Co-ordination Compound Notes PDF Download | उपसहसंयोजी यौगिक | @irfanulllah_mehar.pdf

Co-ordination Compound Notes PDF Download उपसहसंयोजी यौगिक @irfanulllah_mehar.pdf

1. Chemistr
<br>
Notes
o
<br>
IrfanullahMehar
<br>
[email protected]
<br>
Oirfanullah_mehar
<br>
WorldofWisdom
<br>

2. Satt
<br>
Ligand
<br>
Theonies
<br>
Co-ordinatonCnpound
<br>
)
Nosmenelatue
<br>
(sIERIN)fsas)ote
<br>
Jsomeism
<br>
1H0
<br>
AciltBase
<br>
Salt
A(Sett
B)
<br>
VBT
<br>
G)metaCobery
<br>
stasility
<br>
o2l08]2025
<br>
Sot
<br>
Use.
<br>
Dublesal
<br>
Mole
eulasSaet
<br>

3. Double
<br>
Salt
<br>
OR
<br>
K•A](Soy)l2 H50
<br>
(2)
Fe
sOya(NHy),S0-6H,0
<br>
(Gf
<br>
e)
<br>
Co-ovdinationSat
<br>
not
maùtafn40i6
<br>
Maintain
<br>
)Fe(CN),+YKCN
<br>
Fe
(CN):4kCN
<br>
K,[re(cN),]
<br>

4. dener
<br>
ytoroto
<br>
lonepafr
<br>
e
<br>
i)
Deudtey)
<br>
metal
<br>
bseg
(Monodadal
<br>

5. Ialeak
<br>
donate
<br>
land
<br>
4)tetadentate
o
<br>
Donatet
Accept
<br>
8
Hexyclentate
<br>
81E
(Ambidlentate)
<br>
(p)
<br>
Cagenalpetl
<br>
ele.densi
ty
T
<br>
F,
)
Br1
OH,
H,0
<br>
(Backbomlig)
<br>
Metal
<br>
(mCT)
<br>
ele.
<br>
duaity)
<br>

6. CO
,
CN,NO,
en,No2EDT
A
<br>
Lone
paY
<br>
(i)
<br>
ae
<br>
buteansi
<br>
kP+Cla
(CsHy)]
<br>
Lytst
Oyganometalfe
Compouwnd
<br>
+2
<br>

7. Ane
<br>
Ang
<br>
o
TTBondfad
<br>
L
<br>
TTBod
metol
<br>

8. (ii)
<br>
Te
<br>
Non-Aeomatíc
<br>
AgUmatic
<br>
(planes)
<br>
fe
<br>
Aema'e
<br>
Aematfc
<br>
fehocee
<br>

9. (B
<br>
NOTE
<br>
Onthe
<br>
Deut'
<br>
céqsay)
<br>
Chanpe(OS))
<br>
Lemepur
<br>
Manodlentate(uaod-des)egcund
<br>
Lonepaírtaejs Gr.
<br>
momooletate
<br>
Neltra
<br>

10. tvelium)
<br>
ONO
(Nihosil'um)
Hao Aqua
<br>
Brun
<br>
tieo),Nosou
<br>
NH,
<br>
Monodentate
<br>
2
<br>
+2
<br>
NH2
<br>
teát
<br>
(Hydio
zfnium)
<br>
NHg
<br>
(
Penexo)
<br>
(
Superoxo)
<br>
NHy(Avnida)
<br>
NeutraS
<br>
=sCs(thocanbr)
<br>
(
<br>
(Dntdo)
<br>
(Miido)
<br>
a)x
cr(ao/
<br>
co
(Coboy)
<br>
F
<br>
Ng
<br>
(aa)
<br>

11. 15
<br>
(16)
<br>
(
<br>
((9)
<br>
DO
<br>
NO
<br>
-2
<br>
So,2
<br>
CNO
<br>
(210,e)
<br>
Coz2 ea)
<br>
(H63|)
<br>
COO
<br>
(333NAa)
<br>
Bídatate(eeaas)
Le
<br>
(zfarott
<br>
(Oralato)
<br>

12. C00
<br>
L
<br>
(aycine)
<br>
t)Simed
Amínoaeíd
<br>
Ch2
<br>
acoc (efafegÍTEJa)
<br>
Aino
aei
<br>
cOO
<br>
(3031e)
<br>

13. Cha
C-Ch
<br>
Ho)
<br>
Cna
CCHFC-
Cha
<br>
2
<br>
Cn,C=0
<br>
4
<br>
(Baaícpedum)
<br>
CHCN-o
<br>

14. NHyoH
<br>
CH,C=
N
<br>
Cng
<br>
Cn3
<br>
tsbstal
<br>
- N
<br>
1s
<br>
N TRTET5
<br>
(acsn)
<br>
N
<br>
Ivtra
H-Bono
<br>
skRedColew
<br>
denoratom -aRNihrog
<br>
membe)
<br>
1
<br>

15. Tzidentate(fags)
<br>
L
<br>
Cn,CH,NH-
Ch,-Cn,NH
<br>
Pevtotradentte
<br>
Cn,-cn,-NH-Cn,cnVh-Cnh-
nH
<br>
S)
Hexadetate
<br>
6Bono
<br>

16. ex
)EDTA
<br>
-
Cn,
<br>
T
<br>
N
ch,
cH,
Nta
<br>
CH
<br>
XG
donoratom
<br>
EDTA
<br>
-4
<br>
2
<br>
Nc,
<br>
Chyco0
<br>
Peutadenfateea
<br>
Ch,
<br>
PDT
A3
<br>

