Cationic reagent PTAC 65% information

1. 山東兖州天成化工有限公司
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 West of Beizhan Road, Yanzhou
Shandong, 272117 P.R. China
Tel:: [phone]
Fax: [phone]
Mobile/Whatsapp: [phone]
Email:[email protected]
Web:www.yztchg.com
CERTIFICATE OF ANALYSIS
Product Name
Cationic reagent
PTAC1881
Lot No. 20150106
ProductionDate 15.01.06 Analysis Date 15.01.06
Executive standard: Q/0882YTC008-2012
Items Specification Analyzed Results
Appearance Transparent liquid Transparentliquid
Content ≥65.00 % 65.40%
ECH ＜5 ppm Not detected
1,3-Dichloro-2-propanol ＜10 ppm 1.9ppm
Results
Qualified products
Analyst: Jin Xin Auditor:Zhang Yinguang

2. 山東兖州天成化工有限公司
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 Westof Beizhan Road, Yanzhou
Shandong, 272117 P.R. China
Tel: [phone]
Fax: [phone]
Mobile/Whatsapp: [phone]
Email:[email protected]
Web:www.yztchg.com
PTAC1881TechnicalData Sheet
Chemical name 3-Chloro-2-HydroxypropylTrimethylAmmonium Chloride
Alias CHPTAC, PTAC,Quat 188,PTAC1881, CTA 1881
Formula C6H15NOCl2
Mol.Wt. 188.1 CASNo. 3327-22-8
Structure
3-Chloro-2-HydroxypropylTrimethylAmmonium Chloride ≥65%
Moisture content ≤35%
Relative Density 1.16 g/cm
2
(20℃) Appearance Colorless andclear liquid
AutoignitionTemperature NonHypergolic pH(10%aqueous
solution)
5.0-7.0
Crystallization Point -14℃ Viscosity 13-20 mpa.s(25℃)
Solubility inWater Very soluble Stability Stable
Prohibited content
Strongoxidant, strong
base, strong acid
Packing
200LplasticbarrelorIBCton
barrel
Test equipment Gaschromatograph Test temperature
Column temperature:120℃
Sampleinjector:200℃
Application
1．PaperChemicals
Cationicreagentisanimportant additive in paper industry, widely used in starch, cellulose,
chitosan and otherchemical modification. The cationic starch modifiedby cationic reagentcan be
usedaspaper surface sizing, retention and drainage aids, enhancers etc., isa kind of largely
consumedpapermakingadditive.
2．TextileIndustry
(3-chloro-2-hydroxypropyl)trimethyl ammonium chloride modified cotton fibers, improves its
adhesion to the dye;thecationic starch can be used as warp sizing agentafterreaction ofstarch.
Sales & Marketing Department：
Add：No. 66 west of Beizhan Rd, Yanzhou, China
Phone：[phone] Fax：[phone]
Email：[email protected] Web:www.yztchg.com

