Die materials and die systems in prosthodontics - Dental
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Dr. Dwij Kothari
Darshan Dental College & Hospital
Definition
Basic properties of die materials
Materials used for making dies
•Gypsum products
•Die stone
•Electroformeddies
•Epoxyresins
•Polyurethane
CONTENTS
•Silicophosphatecement
•Amalgam
•Metalsprayeddies
•Refractorydiematerials
•Flexiblediematerials
Compatibility with impression materials
Comparisons of the various die materials
Cast & die systems
•Working cast with removable die
oStraight dowel and Curved dowel pin
oDi –Loktray
oPindexsystem
oAccutraksystem
•Solid cast with individual die
oDVA model system
oZeisermodel system
Preparation of the die for wax patterns
Review of literature
Summary and conclusion
References
DEFINATION
Die:-Itisthepositivereproductionoftheformof
thepreparedtoothinanysuitablesubstance.
(GPT-8)
Cast :-A life-size likeness of some desired form. It
is formed within or is a material poured into a
matrix or impression of the desired form
(GPT-8)
Dowel pin:-A metal pin used in stone casts to
remove die sections and replace them accurately
in the original position
(GPT-8)
Die spacerAn agent applied to a die to provide
space for the luting agent in the finished casting
(GPT-8)
MATERIALS USED FOR MAKING DIES IN FIXED PARTIAL
PROSTHESIS
1. Gypsum products-Type IV Dental Stone
Type V Dental stone
2. Die stone-Investment combination
3. Electroformed dies-Silver plated
Copperplated
4.Epoxyresins
5.Polyurethane
Gypsum products are available in five forms (ADA
Type I-V)
TypeI-Impressionplaster.
TypeII-Modelplaster.
TypeIII-Dentalstone.
TypeIV-Dentalstonewithhighstrength.
TypeV-Dentalstonewithhighstrengthandhigh
expansion.
CaSO4 • 2H2O CaSO4•½H2O +1½H2O
(Gypsum) (calcium sulphate hemihydrate)
110-130
Degree C
MANUFACTURING PROCESS
Calcination reaction
Gypsum
Heated for partial dehydration
Open air Autoclave
Beta hemihydrate
(type I and II )
Alpha hemihydrate
(type III, IV, V)
Gypsum is ground and subjected to temperature of 110
o
to
120
o
C to drive off the water of crystallisation
Gypsum
110-130 degree C
In autoclave
Boil with 30% CaCl2or MgCl2
Or
0.5 -1% sodium succinate
Alfa hemihydrate
calcium sulfate dihydrate
Setting reactionresults from the hydration of
calcium sulfate hemihydrate:
CaSO4• ½H2O +1½H2O CaSO4 • 2H2O + heat
(3900 cal/gm)
Properties
Type IV Type V
Water powder ratio 0.22-0.24 0.18-0.22
Setting expansion 0.1% 0.1 to 0.3%
Compressive strength 5000psi 7000psi
Advantage of gypsum as die material
Compatibility with all impression materials
Easy to use
Dimensionally stable
Inexpensive
Disadvantage of gypsum dies
Susceptibility to abrasion
Brittle prone to fracture
Methods to increase abrasive resistance
Substitution of colloidal silica for water.
Treat surface with resin (epoxy, acrylic, styrene or
cyanoacrylate)
Impregnating acrylic resin into stone die.
(compressive strength-7,000 psi)
In order to improve the properties of dental stone:
1.Gumarabic.
2.Calciumhydroxidemixture.
3.ResinstrengthenedgypsumproductssuchasResin
Rockwithhighstrengthandlowexpansion
(particularlyforimplantcasts).
4.Incorporationofwettingagentssuchas
lignosulphonatesreducewaterrequirementofa
stoneharder,stronger,densesetstone
CAD Stone is Type 4 die stone formulated
especially for use with CAD/CAM systems. It
has high compressive strength, low expansion,
and an extended working time, enabling the
pouring of multiple impressions.
•PRIMA-
ROCK has
the highest
compressive
strength
(8,000 psi)
of any Whip
Mix die
material.