17. SrÉgsfosg
Ambfalenate
<br>
donor
<br>
but
<br>
NOz
<br>
utom
<br>
mba)
<br>
1st
<br>
fdon
<br>
O-N=0
<br>
donosaton
<br>
donos
<br>
aton
<br>
OR
<br>
eaJ) ()
<br>
<y21)(c)
<br>
Nitito(N)
<br>
Nisto(o)
<br>

18. (CNo
<br>
SCN
<br>
N=C-o
<br>
S=C=N
<br>
-c=N
<br>
OR
<br>
NCS
<br>
SCN
<br>
OR
<br>
(N)
<br>
(s)
<br>

19. s
Nomonclaoo
<br>
LMLG
<br>
netal
<br>
af
Legand
<br>
tat
<br>
0THomolepHfecml
<br>
13
<br>

20. DL
<br>
1elo8)
De5
<br>
Monday
<br>
Nomenclatue
<br>
-Nacl
<br>
Nqcl
<br>
Magnessunchlonde
<br>
CagCDoy)Calo'umphoxphate
<br>
Al(NO3)
2
<br>
NO3
<br>
Ky
Fe(cN).
<br>

21. Name
<br>
osde
<br>
wíth
no.
<br>
afe
<br>
di,hi,
<br>
count
<br>
Coordl'nation
<br>
ea
wondar
<br>
Metal3
<br>
Coordincd
<br>
Neutral
<br>
LI-Ve
<br>
atete)õNà
<br>
43
<br>
oxidatfenGtatr
<br>
Reman
<br>
44V
<br>

22. metu
<br>
Fe
<br>
Co
<br>
Cu
<br>
Ni
<br>
bis
<br>
is
<br>
Tetrakís
<br>
Cepe
<br>
ove with
<br>
humber
<br>
ate
<br>
+Metal+
atet4)
<br>
6latton4
<br>
Qobaltae
<br>
)
<br>

23. Os
<br>
(mn
<br>
Gold
<br>
Cyunfum
<br>
(Agendate)
<br>
Cremate
<br>

24. Metd
<br>
Noo
<br>
K e(CN
),J
<br>
Lre(cN)]
<br>
X=+-3
<br>
X+6(-1)--4
<br>
4x1
tX+6-I=0
<br>
|X=+2)
<br>
Ks[Fe.CN))
<br>
Potasslumhexnsyjauatafea
<br>
OR
<br>
(Fe)
<br>

25. (
<br>
Qnd
Grace
<br>
Possían
<br>
43
<br>
OR
<br>
ntollls
<br>
oR
<br>
9KFefe
CeN),
<br>
OR
<br>
bue
<br>
Bue
<br>
Fe e
(CN),|9
<br>
X+6X-=y
<br>
ormula-
<br>

26. Co(NH),]
<br>
Uaaoe()
<br>
Hexaammínecobalt(n)chloride
<br>
[Co(H,o),(
NHs
),1,(so),
<br>
Thíammdnetiaquacobabd
()
Sutpate
<br>
TCo(Ms0),
(NH,).(saj
<br>
X+eXo
<br>
)3_J
<br>
x+(3xoj+3X6)
=
+3i
<br>
(x+3)
<br>
L
<br>
(c)
<br>
(C.E)
<br>
ony
<br>

27. JJSr
<br>
Co
Cen)a(sou)
<br>
Tris(ethelindammnE)Colsalt(1)Qfhate
<br>
OR
<br>
LCo(H,NM,
CH,
NH),,(s0,
<br>
Ka
[Colox),]npoihunth
<br>
OR
<br>
Petassiunisox
alatocobalt(n)
<br>
(h1)
<br>
K3[Fe(oN),(oNO),(SCN),]
<br>
Postassfum
lyano(e)dintho(o)dthio
cyonoto
<br>
fevat(m)
<br>

28. [Fe
(eN)(oNo),(sCN),
<br>
Xt
2X-1+2(-)
+2
()=-3
<br>
X=
G-3-3)
<br>
o
K
Fe(Nc),(H,0),
Br,
<br>
oR
<br>
aOs
(en)
aBy(OND)NOS(so),
<br>
(v)
bg
<br>
Soy
<br>

29. Shuctue
Tr
<br>
KFe(en),7
<br>
+3+6)
<br>
Neutal'e'
<br>
Co
(hiMS,
),(m9),]
so
<br>
3t0to
X
<br>

30. Tco(NMals(Hs0);so4)
<br>
Speaite
Name
-
<br>
Hexa
chloroplatincacid(iy)
<br>
HAuc4
<br>
Tetrachloroawricacid(n)
<br>
P+
<br>
Aquavagia
<br>
(aaS)/3ne)
<br>
CT
<br>
(HNO,+Hc))
<br>
(higy
eetive)
<br>

31. L
H5]
<br>
GATHRO
<br>
H
<br>
LHlumtetrahydbtdoalunnate(m)
<br>
(Hydeido)
<br>
Lithiumhetrahydido(,H)Alulnate(1))
<br>
H,o
<br>
Lithm
ehahydido(")
Alanínate(11)
<br>
Hqua(o9)
<br>