3. 山東兖州天成化工有限公司
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 West of Beizhan Road, Yanzhou
Shandong, 272117 P.R. China
Tel: [phone]
Fax: [phone]
Mobile/Whatsapp: [phone]
Email:[email protected]
Web:www.yztchg.com
Introduction ofCationic Reagent(PTAC1881)
I.Production Status
Tiancheng uses DCS automated control system and continuous automated production equipment. The production
capacity ofPTAC is 30,000 tons/year with good quality, high stability.
We established a complete quality control system. We detect products with advanced equipments such as US
Agilent 7890A Gas Chromatograph, Japan Shimadzu LC-10AT LiquidChromatograph, and Switzerland Metrohm
Automatic Potentiometric Titrator to ensure the advancement andreliabilityof production process and product
testing.
II.Properties of Products
Liquid Cationic Reagent is a kind of multi-application fine chemical products. The main chemical composition is
3-Chloro-2-hydroxypropyltrimethylammonium chloride. Molecular Formula is C6H15Cl2NO. Molecular weight
is 188.10. Structural formula is as following:
1). Product Properties Indicators:
2). Product Features
Compared withmost domestic products, our PTAC1881is more stable in quality, higher in purity, and higher
in degree of reaction. In addition, the effective solid content is higher and the degree offrozen crystallinityis
lower.Our PTAC1881isapplicableto use for all seasons.
Compared with the solidreagent, this product is used without preparation or easy to prepare and there is no
water absorption phenomenon. The effective ingredients won’t change during storage and transportation.
3). Application
Reagent can immediately convert to epoxy structure under alkaline conditions and can achieve products
cationization reacted withbasematerial, like starch and guar gum. The polymeride possesses cationic
properties after introduction ofreagentperssad. Thefeaturesare following.
①Increase the adhesive strength;
②Increase affinity for anionic substances;
③Increase the solubility of water-insoluble substances.
Items Specification
Appearance transparent liquid
Content ≥65.00 %
pH 5-7（10%solution）
FreezingCrystallization
Point
≤-10℃
1,3-Dichloro-Propanol ≤10PPM
ECH ≤5 PPM
Solubility
Soluble in water, soluble in lower alcohol, not soluble in
hydrocarbons, ether and other weak polar solvent.

4. 山東兖州天成化工有限公司
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
Material Safety Data Sheet
Section 1：Chemical Product and Company Identification
ProductName 3-Chloro-2-Hydroxypropyltrimethyl Ammonium Chloride
Alias CHPTAC, PTAC, Quat 188,PTAC1881, CTA1881
CASNo. 3327-22-8 HScode 2923900090
Company Yanzhou Tiancheng Chemical Co., Ltd.
Address 66West of Beizhan Rd, Yanzhou,China Zip code 272117
Telephone [phone] Fax [phone]
Mail [email protected]
Section 2:Composition/Information onIngredient
Formula C6H15NO CL2
Section 3: Hazards Identification
Risk Category Non hazardous chemical
Health effect Irritable to eyes,skin and respiratory tracts.
Environmental hazards： No harm
Section 4：First AidMeasures
Skin exposure： Use soap to help assure removal.
Eye contact： Wash with copious quantities of water.
Inhalation： Wash with copious quantities of water and seek medical attention.
Section 5: Fire Fighting Measures
Extinguishing Alcohol-resistant foam, dry chemical,carbon dioxide etc.
Fire fighting procedures
Fire fighters must wear self-contained breathing apparatus, full protective clothing
whenextinguishesfire.Keep the containers cool and prevent rupturewith waterat
the scene.
Conditions to avoid Keep away from fire, strong oxidant, strong acid, strong base etc
HazardousCombustion Products Carbon monoxide, carbon dioxide
Section 6: AccidentalRelease Measures
If the product is not contaminated,putitin a clean container. If the product is contaminated,put itin a container andmake
appropriate disposal. Once accidentalspillsrefer tosection8, personal protective apparatus, and general health habits.
Section 7: Handling and Storage
General Store in shady and dry places, 5-35°C. Tightly close the openingof containersif not used.
Attention
Pay attention to moisture. Avoid storing products in incompatible materials nearby. Refer to section 10.
Away from fire and heat.
Section 8: ExposureControls/Personal Protection
Engineering controls Pay attention to ventilation, airtight operation.
General Health HabitAvoid its contact with eyes, skin and clothing. Eat and drink after thoroughly clean.
Personal Protective ApparatusWear waterproof gloves and proper protective clothing.
Maintenance/Protective measuresCompletely isolate and clean all equipment and pipes before maintenance.
Section 9: Physical and ChemicalProperties
Product Name 3-Chloro-2-Hydroxypropyltrimethyl Ammonium Chloride
Item Description
Appearance Colorless liquid
Active content/ % ≥65.0
DCH content% ≤10×10
-4
ECH content/ % ≤5×10
-4
pHvalue（10%water solution） 5.0-7.0
Section 10: Stability and Reactivity
Decomposition product No
Hazardous PolymerizationNo Hazardous Polymerization underspecified operation and storage.
Stability Stable under specified operation and storage.
Section 11: Toxicological Information
Carcinogenicity National Toxicology Programdoes not classify it as carcinogen, Occupational Safety and Health