Compatible with all types of impression
materials. Its high expansion makes it
especially suited for polyvinyl or polyether
impression materials.
Facilitates multiple pours
DIE STONE INVESTMENT COMBINATION
CommercialGypsumBondedMaterials:-
1.Thedivestmentismixedwithcolloidalsilica
liquid.
2.Dieismade&waxpatternisconstructedonit.
3.Thisentireunitisinvestedinmixtureof
divestment&water,therebyeliminatingthe
possibilityofdistortionofpatternonremovalfrom
thedie.
4. When heated to 677ºC,
-Setting expansion –0.9%
-Thermal expansion –0.6%.
5. Not recommended for high fusing alloys.
6. Highly accurate technique for conventional gold alloys
especially intracoronal preparations.
AMALGAM DIES
1.Theyaremadebypackingamalgaminto
impressionmadeofimpressioncompound.
2.Diesmadeofamalgamexhibitsuperiorstrength,
resistancetoabrasion&reproducefinedetails&
sharpmargins.
Properties
Working time –15 min
Setting time _ 1-12 hrs
Shrinkage _ 0.03%-0.3%
Compressive strength –9500-14200psi
Hardness _ 83RHN
Disadvantages
1.Cannot be used with water containing agar and
alginate impression material.
2.Shrinkage on polymerization.
3.Less dimensional stability.
4.Expensive.
5.Prone to trap air in preparation
Philipduke,StevenHaugandCarleAndresexhibitedseveral
physicalpropertiesthatmaybesuperiorfromaclinicalpointofview.
•Theepoxyresinexhibitedmuchbetterdetailreproduction,abrasion
resistance,andtransversestrengththanthegypsummaterials.
•However,itssettingshrinkagecomparedwiththeexpansion
observedwithgypsumdiematerialsmayrequiremodificationsin
techniquetoobtaincastingsthatwillbewelladaptedtothetooth
preparation.
Philip Duke, B.K eith Moore, Steven P. Haug and Carle J. Andres Study of the physical properties of type 4
gypsum, resin-containing, and epoxy die material J Prosthet Dent 2000;83:466-73
Metal sprayed dies
Bismuthalloywithfusingpointof136ºFismeltedby
placingatconstanttemperatureheldat145ºF.Dieis
poured&solidifyat30poundsofpressure.
Advantages :
A metal coated die can be obtained rapidly from
elastomeric impression materials.
Disadvantages :
Alloy is soft, care is needed to prevent abrasion of the
die.
Electro deposition of metals:-
Can produce detailed reproduction up to 30µm.
Have moderately high strength, adequate hardness &
excellent abrasion resistance.
Basic system consists of:-
-An electrolyte solution
-A source of direct current.
-An anode –pure copper
-pure silver
“Metalizing”:-The surface of the impression is coated with a
conductor of electricity such as graphite, copper powder or silver
before it is attached to the cathode lead wire.
COPPERPLATINGORCOPPERFORMEDDIES:
Generaltechnique:
Electrolyteacidsolution of CuSO
4+organic constituents
Coated impression cathode of a plating bath
With an anode of copper.
Surface is rendered conductive particles of copper or
graphite
Dental stone is then cast into plated impression: when stone
has set, the metal covered die can be removed from the
impression.
A current is passed (5-50mamp/cm
2
of cathode is applied for
10-12 hrs)
SILVER FORMED DIES : (SILVER PLATING)
Forsilverplating-Polysulfides&Siliconeimpressionsareused.
Cleaning&dryingtheimpression.
Metalizetheareatobeplatedwithafinesilver
powderbyburnishingitwithasablebrush.
-Variousmetalizingagentsare:-
-Bronzingpowder.
-Aqueoussuspensionofsilverpowder.
-Powderedgraphite.
Insert cathode wire in the border of
impression in the metalized area
Fill preparations & the teeth with
electrolytic solution
Completely submerge the impression in
plating solution. The silver anode immersed
in the solution should be at least equal in
size to the area of the surface to be plated.
Flexible Die Materials:-
-Similar to heavy bodied silicone or polyether impression material.
Use:-
-To make provisional restoration.