32. X CocvdinatiomErdity)
<br>
CE,
<br>
Total
<br>
->t
<br>
Fe
<br>
Oxidatlen
<br>
Fe
<br>
o.s.
<br>
2X=
6
<br>
stte
<br>
+3
<br>
Co
<br>
Gr3
<br>
te
&SIT
<br>
Cls
<br>
Metels
<br>
P+,p",
N
<br>
Hexaammnechemíum(I))
HexeGhlerocobaltate
(m)
<br>

33. C
<br>
[P(Ho)1,
<br>
[Co
<br>
(NH,)3,
LCociel
<br>
2
<br>
-3
<br>
Hexaaquaplatlnum()Hexachlorochremat(m)
<br>
P+(M20),.)+rCle
<br>
13
<br>

34. eridge
<br>
Lgtto
<br>
Lagnd
<br>
(NHS)
<br>
Tall
<br>
NH02
<br>
)
<br>
0+x-2-1+X+0=t3
<br>
X=+3
<br>
Co
<br>
2lonepaur
<br>
OR
<br>
metal
<br>
NHa
<br>
Co(Nn)y
<br>
Best
<br>
u-amido
e-
oxo0ctaamincobalt
)chlo
<br>
Cl3
<br>
Ais(tetraaminobalt(u))
chlonde
<br>
tehra
am
ninp,tíchlorocobatte(u)
eammineelorocokale
<br>
te
<br>

35. (NHa)Co
<br>
X
Peroxounduperoxo
<br>
Peroxo
<br>
Petassiuanminetnoo
cobalote(ui)e-cuido
<br>
NH
<br>
Q-OxobiaumnecloooobctateIM)
<br>
i(hu
<br>
Potassíu)
<br>
uperoxo
<br>
OxídationSatedj
<br>
C
<br>
o
KyFe
(NN)ca(o),(o),
<br>
Co
<br>
(NH).
<br>
ammineculori
oxo
<br>
fametal
<br>
(u)
<br>

36. Fe(
NH
a)
c1
(0),
<br>
,
(o.),]
<br>
3+
o
-|-4+
2x=-4
<br>
9x=-4+2=9
<br>
-)
<br>
Superoro
<br>

37. Theones
<br>
1111
<br>
Al}nedaenes
<br>
1stNobel
<br>
o)alener
<br>
they
<br>
()
gee.
<br>
tisima
valoney
<br>
(3)
VB(i)CFT
<br>
(1693)
<br>
ChemstY
<br>
(1913)
<br>
e-
d'a
ceve
<br>
(Valancias)
<br>

38. Pri.
<br>
Co
(NMs).
<br>
(91.fastSAJ
)
<br>
Valancy
<br>
CecrolnatHemty
<br>
ecoValay
<br>
Valanoy
<br>
C.N.6
<br>
(igund-z-ixiga)
<br>
+
<br>
afer
<br>
no
<br>
-2
<br>

39. Lsppr
fiànít(
ioms
fro)
<br>
Hecipitade
<br>
(eleotDotatfc
<br>
dot+eob'ne
<br>
chge
<br>
64'sp²,sp°d
<br>
5sPa'
or
dap²
<br>
Co-oveinatienbond
<br>
atached
<br>
ticlkloaJ<)
ine
<br>
-VeNetrl ve
<br>

40. CoclgtGNH
<br>
Complex
<br>
|Pi.Valany
<br>
2
<br>
2
<br>
Co
(NH)s
lz
<br>
1
<br>
g9
Cornpley
-
<br>
6
<br>
No.
<br>
fons
<br>
3
<br>
AaciPp+
(mole)
<br>
3
<br>

41. (
<br>
P+
CI
t
4NH
<br>
Complex
<br>
Lo+
(NN)sa
<br>
Pi
<br>
N
<br>
1
<br>
Pt
<br>
Cee.
<br>
's-
platn
<br>
3
<br>
Comfle
<br>
SNA
<br>
2
<br>
1
<br>
Auteonces
<br>
Repoatem
<br>

42. wenes
<br>
they
<br>
Co
(NHa)Cla
<br>
Co(NHs)5
Cl
<br>
-
<br>
alanet
<br>
Comglex
Co
(NHa)s C),ae
<br>
Seo
<br>
)Compex
<br>
=2
<br>
6
<br>
12
<br>
Cocvebnatien
<br>

43. Q.51molCr(Hso)Oa
<br>
ar
crplex
<br>
Q.0.1moler(M,O)6cla
<br>
O.1mol
<br>
O.2mol
<br>
O.3nol
<br>
O.0mol
<br>
O3no
<br>
O.6
mo
<br>
mal
<br>
tomula
<br>
O.9
<br>
Calhao),Ca
<br>
AneA
<br>
mol
<br>
(M30),
<br>
(1:2)
<br>
(1:3)
<br>
(1.0)
<br>

44. Qo6)2.665
<br>
Ang
<br>
Q.7
<br>
1mole
<br>
A
<br>
Complex
<br>
r(Ms0).]ca
<br>
Cr(Hs0),d,
mole
<br>
A
<br>
Cmplex
-
A
<br>
mole
<br>
13.5
<br>
Coplex-C-0,25/.
<br>
anpleX-
D-
<br>
Gmm
<br>
9.870
<br>
2.665
<br>
2665
<br>
=o01
mole
<br>
Avs-B|
<br>
Con,
,
SOy
<br>