5. Administration does not require it as a carcinogen, IARC does not assess itas carcinogen.
Effect onhuman It will not cause skin irritation or skin sensitization after the human patch test.
Effect on animals
Acute toxicity Rat oralLD50：> 5g/k g
Stimulus No
Sub acute No
Chronic toxicity No
Sensitization No
Teratogenicity No
Section 12: Ecological Information
Ecotoxicity No
Enrichment No
Section 13: Waste Disposal Measures
Waste disposal
Recommend to stackin solid or hazardous waste device. Avoid dust hazardsduring disposal and
transportation. Load them intocontainerbeforehandling, exposure and protective measures to
be taken when exposed. To ensurethere is no quantitative restrictions to process bulkor semi-
bulk waste.Comply with federal and local laws.
Section14: Packing and Transformation
Notrestrict toDOT rules
Packing
This product is packed bypolyethylene plastic barrelor polyethylene plastic square box barrel
withnet weight 250kg / barrelor 1000 kg / barrelrespectively.
Transportation Avoid frozen and sunlight during transportation
Storage
Avoid storage at high temperature orbelow freezing.The optimum storage temperatureis 5-
35℃.Compliance with the above conditions,the product is valid for six months since the
production date. If it exceeds the storage period, recheckby indicator; ifthetestresults meet the
standards, itcan still be used.
Section 15:Regulatory Information
Chemical list TSCAis inclusive of the product ingredients
SARA Title Ш—302/304： No harm to health
SARA Title Ш—311&312： No harm to body
SARA Title Ш—313: Not contain any chemical composition ofSARA Title Ш—313provision
CERCLA：
Not contain any hazardous chemical composition under the regulation of Comprehensive
Environmental Response, Compensation and Liability.
RCRA：
Notclassifiedas hazardous chemical by40CFR261.33; No hazardous properties listed
by40CFR261,SubpartC
Section 16: OtherInformation
HMISprobility
Health 0 Min risk
Flammability 1 ECLH
Reactivity 0 Min risk
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 West of Beizhan Road, Yanzhou
Shandong, 272117 P.R. China
Tel: [phone]
Fax: [phone]
Mobile/Whatsapp: [phone]
Email:[email protected]
Web:www.yztchg.com

6. 山東兖州天成化工有限公司
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
LiquidCationic Reagent
(PTAC1881)
(3-Chloro-2-hydroxypropyltrimethyl)ammonium chloride
Instructions
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 West of Beizhan Road, Yanzhou Shandong, 272117 P.R. China
Paper chemicals dept.: [phone]
Rubber&Plasticchemicalsdept.: [phone]
Fax: [phone]
Email:[email protected]
Webe:www.yztchg.com

