DENR [Compatibility Mode] DENR [Compatibility Mode]

DENR

1. RA 6969:
TOWARDS A BETTER
CHEMICAL MANAGEMENT
RA 6969:
TOWARDS A BETTER
CHEMICAL MANAGEMENTCHEMICAL MANAGEMENT
BY
Engr. Jose Joel D. Maleon
Chemical Management Section
CHEMICAL MANAGEMENT
BY
Engr. Jose Joel D. Maleon
Chemical Management Section

2. RISK
TOXICITY
HUMANS and other
living organisms
EXPOSURE
ENVIRONMENT
HEALTH
living organisms
AIR / WATER / SOIL

3. RA 6969
TOXIC SUBSTANCES, HAZARDOUS AND NUCLEAR
WASTE CONTROL ACT OF 1990
•A law designed to respond to the
increasing problems associated
with toxic chemicals and hazardous
and nuclear waste.
•It is an act that mandates control
and management of import,
manufacture, process, distribution,
use, transport, treatment and
disposal of toxic chemicals

4. DEPARTMENT ADMINISTRATIVE ORDER
1992-29
Implementing Rules and Regulation of RA 6969
TITLE I- General Provisions and Administrative
Procedures
TITLE II- Toxic Chemical Substances
TITLE III -Hazardous and Nuclear WasteTITLE III -Hazardous and Nuclear Waste
TITLE IV – Common Provisions
TITILE V- Prohibited Acts and Penalties

5. PICCS
Philippine Inventory of Chemical
and Chemical Substances
SQI
Small Quantity
Importation
DEPARTMENT ADMINISTRATIVE ORDER 1992-29
Implementing Rules and Regulation of RA 6969
Pre-Manufacturing and
Pre-Importation
Notification
PMPIN
PCL
CCO
Priority Chemical List
Chemical Control Order

6. DEPARTMENT ADMINISTRATIVE ORDER
1992-29
Implementing Rules and Regulation of RA 6969
List of all existing substances
Nominated by Industry in 1993
Initial publication in 1995
Final PICCS in database
2000 - 21,000
PICCS
2000 - 21,000
2005 - 24,000
2008 - 44, 200
2009 - 46, 863

7. DEPARTMENT ADMINISTRATIVE ORDER
1992-29
Implementing Rules and Regulation of RA 6969
PMPIN
SQI
“NEW CHEMICALS” , are those which are
not yet listed on the PICCS database.
PMPIN or SQI must be secured prior
importation and use of new chemicals in the
Philippines

8. DEPARTMENT ADMINISTRATIVE ORDER
1992-29
Implementing Rules and Regulation of RA 6969
Chemical Control Order
Prohibits, limit, or regulatethe use, manufacture,
CCO
Prohibits, limit, or regulatethe use, manufacture,
import, export, transport, processing, storage,
possession, and wholesale of those priority
chemicals that DENR determined to be regulated,
phased-out, or banned due to the serious risks
they pose to public health, workplace &
environment.
Required to register with DENR, secure Import
Clearance and submit annual report(production
& management information)

9. DEPARTMENT ADMINISTRATIVE ORDER
1992-29
Implementing Rules and Regulation of RA 6969
CCO
Mercury & Mercury Compounds (DAO 97-38)
Cyanide & Cyanide Compounds (DAO 97-39)
Asbestos (DAO 2000-02)
Ozone Depleting Substances (DAO 2000-18 /
DAO 2004-08)
Polychlorinated Biphenyls (DAO 2004-01)

10. DEPARTMENT ADMINISTRATIVE ORDER
1992-29
Implementing Rules and Regulation of RA 6969
Phase out Phase out
schedule of
PCB

11. CCO
General Requirements Applied to all CCO
◦Registration with DENR and Obtaining Import
Clearance
◦Limitation in Industrial Use
◦Gradual phase-out of import and manufacturing
◦Gradual substitution of the chemical in the ◦Gradual substitution of the chemical in the
manufacturing products
◦Providing exemptions for certain use and
premises

12. CCO
General Requirements Applied to all CCO
◦Annual Report to DENR. All manufacturers,
importers, and industrial users of chemical must
submit an annual report to the DENR that include
the following information:
◦
Cont….Cont….
◦General Information (premise)
◦Production and management information
◦Number and category of employees exposed and
exposure duration
◦Waste generated and storage and disposal
information

13. CCO
General Requirements Applied to all CCO
Cont….Cont….
CLabeling requirements
CStorage requirements
CTreatment and Disposal requirements
CSelf-inspection CSelf-inspection
CReporting and recordkeeping requirements

14. DAO 2005-27 -REVISED
PRIORITY CHEMICAL LIST
PRIORITY CHEMICAL LIST -
•List of existing chemicals that DENR has
determined to potentially pose
unreasonable risk to public health,
workplace and the environment.
•There are 48 chemicals listed on the PCL.