45. Var Cenplexes
<br>
Aus
<br>
1Ha
<br>
Stuctweg
<br>
=
<br>
266.5
X
G.75
<br>
12.5. 266.5
X
19
5
36
<br>

46. Valance
<br>
veT
<br>
Bond
<br>
Pautig
<br>
Theoy
<br>
eaía)
<br>
f s,p,d
<br>

47. (Hybrjdfeat'm)
<br>
faametie
<br>
arsp(aiy/Lieas)
<br>
CN,=5
<br>
(ayde)
<br>
sp3(tehaheaat)
<br>
dsp
(dx
<br>
dz?
<br>
nes
cbita
<br>
Conplex
<br>
T.B.P
<br>
U
Quctesorbitul
<br>
cmplex
<br>

48. 4)
<br>
Wealk
<br>
lsnh2)
Bm
<br>
EAN
<br>
Camplex
<br>
Metal3d
<br>
Linnd
<br>
e
<br>
i+is
<br>
(eHechve
<br>
(EtoctivAlonfe
Namber)
<br>
alusayspaiv
<br>
C6,CN,No,
,
eh,Nn,
<br>
EDTA
<br>

49. NOTE
G,O
(Oxalato)
<br>
Fe
<br>
Fe
<br>
CN
<br>
Ar)
3
<br>
tWoak but
Fe,
Co,Ni
<br>
Ar]3d4sy7
<br>
shm
<br>
CoN.=6
<br>
ys
<br>
Octhedale
<br>
Janesoritalmpl
<br>

50. NOT
EJly
bridizatiem3)
<br>
Eteotive
<br>
n game
<br>
atonfc
<br>
Ku
(Feco):]
<br>
Stable
<br>
metal
<br>
Aext
<br>
F?ele+2XCN
<br>
tollod
<br>

51. Fet3Y]345
<br>
SrongLignd
<br>
L
<br>
dsp
<br>
CN.6
<br>
Octahealal
<br>
Shnenokitul
complex
<br>
a=l7
32
<br>
)=
<br>
EAN
=
F3t2xC.N
<br>
hottollon
<br>

52. Fet23d
<br>
(fv)FeCHso),]Ca
<br>
H0
weo
<br>
eol
<br>
C.N=
6
<br>
35
<br>
ostahedral
<br>
Outer
asbited
conmplex
<br>
EAN
t
2
<br>
cSutes,
<br>
tolloo
<br>
Qetq
<br>
L
5.92.
<br>

53. =Fet3
<br>
Fet++12.
<br>
N;t
<br>
=23t
12
=
<br>
()(Nicl]
<br>
3d
<br>
Weak astIs
<br>
itis
<br>
C.N.
=
4
<br>
nNettolluo
<br>
UDEAN 26t
834
<br>
ntfollo
<br>

54. 22
<br>
Hug.
<br>
2096
<br>
dsp*n=o
<br>
()Ni(co)]
<br>
(vin)[P+C]
<br>
dsp
,
n=0
<br>
d2
<br>
sp°,
<br>

55. (vi)Co(NH),1*3
<br>
Exceptin
<br>
HN
<br>
arongLgand
<br>
lorel
<br>
(i)
<br>
1
<br>
+2
<br>
quane
planes
<br>
higherone94
<br>

56. (0)
<br>
2
<br>
Co(N)e
<br>
Stasiae
<br>
Stble
<br>
Cot3
<br>
+2.
<br>
aqent)|
<br>
dspi
<br>
is
<br>
notpossikle
<br>
b
<br>
d?sp
<br>
h=0
<br>
theytem
<br>
(oidaion)
<br>
gtakleB:6,co3 Chng
<br>

57. (B
<br>
N;t2
<br>
N -
<br>
Oterobia!
ofo
<br>
+2
<br>
Nt2
=
3d%,
<br>
t2
<br>

58. pairing
<br>
+3
<br>
Shufting
possjhe
<br>
paiingof4910|
<br>
ap³
2
<br>
n2
<br>

59. Q.
<br>
paiing
<br>
asays
<br>
mt2
<br>
pauing
<br>
VBT
<br>
2spb
<br>
X
<br>
-2
<br>
FT
<br>
Anee
<br>

60. EAN
<br>
3)
<br>
notfetlno
<br>

61. LimitatHons
VBT
<br>
1Colou
<br>
Ni2
IOotahedal
<br>
Shng
<br>
Erflain
<br>
4d
<br>
Erplain
<br>
2EAN
<br>
9
<br>
parig
<br>
Explain
<br>
Sxplain
faa
<br>
Gmplexspd2
<br>

62. CFT
<br>
CsyetalFildTheoy
<br>
Haune
<br>
Bethe(as)
<br>
VanVlek(cos)
-
<br>
Metal
<br>
AccordintoCFT
<br>
eRond|()
<br>
1929
<br>
1935
)
<br>
PaintChahge
toy
<br>
bisi
Aectual
<br>
Metal
<br>
Tatl8T100%Coalet
<br>
Actual 70%Covelent
<br>

63. ompex
<br>
onbitala)3Rlg
<br>
tnetal
<br>
A9T
nd
<br>
blR6)
<br>
A
<br>
cbd
<br>
metal
<br>
fanogy
<br>
fa
<br>

64. drydyztzy
dy*d='
<br>
dxydyzzxdvydz
<br>
.jd-orbitale
<br>
GuatOKCrmplex
<br>
Liganda
<br>
|+0.6Ao10D
Y
Ao
<br>
dxydexdzx
<br>
šsEOIE
)
<br>

65. Ligand
<br>
NOTElce-SJ
<br>
Ap=
<br>
E1H)3ch
<br>
r<erksCNcfs(F(oH(Ca0
<br>
NCSKEDTANa
<br>
eg7)
<br>
<encN NO,
co
<br>