-Indirect composite resin inlays or onlays chairside
-Maryland bridges.
Advantage:-
-More rapid setting –10min.
-Ease of removal of provisional restoration.
Douglass Smith, Arun Nayyar, David L. Koth -Fabrication of removable dies using cemented dowel pinsJ
Prosthet Dent: 1992:68:372-4
Whilefabricatingofremovabledies-Douglassused
polyvinylascast,thatmaybeflexedtoremovethe
polymerizedresinfromtheundercutsonadjacentteeth
orfromthedie.
Irreversible hydrocolloid impression
Fill with the fast setting, medium
viscosity polyvinyl impression material
Place the polyvinyl cast into
the pre operative mold
Custom made thermoplastic crown form is filled with auto
polymerizing resin and is seated on the flexible cast.
Thepolyvinylcastisflexedto
removetoothcoloredresinfromthe
undercuts.
Interim restoration on the prepared
tooth
A low viscosity
polyvinyl siloxane
duplicating
material is used to
reproduce dies
Adapt a strip of
putty around the
prepared teeth on
working cast and
dies to limit the flow
of mold material.
Refractory Dies:-
These are made for preparation of all ceramic restorations.
Advantages–Excellentmarginaladaptation
•By applying pressure on
base of tray, master cast is
loosened with duplicating
material intact.
•The master dies removed
from cast and duplicating
material.
•The refractory material is
poured and vibrated in
the area of missing dies.
•Allow the refractory
dies set for about 1-2
hours.
Technical considerations of refractory die material
•Recommendedpowderliquidratiomustbefollowed
sinceitmaycauseuncontrolledexpansionor,shrinkage
duringsettingandpossiblyaweakeneddie.
•Waxburnoutfurnace–upto700°Cfordegassingto
eliminatesulfurandammoniagasesandthenceramic
furnace–upto1080°Cinvacuum.
•Cooled down at room temperature
•Applicationofdiesealant
i.e.Applicationof2thinwashofhalfglaze,halfdentin
porcelaintopreventporousdiematerialtoabsorbwater
fromporcelain&fire.
Compatibility with impression materials:
Dentalstone -Impressioncompound
-Zincoxideeugenol
-Alginate
-Impressionplasterwhen
usedwithseparator
-Rubberbasematerial
Electroplated Cu -Impression compound
Electroplated silver -Polysulphide
-Rubber base material
Epoxy Resin -Rubber base material
Comparisons:
If a release agent is not needed on the surface of the impression,
epoxy dies reproduce detail the best(10µm)
Followed by silver plated dies (30µm)
Then the stone dies (170µm)
However a polysulphideimpression requires the use of a release
agent with epoxy dies and their reproduction of detail is
comparable to that of the stone die
Silver plated dies have superior resistance to abrasion , epoxy
dies have good resistance and stone dies have the least
Materials Advantages Disadvantage Use Precaution
ADA TYPE 4
stone
•Dimensional
accuracy
•Straight
forward
technique
•Low cost
Low abrasion
resistance
Most
situations
Accurate
proportioning
essential
ADA TYPE 5
stone
•Straight
forward
technique
•Low cost
•Improved
strength than
type4
Increased
expansion
Most
situations
Accurate
proportioning
essential
Materials Advantages Disadvantage Use Precaution
ElectroplatingHigh strength
Good abrasion
resistance
•Time
consuming
Complete
ceramic
crowns
•Silver uses
toxic cyanide
•Incompatible
with many
impression
materials
Epoxy resin•High strength
•Good abrasion
resistance
•Polymerization
shrinkage
•Time
consuming
complex
procedure
Complete
ceramic
crowns
Not
compatible
with
polysulfide
and
hydrocolloid
Die Hardener
Materials applied on the surface of die to
increase the surface hardness.
Should have low viscosity
Commonly used materials as die
hardeners:
Cyanoacrylate resins (Eg: Premabond)
Acrylic resin lacquer (Eg: Die Prep die hardener)
Appliedtofinishlineareaofthedietoprevent
abrasionbywaxinginstrumentsduringthefabrication
ofwaxpattern
AppliedwithbrushorPKTinstrumentno1.