7. ClCH2 CH2 N CH3CH
OH CH3
CH3
Cl+
LiquidCationicReagent
(PTAC1881)
(3-Chloro-2-hydroxypropyltrimethyl) ammonium chloride
Ⅰ . Product Introduction：
(3-Chloro-2-hydroxypropyltrimethyl) ammoniumchloride isa kindof cationicreagent, belongs toquaternary
ammoniumsalt, which is an importantorganicsynthesis intermediates too.Molecularformula is C6H15NOCL2
andweight is 188.1.Structural formula is the following:
Under the normal temperature,this product is 65% aqueous solution and immediately transforms into epoxy
structurein alkaline conditions.Soit is widely used forcationic modificationofstarch,guar gum,celluloseand
other material.
Ⅱ .Product Performance indicators:
(1)Appearance: colorless and transparent liquid
(2)Active content: ≥65%
(3)1, 3-dichloro-propanol:≤10PPM
(4)Epichlorohydrin: ≤5PPM
(5) PHvalue: 5-7(10% Solution)
(6) Solubility: soluble in water and 2-propanol
Ⅲ .Product Features
Liquid CationicReagent has the following advantages.
(1)Product appearanceiscolorless and transparent liquid,low impurity content, less than 20 ppm
(2)Product qualityisstable for usingadvanced continuous production technology.
(3)Reactionofproductsishigh, up to90% above.
Ⅳ .Scope of Application
Liquid of CationicReagent can be widely used in the following areas.
(1)PapermakingIndustry
As animportantauxiliary agent,PTACis widelyappliedto starch,cellulose,andchitosanchemical
modification. The cationicstarch,whichismodifiedfromraw starch,can be used as the paper's additivesfor
surfacesizingagent,retention and filtration aid, enhancerand so on.

8. Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 West of Beizhan Road, Yanzhou
Shandong, 272117 P.R. China
Tel: [phone]
Fax: [phone]
Mobile/Whatsapp: [phone]
Email:[email protected]
Web:www.yztchg.com
(2)Textile Industry
Thecotton fiber, which ismodified byPTAC, canenhance the dye’s bonding. And cationic starch can be
used as warp sizing agent.
(3)Water Treatment Industry
Theelectronegativesuspended solidsof water react withPTACto getcationic polymer. Asflocculant, it can
bewidely used in the purification of water
(4)Daily Chemical Industry
The cationic guar gumand other chemicals, which are formed byPTACmodification,areallimportantdaily
chemicals.
Ⅴ. . Note
(1) If there is crystal before use(in winter),pls heat and stir todissolve.
(2) If eyescontact, wash with waterfor15minutesandgo to hospital.
(3) Storage conditions:sealed storage in a cool,ventilatedanddry place.
Ⅵ..Packaging specifications
250 kgdrum
1100kg IBC
22MT flexitank

9. 山東兖州天成化工有限公司
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
The Enterprise Criterion of
YanzhouTiancheng Chemical Co.,Ltd.
Q/0882YTC008-2012
LiquidCationicReagent
Published on March 24
th
, 2012 Carried out on April 24
th
, 2012
Published by Yanzhou Tiancheng Chemical Co.,Ltd.

10. Q/0882YTC008-2012
Preface
This standard published firstly on April, 2012
Since the release of this standard is valid for three year from the date of maturity, re-examination.
This standard was issued by Yanzhou Tiancheng Chemical Co., Ltd.
This standard was draftedby Yanzhou Tiancheng ChemicalCo., Ltd.
The main drafters: Zhu Niande,Wang Guidong,Zhang Yinguang.

11. Q/0882YTC008-2012
1
LiquidCationicReagent
1.MainScope
This standard specifies theliquid cationicreagentrequirements,experimental methods,examining rules,
package,symbol,carriage and storage.
This standard applies to liquid cationicreagentobtained from ECH, hydrochloric acid, TMA solution. The
products are widely used in the paper industry, textileindustry, water treatment industry and daily chemical
industry and other industries.
Structure:
2.Referenceddocument
The referenced terms of the following documents are also provisions of this standard. Itssubsequent
amendments (excluding corrigenda)or revised versions do not apply to this standard, but encourage the parties
to reach an agreement in accordance with the standard to use the latest version of these documents.
GB/T191-2000Signs for packaging and transportation
GB/T601-2002Chemical reagents, preparation of standard titration solution
GB/T603-2002Chemical reagents, testing methods and preparations
GB/T6678-2003Thegeneral rules of sampling.
GB/T6680-2003The general rule of liquid sampling.
3.Technical Requirement
Technical Index of liquid CationicReagent shown in Table 1:
LiquidCationicReagent technical requirements:
4.Experimental methods
4.1 Appearance
Fetch 200 ml sample to a colorlessglass beaker, and visual measurement.Liquid cationicreagent is colorless
and clear.
4.2Active matter content
4.2.1 Instruments
One Over Ten-thousand Analytical Balance:
Acid-base burette, 25ml;
Lodineflask, 250ml.
4.2.2Reagents
Sodium hydroxide standard solution: c（NaOH=0.5 mol / L），refer GB/T601Chemical Reagent, preparation
of standard titrationliquorto make up.
Hydrochloric acid standard solution: c（HCl）=0.1 mol / L, refer GB/T603Chemical Reagent, Test
methods used in the preparation of formulations and preparationsto make up.
Items Technical index
Appearance Colorless and clear liquid
Active matter content/% ≥65.0
1,3dichlorhydrin content/% ≤10×10
-4
ECH content/% ≤5×10
-4
PH value 5-7