66. 3
<br>

67. dbsydyzdex
<br>
+0.4A4
<br>
|-0.6A
<br>
d22
<br>

68. Ao
=
<br>
CFSE
<br>
and
<br>
Release
<br>
etakle
<br>
in
ocaheda
<br>
faureT
<br>

69. Octaheolal
<br>
CFSE=
(-0.y
X
ntg+
<br>
totahedaal
<br>
fauea1fn
octa
<br>
no.
<br>
t0.6xn)
Aohp
<br>
paieal
<br>
(yno
39)]
)
<br>
CFeE 0.6XMe
<br>
pag
neng
<br>
t2)np
<br>

70. 28)0B]
2025
<br>
Squaheflene.eneg
<br>
dyzdzx
<br>
Oeta
hedel
<br>
tetrahedlal
<br>
Asp
<br>
ore
<br>
<odz
(dky
K
dry
<br>
fomulg
<br>
(-0.yx
n,
<br>
+
<br>
-o6xneto.4xnu,)at
hp.
<br>

71. CFT
<br>
Highapin
<br>
(See go))
<br>
Octahodral
<br>
afgoT
<br>
Laospin
<br>
A.>PE
<br>
J4
<br>
kuttetraea
<br>

72. d
<br>
Octahedlal
<br>
electsonfeforaye
<br>
Highapinit
<br>
<br>
Ao<PEnlT
<br>
LnoSpfn
<br>
d tag
<br>
d
<br>
Tetraedial
<br>
d
et
<br>
d3e2
t,I
<br>
JSe2t,3
<br>
et,3
<br>
JG
<br>
Jet
<br>
et
<br>
e4t
<br>
6
<br>

73. Ku
Fe
CcNDe
<br>
C.N
<br>
CfsE
<br>
xn
<br>
CFSE(- OyXn
<br>
Poiing
<br>
Biamgnat'c
<br>
Louo
<br>
-2,4A0
<br>
cetes
=
Deo
<br>
CFSE
)
<br>
-2.
4
Aot3p
<br>
x6
4o.6Xo
Aot3P.
<br>
,O.6
<br>

74. Kare
Fe
<br>
5
<br>
01
592
<br>
CCSE-Zeh
<br>
Ka[ef
<br>
CNG
<br>
scta.
<br>
Fe
<br>
F-
|Ax)345
<br>
Fe(cN)e
<br>
CN=6
<br>
beoals
<br>
1Fe3d
5
<br>
n=.
<br>
F
iweek
<br>
CASE(-Oy
XHagt-0,6
<br>
AtP
<br>
peta,
Lonoepin
<br>
-(-o9
x3+0.6X>]A.
<br>

75. CFSE
<br>
CoN4
<br>
M
<br>
e2
t
<br>
M=1,0e
l732
<br>
--
<br>
3
<br>
5
<br>
db]
e
tdeT
,m,ee,cFSE
<br>
6.92
<br>
(-o6X2+O.y 3)
<br>
2
<br>

76. Ni
(cl4)
<br>
C,N
4
<br>
CFS
<br>
CFSE?
<br>
+etrahedral
<br>
n=2
<br>
(-0o6
X4t
0o
4X4)At3p
<br>
-Oo
&
Att3p
<br>
-0.360Do
<br>
O.8
X
45
Ao
<br>

77. fopcFSE
<br>
tcetacda
<br>
DoPE
<br>
Luo
spin
<br>
t0.6Xng)AotnP
<br>
=-l X150003X12000
<br>
3600
<br>
=t9006
m
<br>

78. brn
<br>
c
(NH).7
<br>
R
(i-0)
N
<br>
Fetl
<br>
Hghapin
<br>
tet
(NO NOg
<br>
d1,(0
wek
<br>
Sxpementally
<br>

79. J
<br>
etal
<br>
)d-seies
<br>
3)dseieef
Os.
<br>
Irwfngwilunorde
<br>
Specho
chemica!
<br>
seles
<br>
)3
<br>
5d>yd>3
<br>
Aspl:3
Ao
<br>
ti)
[Co
(Nn)]
Rh(N,),<()
<br>
<Rnln0)T<(os(s0),
<br>

80. Ao
<br>
ses
<br>
re2
=
3d
<br>
10,b00O
<br>
IreCn0,)*<IFrn,0)]*
<br>
<
<br>
spin
<br>
sCurnve
<br>
PE
<br>
+2
<br>
Fe(H,0),
T*
<br>
Fe3
=
35
<br>
CFSEd
<br>
40.6
<br>
)Aot
<br>

81. (i)
<br>
tim)
<br>
lealk
<br>
wile'un
<br>
L
<br>
2
<br>

82. iv)fua
are
Gncepttheortica
y
<br>
(PSE
<br>
Min.
<br>
ninoaliCuse
<br>
(o)
<br>
CFSE
vN;
<br>

83. *Lijand
<br>
zanele
<br>
OXalate
<br>
NO,
<br>
Ox2
<br>
( H) ieà
<br>
Co>CNNOen>
NN,>EDTA>
NCS>H,0\o
<br>
BelesL
<br>
NCS
<br>
ohonlcal
<br>
sthongiands
<br>
strmg
<br>
butscN,
<br>
j21Oealk
<br>
SeulkUgondbutFe,Co,
nN,
Y.
<br>
hc
<br>
-he
<br>