Quicklyblownoffanddriedfromabovethemargin
towardthecervicalarea.
or
Blotwithtissue
OptimalThickness2-3microm,butifnotproperly
manipulated10microm(JPD1991;65;713)
Airblowingorblottingtheexcesswithtissue,decreases
thefilmthicknessofdiehardenerto1microm
HisaoF Effectiveness of hardening films on die stones. JPD 1980;44;57.
Lacy AM et al (JPD1980:44:356) concluded that
Cyanoacrylateresinsandresinousdiehardeners
effectivelyimprovedthehardnessandabrasionresistance
ofstonedies.
Applicationofliquidresinsfollowedbyblottingand/or
blowingwithcompressedairproducedanimproved
surfacewithoutclinicallysignificantdimensionalchange.
Theextentoffilmbuildupwasqualitativelyrelatedtothe
viscosityoftheresin.
PaulE.Harrisetal(JPD2004;92;35)comparedthe
surfacemicro-hardnessoftypeIVandtypeVgypsum
materialswithandwithoutsurfacediehardeners
(Premabond910&Clearcoat).Theyconcludedthatdie
hardenersevaluateddidnotincreasethesurfacehardnessof
gypsummaterials,buttheyactuallydecreasedthesurface
hardness.
Paul E. Harris Alteration of surface hardness with die hardener. JPD 2004:92;35.
Die Spacer :-
An agent applied to a die to provide space for the
luting agent in the finished casting.
Types of die spacers:
Resins
Paint or liquids
Model paint
Coloured nail polish
Thermoplastic resins dissolved in volatile solvents.
PEEL-AWAY DIE SPACER
Following crown fabrication easily removed and a
final check for fit is made on the original clean die.
25 microns of space.
Advantage:
Eliminates see-through of undesirable die spacer color
under all ceramic crowns
Allows true verification of fit to the original die form
Die Spacer Pens (Kerr Laboratory)
Poly fiber disposable tip.
die lub
Die Separator
The lubricants or die separators which can be used to
prevent wax from adhering to stone are oils, liquid soap,
detergents and a number of commercially available
preparations.
Die Separator
Easy removal of wax pattern
without damaging margins.
Applied with brush
Excess to be removed with
tissue paper
Eg: Kleenlube (Kerr)
Picosep(Renfert)
Dielubewax sep(DenteconInc.)
Cast & Die
Systems
CONTENTS
Die systems
Working cast with separate die
Working cast with removable die
Conventional dowel pin system
Di-lok
Pindex
DVA
Belle de st. Claire
Zeiser
Accu-trac system
Mono trac
Working cast with separate die
Simplestmethodof
fabrication
Advantages:
Easytofabricate
Keepsrelationbetween
abutmentsfixed
Bettercontoursand
emergenceprofilewhile
waxpatternfabrication.
Procedure:-
Both working cast and sectional die can be obtained by:
-Pouring impression twice
-Making two impressions
Preparation of separate die
Stoneaddedtoside
ofimpressioninsmall
increments
Traytiltedtofillthe
Impressiondisplacing
airasitmoves
Addstoneinsmall
increments
Iflargeamountofstone
droppedintopreparation
or
Iftwosizablemassesof
stonemeet
Airtrappedvoids
•Build to height of approx 1 inch
Pour stone to receive
working cast
Make base
Retrieve cast
Trim sectional cast
Octagonal in shape
Sidesparallel or slightly
taper towards base
Handle1 inch long
Pear shaped acrylic bur
trimmed apical to finish line
Final trimmingsharp blade
Smoothened
WORKING CAST WITH REMOVABLE DIE
Advantage:
Convenienttouse
Variousdrawbackofseparatedieare
overcome
Disadvantage:
Riskofintroducingerrorinthe
patternifdiedoesnotseataccurately
intheworkingcast
Requirements:
1) Dies must return to their exact original position
2) Dies must remain stable even when inverted
3) Cast containing dies must be easy to mount on an
articulator
Systems using die pins
Methodsofrepositioningdie
initsworkingcast
Systemsusingpreformed
plastictrayswithoutdiepins
Pre pour techniquePost pour technique
Devicesareoriented
intheimpression
beforeitispoured
Attachedtotheunderside
ofthecastthathasalready
beenpoured
Systems using die pins
Conventional dowel pin systems
Dowelpin(GPT8):ametalpinusedinstone
caststoremovediesectionsandreplacethem
accuratelyintheoriginalposition
Straight Curved
Straight dowel pin
Flat sided
dowel
Double straight
dowel with
common head
(Bi pin)
Rounded single
dowel pin
BI-PIN with case
BI-FIXED-pin
Doublesstraightdowel
withfixingwirefor
accuratepositioning
inimpression
Procedure
(Pre pour technique)
Marking to act as
guide in placement
of pins
Positioning of dowel pins
A)
Mann paralleling instrument
Clamps holding
Dowel pins
(33)
C)
•Disposable anesthetic needles
D) Straight pins with modeling clay
E) Matchsticks (JPD 1975;34;467)
Drawverticalparallellines
toindicatecommonpath
ofremovalofalldie
segments.
