO4)

Important to get correct pH before addition Important to get correct pH before addition
of coagulant (especially alum)of coagulant (especially alum)
How liquid solids separation takes How liquid solids separation takes
place in clarifierplace in clarifier

MOHD IKHSAN YAACOB
Step 2: CoagulationStep 2: Coagulation

Charge neutralization processCharge neutralization process

Addition of chemical coagulant to destabilize Addition of chemical coagulant to destabilize
colloidal particles in water by neutralizing the colloidal particles in water by neutralizing the
forces that keep them apart. The process forces that keep them apart. The process
requires mixing energy to make destabilized requires mixing energy to make destabilized
particles to collide for floc formationparticles to collide for floc formation

Chemical coagulants commonly used areChemical coagulants commonly used are

Aluminium salts: Alum, Polyaluminium Chloride Aluminium salts: Alum, Polyaluminium Chloride
(PAC)(PAC)

PolyelectrolytePolyelectrolyte

Organic coagulantOrganic coagulant
How liquid solids separation takes How liquid solids separation takes
place in clarifierplace in clarifier

MOHD IKHSAN YAACOB
Step 3: FlocculationStep 3: Flocculation

Floc building process Polymers are added Floc building process Polymers are added
to agglomerate small coagulated flocs to to agglomerate small coagulated flocs to
form big & dense ones so that it can settle form big & dense ones so that it can settle
fastfast
Step 4: SettlingStep 4: Settling

After coagulation and flocculation process, After coagulation and flocculation process,
dense flocs will settle at the bottom of dense flocs will settle at the bottom of
clarifier and form sludge blanket.clarifier and form sludge blanket.
How liquid solids separation takes How liquid solids separation takes
places place in clarifierplaces place in clarifier

MOHD IKHSAN YAACOB

Sludge blanketSludge blanket

Depth of sludge blanket is the working depth of Depth of sludge blanket is the working depth of
sludge over the bottom of the sludge sludge over the bottom of the sludge
recirculation draft tube in an upflow-solids recirculation draft tube in an upflow-solids
contact clarifier. Typically 60 to 80 inches below contact clarifier. Typically 60 to 80 inches below
the water surfacethe water surface

Too high or too low a blanket will results into Too high or too low a blanket will results into
carryovercarryover
How liquid solids separation takes How liquid solids separation takes
places place in clarifierplaces place in clarifier

MOHD IKHSAN YAACOB
Clear Water
Clear Water
Typical Flow Diagram
Of a Up flow Sludge Blanket
Water Clarifier

MOHD IKHSAN YAACOB

Sludge blowdownSludge blowdown

Sludge must be removed in proportion to the Sludge must be removed in proportion to the
amount formed and frequent intervalsamount formed and frequent intervals

Too less sludge blowdownToo less sludge blowdown

Sludge solidified and become hard to removeSludge solidified and become hard to remove

Raised sludge blanket too high>excessive carryoverRaised sludge blanket too high>excessive carryover

Scum floating and odor – anaerobic decompositionScum floating and odor – anaerobic decomposition

Too much sludge blowdownToo much sludge blowdown

Deplete sludge blanket>excessive suspended solids Deplete sludge blanket>excessive suspended solids
carry over.carry over.
How liquid solids separation takes How liquid solids separation takes
places place in clarifierplaces place in clarifier

MOHD IKHSAN YAACOB
How to determine How to determine
chemical dosage?chemical dosage?

MOHD IKHSAN YAACOB
How to determine chemical How to determine chemical
dosage?dosage?
Jar TestJar Test
And And
Plant Plant
TrialTrial

MOHD IKHSAN YAACOB
Where are typical injection points?Where are typical injection points?
Flocculants
Coagulant
Soda Ash
10 ~15 ft 5 ft
W
a
t
e
r

r
i
s
e

r
a
t
e
2
m
3
/
h
r
Coagulant Soda Ash Raw Water

MOHD IKHSAN YAACOB
FilterFilter

MOHD IKHSAN YAACOB
FilterFilter

To filter the solids To filter the solids
escaped from the escaped from the
clarifierclarifier

To remove fine particles To remove fine particles
up to 10 micron sizeup to 10 micron size

Optimally operated Optimally operated
filter will not burden filter will not burden
softenersoftener

To achieve water To achieve water
turbidity <5NTUturbidity <5NTU

MOHD IKHSAN YAACOB

When to backwash the filter?When to backwash the filter?