12. Q/0882YTC008-2012
2
Phenolphthalein indicator：10 g / L, refer GB/T603Chemical Reagent, Test methods used in the
preparation of formulations and preparationsto make up.
4.2.3 Operation steps
1）Blank titration
Weigh 2.6-3.4gcationicreagent sample precisely (exact to 0.0002g). Put it intoan arid iodine flask,
add 60 mldistilled water and three drops phenolphthalein indicator to it, and use 0.1 mol / L sodium
hydroxide standard solution to titrate to reddishcolor.
2）Active content titration
Weigh 1.0-1.1gcationic reagent sample precisely (exact to 0.0002g). Put it into an arid iodine flask,
use pipette to fetch 10 ml0.5 mol / L sodium hydroxide standard solutioninto an iodine flask, add
10 mldistilled water and three drops phenolphthalein indicator to it, seal it off, Shake it evenly
enough,use0.1 mol / L hydrochloric acid standard solution to titrate sample, continue dripping until
the red color vanishes.
4.2.4 Calculation
Active substance content samples, according to formula（1）、（2）:
1 1 2 2( ) 0.1881
100%
c V c V A
X
m
· ·- - ´
= ´ （1）
3 3
C V
A =
W
´
（2）
In the formula:
X——test samples of active substance content;
c1——Concentration ofsodium hydroxide standard solution mol / L;
V1——Volume of the sodium hydroxide standard solution consumed by test sample, ml;
c2——Concentration of hydrochloric acid standard solution, mol/L;
V2——Volume of hydrochloric acid standard solution consumed by test sample, ml;
m——Quality of test sample, g;
C3——Concentration of sodium hydroxide standard solution mol / L;
V3——Consumed Volume of sodium hydroxide standard solution，ml;
0.1881—mass of thereagent in 1 mlhydrochloric acid standard titration liquid[c（HCl）=1.000 mol /
L], g.
4.3 Measurement of ECH content and 1,3-dichloropropanol content
4.3.1Reagent
ECH, HPLC grade;
1, 3-dichloro propyl alcohol,HPLCgrade.
4.3.2Instruments
GC: Rui Hong SP-6800A or other similar instruments.
Detector: FID split/splitless
Capillary column: SE-30 0.35 mm x 30 m x 0.1 µm
4.3.3Operation
1）Confection of standard solution
Use 5 μL micro-injector to fetch 1 μL、2 μL、3 μL、4 μL ECH and injected into 50 mlcolorimetric
cylinder separately, and use the same way to injected into the above 50 ml colorimetric cylinder
separately. Thin up to scale, fully shake, and reserve.
2）Confection of sample
Weighcationic reagent about 40g, put it intodistillation flask and vacuum distillation to near
dryness slowly, collect the liquid slip out, test.
3）Gas chromatography
Chromatographic column: SE-30 0.35 mm x 30 m x 0.1 µm
Carrier gas: nitrogen 0.06MPa;
Hydrogen: 0.06 MPa;