Draw broken lines dividing into half
Orientation grooves
Di lok tray system
(Di –Equi Dental products Co)
Snap apart plastic tray with internal orienting
grooves and notches to reassemble the working
cast and die.
Before usingcheck for space in articulator
Cast poured1inch height
No stone in lingual area
Trim to fit Di lok tray
Horizontal grooves
Fill tray ¾ with stone
Seat the cast cervical area
of teeth be about 4mm above
the edge of tray
Disassemble the tray
Cut till ¾ length
PINDEX SYSTEM
(Coltene / Whaledent)
Light beam
director
Drill hole
Work table
Handle bar
Motor housing
Bottom should be flat to ensure
that the Pins will be parallel Faciolingual width –20 mm
Two pins for each die
Two for each pontic area
One /Two pins in each
terminal segment
containing unprepared
teeth
Shorter pins on lingual side
Longer on buccal sidemakes the ends of the dowel
pins more accessible for easy removal after the casts
are mounted.
Strip of utility wax along ends of
long pins
Ball of wax on isolated pins on
contralateral side
Ends of shorter sleeves place wax
Pinned cast can be removed from base in one piece
sectioning of cast from underside.
(limited interdental spacepossibility of damaging
finish line.
DVA System
Pre manufactured base system
Two tapered round brass pins per die -7mm
Impression on alignment fixture
Secured with putty
Marking dowel pin locations
On clear plate with twin tip
marker
Drill holes for dowel pins
Using drilling press
Insert dowel pins
Impression is poured and stone
is placed around dowel pin
Alignment fixture is replaced over
poured impression
Set cast is removed from
baseplate with gentle tapping
Cast is trimmed
Cast is sectioned Definitive cast trimmed with
DVA model system
Zeiser model system
(Girrbach dental Gmbh, Germany)
(14,17)
Impression leveled, blocked out
with silicone putty
positioned over the base
Pin locations determined Pin holes drilled in base
Pins inserted into base Impression is poured
Base inverted The cast is separated
from the impression
Belle de st.claire
Round slightly tapered S.S. dowel pins15 mm long
Flatsurfaceandplasticindexerpositivelock
retentionandanti-rotationalFeature.
Holespindexsystemwithdrillavailablewith
thesystem
Plastic indexers
Accu-Trac Die Precision System
-
(Coltène Whaledent)
(14,17)
Place the impression on the
precision base and adjust,
so that it is centered and
horizontal.
Place die stone in the
impression and in the
base of tray
Open the retaining
arms to remove the
model
Monotrac Articulation
Vertical single pour base (VSP)
Pour stone
Spray silicone spray on VSP
Cones.