High pressure dropped across the filter and High pressure dropped across the filter and
resulting low water throughput, orresulting low water throughput, or

Filtered water turbidity has reached the Filtered water turbidity has reached the
preset value, i.e. turbidity >5NTUpreset value, i.e. turbidity >5NTU
FilterFilter

MOHD IKHSAN YAACOB

Functions to remove Total Hardness, namely Functions to remove Total Hardness, namely
calcium and magnesium ions by ion exchange calcium and magnesium ions by ion exchange
process in sodium zeolite resinprocess in sodium zeolite resin

Subject to mud and iron fouling – hence Subject to mud and iron fouling – hence
important to receive acceptable influentimportant to receive acceptable influent

Backwash and brine regeneratiom is requiredBackwash and brine regeneratiom is required

Reversible process – based on ion selectivity Reversible process – based on ion selectivity
and concentration dominantand concentration dominant
SoftenerSoftener

MOHD IKHSAN YAACOB
Ion Exchange ProcessIon Exchange Process
C
a
l
c
i
u
m
M
a
g
n
e
s
i
u
m
Sodium

MOHD IKHSAN YAACOB
Ion Exchange ProcessIon Exchange Process
S
o
d
i
u
m
Calcium

MOHD IKHSAN YAACOB
How Can You Tell If Your Softener How Can You Tell If Your Softener
Is Not Working Correctly?Is Not Working Correctly?

Check hardness of water leaving Check hardness of water leaving
softener. Good if below 2 ppmsoftener. Good if below 2 ppm

Check amount of treated water Check amount of treated water
between regeneration – to determine between regeneration – to determine
regeneration cycles (in days)regeneration cycles (in days)

MOHD IKHSAN YAACOB
Brining
45~60 min
Slow Rinse
20~25 mins
Fast Rinse
45~60 mins
Backwash
Until clear water
What if softener is exhausted What if softener is exhausted
and high hardness breakthrough?and high hardness breakthrough?

MOHD IKHSAN YAACOB
Purpose Of BackwashPurpose Of Backwash

Remove mud, sand, dirt and broken resin Remove mud, sand, dirt and broken resin
beadsbeads

Dirt and broken resin beads must reach Dirt and broken resin beads must reach
top of water distribution headertop of water distribution header

A successful backwashA successful backwash

50% expansion of resin bead50% expansion of resin bead

10~20 minutes10~20 minutes

Clear waterClear water

MOHD IKHSAN YAACOB
Purpose Of BackwashPurpose Of Backwash

SOFTENER-BriningSOFTENER-Brining

Remove hardness ions from resin beadsRemove hardness ions from resin beads

Replenish sodium ions on resinReplenish sodium ions on resin

Must be enough salt to force calcium & magnesium off Must be enough salt to force calcium & magnesium off
the resin SOFTENER-Regenerationthe resin SOFTENER-Regeneration

A successful regenerationA successful regeneration

Use 1kg of salts/ 5liters of resinUse 1kg of salts/ 5liters of resin

Prepare brine solution concentration of 25~27% by Prepare brine solution concentration of 25~27% by
weight in brine tank stirrerweight in brine tank stirrer

Has at least brine solution concentration 8% by weight Has at least brine solution concentration 8% by weight
after softener eductorafter softener eductor

Maintain a brine concentration at 8% by weight >30 Maintain a brine concentration at 8% by weight >30
minutes to fluidized resin bedminutes to fluidized resin bed

MOHD IKHSAN YAACOB
Purpose Of BackwashPurpose Of Backwash

SOFTENER-Slow rinseSOFTENER-Slow rinse

Push salt all the way through the softenerPush salt all the way through the softener

Is at the same rate as generation for 20~25 minutesIs at the same rate as generation for 20~25 minutes

SOFTENER- Fast RinseSOFTENER- Fast Rinse

Remove excess salt from the softener before it goes Remove excess salt from the softener before it goes
back on serviceback on service

Uses the same flow rate at which the softener Uses the same flow rate at which the softener
operatesoperates

MOHD IKHSAN YAACOB
ELUTION STUDYELUTION STUDY
REGENERATION PROFILEREGENERATION PROFILE
0
10
20
30
Salometer
Degree
10203040506070
Regeneration
Time
Regeneration

MOHD IKHSAN YAACOB
SOFTENER CYCLESSOFTENER CYCLES
G=(Ec, Eq/L)*(Resin Vol,L)*(50)G=(Ec, Eq/L)*(Resin Vol,L)*(50)
TH,ppmTH,ppm
G=______mG=______m
33
/regeneration?/regeneration?
WhereWhereG = Capacity (mG = Capacity (m
33
/regeneration)/regeneration)
Ec = Exchange capacity (Eq/L resin)Ec = Exchange capacity (Eq/L resin)
L = Resin Volume (Liters)L = Resin Volume (Liters)
TH = Total Hardness (ppm)TH = Total Hardness (ppm)