84. FeCCN)
<br>
CFSE
oy
E
<br>
erceçhon
<br>
[Fe(co),]
<br>
+2
<br>
Subi
<br>
1>3)42)5>6
<br>
CFSE le) stability
<br>
Revese
<br>
roles
<br>
Sameyeg
<br>
42
<br>

85. (4)
<br>
CCN):JT
Teen, fe
(eDTH)
J
<br>
INCFSE
<br>
Stabi
<br>
CFSE
<br>
[P(CN)J
<br>
Tetra
<br>
43
<br>
1>2>3
<br>
2
<br>
CFSE=Sq>Octa>tetrey
<br>
12
<br>
SSqotocahecdaal
<br>

86. Ordey
<br>
(i)
E
<br>
5d4dB
<br>

87. Stuctusal
<br>
Ssomeusm
<br>
L,
Sequence
otRends
<br>
(dT
<br>
)
<br>
Geomehical
<br>
(aTA)
<br>
Bend
<br>
but
<br>
steeo
(orfan)
<br>
Gptfcal
<br>
tyonfres
)
<br>
Planab&ent
<br>
but
<br>

88. ()
BiNTe(Sonization)
<br>
(m)
<br>
os(Linkage)
<br>
isosncsT)
<br>

89. ((i)3NT]HNÖNI
-
<br>
Coruntejnf
<br>
L
<br>
Co(NIHg)5C.BrCempound
<br>
CoCN
Ma)By]
<br>
o
Cocrobnationntiti,
<br>
I1S)
Ry
<br>
9iteppt
<br>
GR
<br>
Co
(NM),Br
<br>
SolM
<br>
Tyelle
<br>
Ppt
<br>

90. Co
(Nn)clso4
<br>
(oite
<br>
yellnoppt
<br>
+
Cemplex,
<br>
PPt
<br>
Co
(Nna)sso,
<br>
Ai-c
<br>
uslite
ppt)
<br>

91. (famsag)
<br>
Hyeathion
iscmewsm
<br>
OR
<br>
oR
<br>
(90a)
<br>
(Linkage'smeem)
<br>
(h,0)5(CN)
<br>
(CN),CNs,
NO)
s)S
<br>

92. Ni(1,0)5(Ncs)7
<br>
(iv)Coordinat'mkomeiism
<br>
CE.
<br>
OR
<br>
OR
<br>
b)
<br>
aR[Ni(,0,lseN)]"
<br>
Exchange
<br>
[cr
(NHs)
<br>
a
<br>
ennE
<br>

93. K
<br>
K
<br>
eclage.
<br>
(vi)Coordi'ntin
<br>
Co
<br>
Pt
NHaCle
<br>
Nn
<br>
Co
<br>
Polymenaadion
<br>
co
ly
<br>
Co
<br>
poymsatonn
<br>
Lipnd
<br>
):2
<br>
p+
'
NIHs
!Cly
<br>
(Nr).
<br>
!2
<br>

94. ,-Ch-Ch,-
NHauehe
<br>
NHCh,Ch,
<br>
n-prop
<br>
LNnaCnCha
<br>

95. (2Steseo
<br>
Guecme
tical
<br>
(ay)
<br>
Bmdange
<br>
chet
<br>
4
ea
hed
<br>
109°28(s)
<br>
oridzaten-
CoN.=
4
<br>
Mytbidisatia
<br>
geometicalné5)
<br>
CeikT)gandGion)-30)
<br>
(1eofs5)
<br>
319
muroT
mage
<br>
(Supeimposed)
<br>
-
planeabsent
<br>
8-plannes
<br>

96. Tchrahedald
<br>
N
CI,Er
<br>
C)
<br>
osbNiF
CI
BsD
<br>
F
<br>
Ni
<br>
eometcal
<br>
-2
<br>
cptfcal
<br>
X
<br>
geD
<br>
Goptical
<br>
N
<br>
By
<br>

97. Squaseplanas
<br>
(
<br>
AB=
<br>
Fosgeomethical
<br>
Mab,
<br>
Optfeclabced
because
<br>
en,)
<br>
Condtme
<br>
Ma,bc
<br>
ox®,
<br>
Mabcdm(AB,.
<br>
bidentateLigandAa
domae
<br>

98. S.
Plane
<br>
m
(AB)bc
<br>
m(AB)
<br>
mabcd
<br>
Ma,
bc
<br>
Ma,
b
<br>
q
b
(180°)
<br>
trwne
<br>
b
<br>
d's
<br>
B
<br>
m
<br>
Cm
<br>
qd
(180)
<br>
b
<br>
G's
<br>
Cis
<br>
b
9o
<br>
s
<br>
m.
<br>
b
<br>
b
<br>
b
<br>
C
<br>
trens
<br>
m
<br>
trans
<br>
frans
(180)
<br>
b=180
<br>
A
<br>
-
<br>
C
<br>
90
<br>
alucays
<br>
m.
<br>

99. ()
<br>
-2
<br>
[Nia,
Br]
<br>
geot
opt,tota
<br>
2
<br>
Ma,
b
+O2
<br>
Lsshong
sq1
planan
<br>
Mabc=3+O=3
<br>
m(AB)b,
=
D+o0
<br>
0O
D
<br>
0+1=2
<br>
2+0
2
<br>
(o,
<br>
To
<br>
2
0
2
<br>
tetrahedral
<br>
tehahedtal
<br>
tetrhearal
<br>
m(A,
<br>