13. Q/0882YTC008-2012
3
Air: 0.15 MPa;
Column pressure: 0.04 MPa;
Oven temperature: 120 ºC;
Sample injector temperature: 200 ºC;
Detector temperature: 200 ºC;
Sample injection volume: 1µl.
4.3.4 Calculation
1）Draw standard curve
Calculate the standard sample solution as ECH, 1, 3-dichloro-propanol thecorresponding peak
area average value, use content as the abscissa, the corresponding peak area as the ordinate. Draw
the standard curve of ECH, 1,3-dichloropropanol separately.
Or application of the calculation method, use content as the abscissa, the corresponding peak area
as the ordinate, calculated the standard curvilinear equation of ECH, 1, 3-dichloropropanol
separately.
1 1
n n
i i
i i
y b x
a y bx
n
= =
-
= = -
å å
（3）
1
2
1
( )( )
( )
n
i i
i
n
i
i
x x y y
b
x x
=
=
- -
=
-
å
å
（4）
Correlation coefficient r:
2
1
2
1
( )
( )
n
i
i
b
n
i
i
y y
r
x x
=
=
-
=
-
å
å
（5）
From（3）、（4）、（5）get the standardcurvilinear equation:
Standard curve of ECH 500 141y x= - + (6)
Standard curve of1, 3-dichloropropanol1999 141y x= + (7)
2）Cubature
Sample mapping processing method with standard solution map processingmethod. From the
sample get ECH, 1,3-dichloro-propanol the corresponding peak area average value, brought into
equation（6）、（7）separately and calculated, from the sample get the content of
ECH,1,3-dichloro-propanol.
4.3.5Standard gas chromatogram
4.4 DeterminepH value
4.4.1 Definition
It also called hydrogen ion concentration index, which is a scale of hydrogen ion activity from solution.
And it usual sense measurement of the solution pH value.
4.4.2 Principle:
Use PHS-25 type acidometer, namely the useof pH combination electrode in solution of different
acidity measured direct current generate by bit, through pre-amplifier transport pH to A/D converter, in
order to achieve the pH value digital display purposes.
4.4.3 Instruments
1）Acidometer, PHS-25 type;
2）Beaker, 250 ml;
3）Wash bottle.
4.4.4 Operating steps:

14. Q/0882YTC008-2012
4
Add 90 mL distilled water into 250 mL beaker, weigh 10 g sample to the beaker (exact to 0.0002 g), stir
with a glass rod, until the sample completely dissolved in distilled water. Refer PHS-25 type acidometer
operating instruction manual to operate and mark. Measure twice; take the average of two measurements
as measured result.
4.4.5 Calculation of measurement results:
Direct readings, is the pH value.
4.4.6Measurement accuracy
The results of twoparallel measurements, the relative error should be less than 1%.
5.Marks, Package, Carriage and Storage.
5.1Marks
Products pail pack should be attached with clear and firm label. Marked: product name, product standard mark,
net content, batch number (or date of manufacture), maker, address and so on. Storage and transportation signs
should be consistent with the relevant provisions of GB/T191
5.2Package
In plastic bucket, 240±0.005 kg net weight per barrel, other options negotiated by both parties.
5.3 Carriage
Product duringtransportshould pay attention to waterproof, freeze-proofing, avoid contact with
open flame, not mix with corrosion, flammable, explosive items; bandiscards during loading andunloading.
5.4Storage
Product should be stored in dry, ventilated, shady and cool storeroom. Keep away from heat and fire, pay
attention to keep warm in winter.
5.5Shelf life
Accord with above conditions,shelf life ofthe productis12months. It can’t be used after shelf life unless it
is qualified after inspection.
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 West of Beizhan Road, Yanzhou
Shandong, 272117 P.R. China
Tel: [phone]
Fax: [phone]
Mobile/Whatsapp: [phone]
Email:[email protected]
Web:www.yztchg.com