15. DAO 23, Series of 2007
• Authorizes the DENR to prescribe
additional requirements and additional requirements and
establish procedural requirements
for issuance of a PCL Compliance
Certificate.

16. PRIMARY CRITERIA FOR ADDING NEW CHEMICALS FOR PCL
•Persistence
•Bioaccumulation potential
•Toxicity and hazards potential
SECONDARY CRITERIA FOR ADDING NEW CHEMICALS FOR
PCL
•Exposure Potential
•Quantity of Chemicals
manufactured and used.

17. DOCUMENTARY REQUIREMENTS FOR PCL
COMPLIANCE CERTIFICATE APPLICATION
www.emb.gov.ph

18. PRIORITY CHEMICAL LIST
Chemical Abstract
Services No.
Philippine Inventory of Chemicals and
Chemical Substances (PICCS) Name
Chemical Abstract Services (CAS)/
INDEX Name
108-90-7 1,4-CHLOROBENZENE Benzene,chloro-
106-93-4 1,2-DIBROMOETHANE Ethane,1,2-dibromo
95-50-1 0-DICHLOROBENZENE Benzene,1,2-dichloro
106-46-7 1,4-DICHLOROBENZENE Benzene,1,4-dichlro-
107-06-2 1,2-DICHLOROETHANE Ethane, 1,2-dichloro-
122-66-7 1,2 DIPHENYLHYDRAZINE Hydrazobenzene
108-46-3 3-HYDROXYPHENOL 1,3-Benzenediol
7647-18-9 ANTIMONY
PENTACHLORIDE
Antimony chloride
7440-38-2 ARSENIC COMPOUNDS Arsenic
1332-21-4 ASBESTOS* Asbestos
71-43-2 BENZENE Benzene
7440-41-7 BERYLLIUM COMPOUNDS Beryllium
7440-43-9 CADMIUM COMPOUNDS Cadmium
56-23-5 CARBON TETRACHLORIDE**
General Name CHLORINATED ETHERS
General Name CHLOROFLUORO CARBONS**
67-66-3 CHLOROFORM Trichloromethane
76-06-2 CHLOROPICRIN Methane, trichloronitro
18540-29-9 CHROMIUM COMPOUNDS Chromium
57-12-5 CYANIDE COMPOUNDS* Cyanide
64-67-5 DIETHYL SULFATE Sulfuric acid,diethyl ester
106-93-4 ETHYLENE DIBROMIDE 1,2 Dibromoethane

19. PRIORITY CHEMICAL LIST
Chemical Abstract
Services No.
Philippine Inventory of Chemicals and Chemical
Substances (PICCS) Name
Chemical Abstract Services (CAS)/
INDEX Name
75-21-8 ETHYLENE OXIDE Oxirane
111-30-8 GLUTARALDEHYDE Pentanedial
50-00-0 FORMALDEHYDE Formaldehyde
9002-83-9 HALONS** Ether, chlorotrifluoro-homopolymer
118-74-1 HEXACHLOROBENZENE Benzene, hexachloro
67-72-1 HEXACHLOROETHANE Ethane, hexachloro
302-01-2 HYDRAZINE Hydrazine
7439-92-1 LEAD COMPOUNDS Lead
149-30-4 MBT 2(3H)-Benzothiazolethione
594-42-3 MERCAPTAN,
PERCHLOROMETHYL
Methanesulfenyl chloride,
trichloro-
7439-97-6 MERCURY COMPOUNDS* Mercury
74-87-3 METHYL CHLORIDE Methane, chloro
75-09-2 METHYLENECHLORIDE Methylene,dichloro
2385-85-5 MIREX
87-86-5 PENTACHLOROPHENOL Phenol, pentachloro
127-18-4 PERCHLROETHYLENE Ethene,tetrachloro
108-95-2 PHENIC ACID Phenol
75-44-5 PHOSGENE Carbonyl chloride/ Carbonicdichloride
85-44-9 PHTHALIC ANHYDRIDE 1,3 Isobenzofurandione
59536-65-1 POLYBROMINATED BIPHENYLS Fire Master BP6
1336-36-3 POLYCHLORINATED
BIPHENYLS*
1,1-Biphenyl chloroderivatives
1,1,1-TRICHLOROETHANE**
79-01-6 TRICHLOROETHYLENE Ethene,trichloro
TRIBUTYLTIN
7782-49-2 SELENIUM Selenium
75-01-4 VINYL CHLORIDE Chloroethylene