Separator on stone
Trim impression –fit the
base molds
Pin –act as guide for placement
Remove base mold
and impression
VSP base removed by tapping
Sectional impression
Dies for CAD CAM systems
CEREC SYSTEM
(Sirona Dental System,
Germany)
Intraoral camera to take optical impression of the
preparation
Preparation covered with opaque powder
( Titanium dioxide)
Image as
viewed on monitor
Cavity outlines are identified for
formation of future restoration
Cerec milling unit
Procera all ceram system
(Nobel Biocare)
Scanning of the die
Scanner probe with a
ball tip
Light pressure of about
20 gms
Elevated by 200 micro meter
Displayed image
Spacer thickness programmed designing of the restoration
done
1. No guide left for axial contours
Overcontouringtissue impengement
and poor accessibility for oral hygiene
plaque buildupInflammation
Undercontouringunesthetic opening of
interproximal spaces
2. No proper emergence profile
TECHNIQUE
Elastomeric impression of
untrimmed cast made
Pink polysiloxane material
(Gi-mask,Coltene)placed
in putty index
Impression with silicone
material placed on the
working cast
Cast with soft tissue mask
REVIEW OF LITERATURE
Gerald T Nomura et al J Prosthet Dent 1980:44:1:45
evaluated the accuracy, fit, detail registration and Knoop
hardness of 3 commercially available resin die systems
•The control used was improved stone
•Impressions were made of each MOD and complete
crown preparation
•A total of 80 dies were obtained
•40 die registrations were also made , 10 of each material
•4 dentists were selected to see the master castings on
each die and to evaluate it as fit or non fit
Thefitofeachcastingwasconfirmedbyseatingitonthedie
uponwhichthewaxpatternwasmade
Theauthorconcludedthat
1.Completecrownepoxyresindiesareundersized
2.MODonlayepoxyresindiesareaccurate
3.Detailduplicationofepoxyresindiesiscomparabletodie
stone
4.Hardnessvaluesofepoxyresinarelessthanthoseofstone
E. Ricardo Schwedhelmet al J ProsthetDent 1997;78:554-9
Study evaluated the fracture resistance of 4 die stone materials at
different time intervals.
Additional silicone impressions were made of a maxillary master
cast.
Two Type V, one Type IV die stones and one Type IV resin
reinforced stone were tested. A total of 80 casts were prepared,
separated, and tested on the InstronUniversal Testing Machine at
1/2, 1, 12, and 24 hours to measure resistance to fracture.
Significant differences to fracture resistance of the different die
stone materials were observed at all time intervals except at 24
hours. Type IV resin gypsum product was the only material that
really benefits by waiting 24 hours for the cast to set.
Conclusion: It is recommended to wait at least 12 to 24
hours when separating casts from impressions to avoid
casts from fracturing.
It is possible that residual moisture in the stone cast
may be concentrated near the preparation and may
affect the strength of die stone.
Lawrence G. BreaultetalJ Prosthod1998;7:13-16 conducted a
study were in Substitution of a 5.23% solution of sodium
hypochlorite in place of 10% of the gauging water when mixing a
Type V stone.
Conclusion: resulted in an increased compressive strength and
rigidity and a decrease in setting time. There was no change in
tensile strength, setting expansion, hardness, or detail
reproduction.
Incorporation of sodium hypochlorite in the gauging water may
be an effective, convenient, and inexpensive method of
disinfecting gypsum casts in the laboratory without adversely
effecting physical and mechanical properties. However, there
may be a reaction between sodium hypochlorite and base metal
alloys.
Alvin G. Wee, C. Cheng and Ryan N. conducted a study to
check an accuracy of 3 conceptually different die systems
used for implant casts.
3 different die systems tested: double-pour (Pindex),
plastic base (DVA), and die tray (KO Tray)
They concluded that the use of a double-pour or plastic
base die system is recommended when sectioned dies are
needed for a multi-implant–retained prosthesis
Alvin G. Wee, C. Cheng and Ryan N. Accuracy of 3 conceptually different die systems used for
implant casts J Prosthet Dent 2002;87:23-9
C, Douglass Smith, Arun Nayyar, David L. Koth-Fabrication of
removable dies using cemented dowel pinsJ Prosthet Dent:
1992:68:372-4
Alvin G. Wee A nsgar C.Cheng, andRyan N. Eskridge-accuracy
of 3 conceptually different die systems used for implant casts J
Prosthet Dent 2002;87:23-9
Michael A. Mansueto and Rodney D. Phoenix -A
Comprehensive Approach to Die Trimming J Prosthod
1994;3:251-255