100. Oclahedlaal
<br>
Octahedal
<br>
90=12
<br>
Totadpaaithon-i5):
ma
bede7total
<br>
scme
=
30Srd
<br>
|5
<br>
qeometfoal
<br>
Same
<br>
B
<br>
CN=6 Oetahedal
<br>
D
<br>
-t
30
<br>
7
<br>
opticat
<br>
optlcal
-30
feor
<br>
QE)
<br>
15
<br>
bendanglechange
<br>
plane
<br>
=
isomes
<br>

101. Octaheclsal
<br>
QthedaldtySquore f
AT
<br>
Plane hlos
<br>
OOctahedal
<br>
Squwe
<br>
Opposite
(180°) 21T
<br>
R
<br>
plane
)-
Opticaf
abtent
<br>
egas
Lhand(Monsdentate)
<br>
(i)MaT
<br>
8Squane
fat
<br>
plane
TT
opticalabtent
<br>
m
<br>

102. (iv)
ma,
bc
<br>
b
<br>
b
<br>
ais
<br>
iv)Ma,
bi
<br>
Fac(Faetal)
<br>
la
<br>
C
<br>
Ppticl=
o
<br>
b
<br>
2
<br>

103. sloel215
<br>
CoL.202y
<br>
(vi)
<br>
C
<br>
optfcal
o
<br>
2
<br>
plane
<br>
ba
<br>
alcte
<br>
cís
<br>
5Lyeo)+2Copt.)
=6
<br>
allaetraue
<br>
Lb
<br>

104. VVY.
<br>
(viD
<br>
(
vim)
<br>
Ex
<br>
m(AA)
<br>
A
<br>
m
<br>
A
<br>
m
(DA),ba
<br>
Co
(en),
<br>
A
<br>
2
<br>
+3
<br>
n
OX
<br>
planet but38
<br>
aT
plane
<br>
A
<br>
absent
<br>
(m(AP),bc
<br>
3O
<br>
m
<br>
Ot2
<br>
trane
<br>
A
<br>
tot2+2
3
<br>

105. CT
<br>
(ix)
<br>
A
<br>
B
<br>
b
<br>
m
<br>
A
<br>
trane alwaysslane)s)
<br>
m
(AB)2
<br>
A
<br>
B
<br>
A
<br>
2
+
47
<br>
A
<br>
b
<br>
n
<br>
D
<br>

106. FsBro
<br>
3
<br>
3
<br>
=0
<br>
[CoCen,d]*1
<br>
2+0.
2
<br>
=
2+o2 kac
Mes
<br>
=5t26
<br>
a co
(ox),],ot22
m
(An)
<br>
(o
(en),
o
2t23
<br>
=2t
2
4
<br>
IS+3O=30
<br>

107. QFe(en)H,0CNC
<br>
An
<br>
ii)
<br>
()
<br>
(i)
o
<br>
M
(AA),bc
<br>
3
<br>
,-3
<br>
cs
<br>
Complex
<br>
men
<br>
CN
<br>
Cmplex
<br>
)trewi
<br>
+3
<br>
Fe(o]46)
<br>

108. NOTE)
<br>
Fe(n0)[en),CN
<br>
Metal
<br>
kaeme
<br>
Cnbony (eTg
<br>
Caeng
<br>
Ans)
<br>

109. NOTEO
<br>
Onometallfecomp.
<br>
EAN
<br>
m
6
D.s,
<br>
A-
NCco,]
<br>
aleae
complete
aa
<br>
aben
<br>
NíSd84= 3d0
<br>
Fe
<br>
EAN=28+ 36
<br>
Lowe-ve
<br>
Fe
(co))
nft,
<br>
=
(Ar)
3d4s
<br>
Co
<br>
(MH)+29A:)V
<br>
D
<br>
daps(de')
<br>
EAN26410
a36
<br>

110. 0C
<br>
Cr(co)
<br>
Co
<br>
35
4e
<br>
oa
faias
(3c-2e-
&end)
<br>
CO
<br>
Co
<br>
EAN=u+12
=
3G
<br>
d2sp,
<br>
CO
<br>
Co
<br>
tiy9c-2eleGubony6
<br>

111. 72
<br>
Co,Cco)g-
<br>
EAN
<br>
fe,Cco)
<br>
1Colbat fepg6
<br>
1
<br>
nfeu)
<br>
2Co
<br>
2X27+8X2
<br>
15
4+16
<br>
+8CO
<br>
ele
=
2
<br>
m-m
<br>
=I
m-
m
bm
<br>
2
<br>
metal-metulbenel
8tID
<br>
bene
<br>
6
<br>
2X26+9X2 529
1870
<br>
eAN
<br>

112. OC
<br>
-Fe
<br>
CO
<br>
Mn(co)s
<br>
CO
<br>
maximusmotal
<br>
Fe
<br>
carbrmg 3
<br>
Excepon
type
<br>
T.B,P,Pahumagenetic
<br>

113. EAN=
95
+10
e
<br>
Mna(co),o
<br>
6AN
<br>
2
X25F2X10
0
<br>
Oc
<br>
CO
<br>
co
<br>
foxDmeh
<br>
Suctu
<br>
Qctahedra
<br>

114. PackBondng
<br>
(eE
<br>
Lipond
<br>
met
<br>
ele.
<br>
ín
MetalCanboylCmplrx
<br>
Metal
<br>
TI2p
<br>
OR
<br>
oR
<br>
GeauSinsgfcmechanoun
<br>
Metal
<br>
Lnstle afe
<br>
Propeties
<br>
Caiboinyt,eal
<br>
CO
<br>
dencit
<br>
Catbonl
Cemple
x
<br>
But
<br>
Baek
<br>
RackRmding
<br>
oppte
<br>
Carcbeng
<br>
ele.denety
<br>
ele,
<br>
bemdorole
<br>
-b)d
<br>