MOHD IKHSAN YAACOB
How do you determine the How do you determine the
condition of the resincondition of the resin

MOHD IKHSAN YAACOB
Poor control and Poor control and
monitoring of softenermonitoring of softener

MOHD IKHSAN YAACOB
Poor control and monitoring of Poor control and monitoring of
softener: SCALEsoftener: SCALE

MOHD IKHSAN YAACOB
DEAERATORDEAERATOR

MOHD IKHSAN YAACOB
DEAERATORDEAERATOR
REMOVING GAS FROM WATERREMOVING GAS FROM WATER

Dissolved gases present in boiler waterDissolved gases present in boiler water

OxygenOxygen

Carbon dioxideCarbon dioxide

They are corrosive and must be They are corrosive and must be
removed before boiler useremoved before boiler use

DEAERATOR is used to removed this DEAERATOR is used to removed this
dissolved gases by achieving water dissolved gases by achieving water
boiling pointboiling point

MOHD IKHSAN YAACOB
DEAERATORDEAERATOR
Solubility of Oxygen in Pure Solubility of Oxygen in Pure
WaterWater
0
4
8
12
16
20
24
28
Temperature C
O
x
y
g
e
n
,

p
p
m
10 psi1010 8 7 6 4 3 2 2 2 0
5 psi141410 9 8 7 6 5 4 4 4 0
0 psi1616131110 9 8 7 7 6 5 0
-10 psi26262420151210 9 8 7 6 4 0
20406080100120140160180200220240

MOHD IKHSAN YAACOB
DEAERATORDEAERATOR
TWO TYPES OF DEAERATORTWO TYPES OF DEAERATOR
1.1.PRESSURE DEAERATORPRESSURE DEAERATOR
2.2.VACUUM DEAERATORVACUUM DEAERATOR

MOHD IKHSAN YAACOB
PRESSURE DEAERATORPRESSURE DEAERATOR
Water
InletVent
To
atmosphere
Water Outlet
Steam
Inlet

MOHD IKHSAN YAACOB

MOHD IKHSAN YAACOB
PRESSURE DEAERATORPRESSURE DEAERATOR

Usually used in power plant to remove Usually used in power plant to remove
OO
22 in feed water in feed water

Water is atomized, steam scrubbing and Water is atomized, steam scrubbing and
venting of gasesventing of gases

Operate at 5psig, 100~105OCOperate at 5psig, 100~105OC
OO
22 can be reduced to 0.07~0.04ppm can be reduced to 0.07~0.04ppm

MOHD IKHSAN YAACOB
VACUUM DEAERATORVACUUM DEAERATOR
Extraction pump
From
Feed Water
Tank
Steam
Deaerated
Water
-550mmHg Vacuum
Boiling Point 70
O
C

MOHD IKHSAN YAACOB
VACUUM DEAERATORVACUUM DEAERATOR
OO
2 2 and COand CO
22 is removed by creating is removed by creating
vacuum pressurevacuum pressure

In this case water boiling point is In this case water boiling point is
loweredlowered

Pressure -550mmHg, coupled with water Pressure -550mmHg, coupled with water
temperature between 60temperature between 60
OO
~70~70
OO
CC

Decrease solubility of dissolved gases at Decrease solubility of dissolved gases at
boiling pointboiling point

MOHD IKHSAN YAACOB
VACUUM DEAERATORVACUUM DEAERATOR

Vacuum is created using steam ejector Vacuum is created using steam ejector
(Venturi effect with high kinetic head(Venturi effect with high kinetic head
OO
22 can be reduced to 0.2~0.5 ppm can be reduced to 0.2~0.5 ppm

Have to prevent air in leakage into the Have to prevent air in leakage into the
system through pump, seals, valve, system through pump, seals, valve,
fittings, flanges etc.fittings, flanges etc.