20. WHO ARE COVERED?
•Importers
•Users (Industrial)
•Distributors •Distributors
•Manufacturers

21. DOCUMENTARY REQUIREMENTS FOR PCL
COMPLIANCE CERTIFICATE APPLICATION
•Application form or Letter of Application
•Notarized Annual Report
•MSDS
•DENR ID (Hazardous Waster Generator’s
ID)ID)
•Environmental Compliance Certificate
(ECC)
•Discharge Permit
•Permit to Operate

22. DOCUMENTARY REQUIREMENTS FOR PCL
COMPLIANCE CERTIFICATE APPLICATION
•Operation Process Flow
•Chemical Management Plan
•Contingency Plan
•Photo of storage facility
•Basic knowledge on the use and release •Basic knowledge on the use and release
of the chemical
•Ground water analysis (for User-
Manufacturer)
•Self-Monitoring Report (for User-
Manufacturer)

23. DOCUMENTARY REQUIREMENTS FOR PCL
COMPLIANCE CERTIFICATE APPLICATION
•Summary of Importation (for Importer-
Distributors / Importer-User)
•List of Users and Customers (For
Importer – Distributor)
•Processing fee•Processing fee

24. HANDLING
•Inventory
•Use of PPEs
•Labeling
•Transport
STORAGE
CHEMICAL
MANAGEMENT
ACCOUNTABILITY /
RESPONSIBILITIES
•Management
•Supervisors
•Rank and Files
•Trainors
STORAGE
•Compatibility
•Stacking
•Secondary Containment
•Safety Equipments
MANAGEMENT
PLAN
DISPOSAL
•Method of disposal
•Waste handling
•Waste storage
SUBSTITUTION
PLAN
•Alternatives
•Timelines

25. CHEMICAL MANAGEMENT PLAN
HANDLING
•Personal Protective Equipments
•Labeling

26. CHEMICAL MANAGEMENT PLAN
TRANSPORT
• LOADING PROCEDURE
• PERSONAL PROTECTIVE EQUIPMENT
• EMERGENCY CONTAINMENT
• MSDS
• LABELING

27. HANDLING
•Chemical Identification and
Inventory
CHEMICAL MANAGEMENT PLAN
Internal registration of
chemicals

28. CHEMICAL MANAGEMENT PLAN
STORAGE

29. CHEMICAL MANAGEMENT PLAN
STORAGE

30. CHEMICAL MANAGEMENT PLAN
STORAGE

31. CHEMICAL MANAGEMENT PLAN
DISPOSAL

32. CHEMICAL MANAGEMENT PLAN
SUBSTITUTION PLAN
Gantt Chart for lead free production

33. CONTINGENCY PLAN
Exposure Spills and
leaks
•Inhalation
•Eye contact
•Skin contact
•Ingestion
CONTINGENCY PLAN
Environmental
Contamination
•Information
•Remediation

34. ACCIDENT PREVENTION AND
CONTROL
•Fire Drill
CONTINGENCY PLAN
•Spill
Response Drill

35. ACCIDENT PREVENTION AND
CONTROL
CONTINGENCY PLAN
•Evacuation Drill

36. ACCIDENT PREVENTION AND
CONTROL
•Adequate Emergency Response
Procedure
•Conduct safety drills
CONTINGENCY PLAN
First aid kits
on strategic
areas

37. CONTAMINATION CONTROL
Some companies decontaminate their uniforms on-site to
avoid chemical contamination outside the facility.

38. EDUCATION AND
AWARENESS RAISING
BASIC KNOWLEDGE ON THE USE AND
RELEASE OF THE CHEMICAL
Personnel Training

39. The Certificate contains post
requirements that state on risk
management measures to
protect human health and
environment.
Addresses the potential hazards Addresses the potential hazards
and impacts of PCL chemicals .
The Certificate requires
compliance with the other
applicable policies and
procedures based on national
laws and international treaties.