115. 2
<br>
Co
<br>
ele.ayns
<br>
ele
<br>
Bone
<br>
TT-Bend
<br>
etal
<br>
2
<br>
metal
<br>
Bond
<br>
ti)mectul
<br>
2P
<br>
TT
2Px
<br>
Bonol
<br>
ele,dunity
<br>
roler
<br>
ole
<br>
Salility
<br>

116. Q.1
<br>
bonelng
<br>
cektt
co
<br>
denety)
<br>
CO
<br>
(7etal
<br>
A(.5
A
<br>
Fe
(co)s
<br>
-2
<br>
Q.r
(co),
<br>
-Co
(Co):J"
<br>
eleo
<br>
bond
ordea
<br>
clhage
<br>
Back
bondi
ng
<br>
.
ele.
<br>
Fe
C
<br>
B.0.
<br>
(elee
<br>
BonaLenh1.5
a°
<br>
(Ane
<br>
tBeekbond
<br>
[maCco),)
[e
Cco)s
<br>

117. 1
<br>
Sol4
<br>
m
4c e.0y23>4)5
<br>
M
C
<br>
Csmple
x
<br>
X
<br>
B.L
<br>
m
<br>
=5)4>3>2)
<br>
B.
L
152>3>4)5
<br>
Stability(anf)
<br>
[m]
<br>
stepwise.
<br>
OT
7Ysimulteneru
<br>
GveullstailityCnston
<br>

118. Steps
<br>
(i)m+L
<br>
(ii)mLt
L
<br>
(m)
m
Lt
<br>
mL
<br>
(i)mktL
my
<br>
K
<br>
6R
<br>
K)
<br>
gm186
<br>
mL
<br>
k_ML
<br>
B Ki.Ka.KsKaky
<br>
m.L
<br>
mls
<br>
Stepojse
Stabilitycoa
<br>
[mL][L
<br>
mLy
<br>

119. B=
K KaKa.k
<br>
MLy
<br>
Ki
<br>
1
<br>
K
<br>
IKy
FeFe
<br>
mly
<br>
(Dn
<br>
(ardpriiy)
<br>
FeCH,o).T-e216'8
<br>

120. ho.
<br>
Fe(CN),
1
=
B3
X
I0
<br>
+2
<br>
m(r,0)t
<br>
=B
<br>
and
<br>
EDTA
<br>
bd
<br>
m[ED)
<br>
Aue-D
<br>
Reattachqnent
alPos&bility
<br>
+GH,0
<br>

121. h
<br>
OH,
<br>
H,D
<br>
i)
<br>
1
bond
<br>
dbnd
<br>
2bomd
<br>
byeak
<br>
)Reattacmet
<br>
ottaclhed
<br>
O,
<br>
Cnengt
<br>
Max
tabi
ity-)
EDTA
<br>
RE)
<br>
Possibilty
<br>

122. Applicaiens
<br>
Bidogical
<br>
+2.
<br>
()Cot3
<br>
Coosolihationampounole
<br>
(ory
deog
<br>
Hahepini
<br>
Vitq
-
B,
<br>
Aieneet
<br>
r)
<br>
laospfn
<br>
O,(wealkliyand)
<br>
i'sease
<br>
-Rg
aunal
<br>
(DNA
ep
ucation
s )
<br>

123. (vi)
<br>
ZH2
Dueulin(5)
Aminoecid
<br>
51
<br>
"safo
Protejn minimum
=
l00Ajno
<br>
acfd+
meleoulasuot
10D00
<br>
(vn)
<br>
HER PB2.ca)
<br>
(denatuybicatn)
<br>
=
<br>
oe
<br>

124. (2)QalitatfveAraysís
<br>
(i)Fes)Test
<br>
Fez
+
lk4(FeCcN)
<br>
(ii)
Fe2
o)
Tes
<br>
FeClat
K3leCcn)]
kFFiton)
<br>
OR
<br>
o
R
<br>
K3
<br>
Tuu'sbullolwe
<br>
dap?n-1up)
<br>

125. ùv)NMg
<br>
Nh
<br>
+
NH
<br>
activesphacieg
<br>
(amg)
<br>
pink
/Re
<br>
H-
b
tna
<br>
(4,N-Mq-o-My
<br>
mone
<br>
mulan'sba
<br>
(Brnwn)
<br>
(-RN)
<br>
memberead)
<br>
fasle
<br>

126. lvi)
<br>
Cen.M,sby
<br>
Sod'umnithoyassae
<br>
Na,
TF?
(cN),NO1s
<br>
No,F
(CN),Nos
<br>
rG
<br>

127. Phagraphy
<br>
Hy
Po
<br>
XXX
<br>

128. IrfanullahMehar12thBio1O0%(2023)
<br>
KuchamanCity
<br>
BIOUGH
<br>

129. WorldofWisdom
<br>
YOURWISDOM
<br>

130. Congratulations!
<br>
You'vereached550,000views
<br>
550,000
<br>
VIEWS
<br>
ACHIEVEDSEPTEMBER 6TH,2025
<br>
WorldofWisdom
<br>
vidlQ
<br>
Sharethisachievement
<br>