Water level must be below the water Water level must be below the water
sprayer nozzles for atomizationsprayer nozzles for atomization

MOHD IKHSAN YAACOB
Poor Control & Monitoring of De-Poor Control & Monitoring of De-
aerator will results into OXYGEN aerator will results into OXYGEN
PITTINGPITTING

MOHD IKHSAN YAACOB
BOILER INTERNAL BOILER INTERNAL
TREATMENTTREATMENT

MOHD IKHSAN YAACOB
Circulation in A Water Tube Circulation in A Water Tube
BoilerBoiler
Steam
Drum
Mud
Drum
D
o
w
n

c
o
m
e
r
s
R
i
s
e
r
s
Hot
Gase
s
Fire
Box
Mud
Drum
Super
Heater
Header

MOHD IKHSAN YAACOB
Steam
Drum
Down
comers
Risers
Bottom Side Wall Tube Header
Main Steam
Range
Saturated Steam
Superheated
Steam
Top
Side Wall
Tube Header
Typical Water/Steam
Flow Diagram of a Fraser
Water Tube Boiler
Super Heater
Header

MOHD IKHSAN YAACOB
BOILER WATER BOILER WATER
TREATMENTTREATMENT

THREE MAJOR PROBLEMS IN BOILERTHREE MAJOR PROBLEMS IN BOILER

CorrosionCorrosion

Scale and depositionScale and deposition

CarryoverCarryover

THE PURPOSE OF BOILER WATER THE PURPOSE OF BOILER WATER
TREATMENTTREATMENT

To prevent corrosionTo prevent corrosion

To prevent scale and depositionTo prevent scale and deposition

To prevent carryoverTo prevent carryover

MOHD IKHSAN YAACOB
ROOT CAUSE OF BOILER ROOT CAUSE OF BOILER
WATER PROBLEMSWATER PROBLEMS

Poor water qualityPoor water quality

Hardness, TDS, pH, Silica, Iron, etcHardness, TDS, pH, Silica, Iron, etc

Poor external treatmentPoor external treatment

Pre-treatment i.e. Clarification, Filter, Pre-treatment i.e. Clarification, Filter,
Softener and De-aerationSoftener and De-aeration

Poor internal treatmentPoor internal treatment

Scale and deposit Control, Corrosion Scale and deposit Control, Corrosion
prevention, anti foamingprevention, anti foaming

MOHD IKHSAN YAACOB
CORROSIONCORROSION

Corrosion causeCorrosion cause

Oxygen and low pH is the main culpritOxygen and low pH is the main culprit

Deposition that cause underneath corrosionDeposition that cause underneath corrosion

MOHD IKHSAN YAACOB
CORROSIONCORROSION

IMPACTIMPACT

Deterioration of boiler metal/tube punctureDeterioration of boiler metal/tube puncture

High repair costHigh repair cost

Unscheduled shutdownUnscheduled shutdown

PREVENTIONPREVENTION

Remove dissolved gases (ORemove dissolved gases (O
22 and CO and CO
22) by deaerator before ) by deaerator before
entering boilerentering boiler

Maintain alkaline pH in boiler waterMaintain alkaline pH in boiler water

Use oxygen scavenger to remove residual OUse oxygen scavenger to remove residual O
22 and maintain and maintain
sufficient reserve in boiler watersufficient reserve in boiler water

Keep TDS within operating limitsKeep TDS within operating limits

Proper wet storage procedure when boiler will be idle for Proper wet storage procedure when boiler will be idle for
long periodlong period

MOHD IKHSAN YAACOB

MOHD IKHSAN YAACOB
SCALESCALE

SCALE CAUSESCALE CAUSE

Calcium, magnesium, sulfate, silica, soluble iron, aluminium form Calcium, magnesium, sulfate, silica, soluble iron, aluminium form
precipitates (Over saturation)precipitates (Over saturation)

IMPACTIMPACT

Scale form insulator film affecting heat transfer efficiency.Scale form insulator film affecting heat transfer efficiency.

Tube failure from overheatingTube failure from overheating

Underneath deposits corrosionUnderneath deposits corrosion

Deposits plug tubes causing starvation and subsequently Deposits plug tubes causing starvation and subsequently
overheatoverheat

Take long time for cleaningTake long time for cleaning

Might need acid cleaning, depends on scaleMight need acid cleaning, depends on scale

Productivity downedProductivity downed

Mill profitability downedMill profitability downed

MOHD IKHSAN YAACOB
SCALESCALE

PREVENT SCALINGPREVENT SCALING

Minimize hardness in softener water(0~2 ppm)Minimize hardness in softener water(0~2 ppm)

Maintain recommended Silica levelMaintain recommended Silica level

Maintain suspended solids/ turbidity in feed Maintain suspended solids/ turbidity in feed
water <3 NTUwater <3 NTU

Keep minimum Aluminum in feed water<0.3ppmKeep minimum Aluminum in feed water<0.3ppm

Minimized the amount of iron in feed water < Minimized the amount of iron in feed water <
0.3ppm0.3ppm

Maintain good blow down frequency over TDS Maintain good blow down frequency over TDS
level <2000ppmlevel <2000ppm

MOHD IKHSAN YAACOB
SCALESCALE

MOHD IKHSAN YAACOB
CARRYOVERCARRYOVER

WHAT IS CARRY WHAT IS CARRY
OVEROVER

Boiler water carried Boiler water carried
into steaminto steam

CAUSE BYCAUSE BY

Foaming (Chemical)Foaming (Chemical)

Misting (Operational)Misting (Operational)

Priming (Operational)Priming (Operational)

MOHD IKHSAN YAACOB
CARRYOVERCARRYOVER

WHAT ARE THE CONSEQUENCESWHAT ARE THE CONSEQUENCES

Deposits in superheated tubes-tube burstDeposits in superheated tubes-tube burst

Deposits in turbine blades-Efficiency droppedDeposits in turbine blades-Efficiency dropped

Turbine erosionTurbine erosion

PREVENTIONPREVENTION

Use anti foam if cause by foamingUse anti foam if cause by foaming

Do not run boiler at high water levelDo not run boiler at high water level

Do not overload boilerDo not overload boiler

Control dissolved solids levelControl dissolved solids level

Avoid oil contaminationAvoid oil contamination

MOHD IKHSAN YAACOB
BOILER INTERNAL BOILER INTERNAL
TREATMENTTREATMENT
Sulfite Oxygen ScavengerSulfite Oxygen Scavenger

Prevent pitting corrosionPrevent pitting corrosion

Catalyzed: React with O2 500 times faster Catalyzed: React with O2 500 times faster
than ordinary sulfitethan ordinary sulfite

Maintained reserve at 30~50 ppmMaintained reserve at 30~50 ppm

Low sulfiteLow sulfite

High DO in feedwaterHigh DO in feedwater

Boile may have corrosion problemBoile may have corrosion problem

High SulfiteHigh Sulfite

High treatment costHigh treatment cost

MOHD IKHSAN YAACOB
BOILER INTERNAL BOILER INTERNAL
TREATMENTTREATMENT
OrthophosphateOrthophosphate

Hardness inhibitorHardness inhibitor

Form Calcium HydroPatixe (less Adhesive Sludge) Form Calcium HydroPatixe (less Adhesive Sludge)
before it is removed through blow downbefore it is removed through blow down

Below range ~ No protection on hardness in leakageBelow range ~ No protection on hardness in leakage

Maintain 30~80 as reserveMaintain 30~80 as reserve

Low PO4Low PO4

High hardness in feed waterHigh hardness in feed water

Boiler may have scale problemBoiler may have scale problem

High PO4High PO4

High treatment costHigh treatment cost

MOHD IKHSAN YAACOB
BOILER INTERNAL BOILER INTERNAL
TREATMENTTREATMENT
Alkalinity BoosterAlkalinity Booster
pH Maintained at 10.5 ~ 11.5
P-Alkalinity maintained at 350~800 ppm
for boiler pressure <350psi
Dose depend on feed water M-Alkalinity
& Silica level
Maintain Silica to Alkalinity ratio 1:5
Important in preventing corrosion and
scale especially silicate deposit.

MOHD IKHSAN YAACOB
BOILER INTERNAL BOILER INTERNAL
TREATMENTTREATMENT

Scale inhibitor or dispersantScale inhibitor or dispersant

Synthetic polymerSynthetic polymer

Keep the hardness solubilization in bulk Keep the hardness solubilization in bulk
waterwater

Disperse precipitates and keep the Disperse precipitates and keep the
sludge suspension form in bulksludge suspension form in bulk

Low dose ~Deposits or Scale formationLow dose ~Deposits or Scale formation

MOHD IKHSAN YAACOB
Control specificationsControl specifications
Total Total
hardnesshardness
(ppm)(ppm)
Total ironTotal iron
(ppm)(ppm)
pHpH
M-M-
alkalinityalkalinity
(ppm)(ppm)
Softened Softened
waterwater
0~2 0~2 <0.3<0.3
Boiler Boiler
feed feed
waterwater
0~20~2 <0.3<0.3 7.0~7.57.0~7.5 25~3525~35

MOHD IKHSAN YAACOB
Control specificationsControl specifications
SULFITESULFITE 30~80 PPM30~80 PPM
PHOSPAHATEPHOSPAHATE 30~80 ppm30~80 ppm
TDSTDS <2000 ppm<2000 ppm
P AlkalinityP Alkalinity 350~8--350~8--
pHpH 10.5~11.510.5~11.5
IronIron <5 ppm<5 ppm
SilicaSilica <150ppm<150ppm
ChlorideChloride <500 ppm<500 ppm