Energy transformations Fuels contain energy in the chemical bonds. When chemical reactions occur energy can be transformed from one form to another. Energy efficiency – measure of the % of energy converted into useful energy
Electricity production Electricity from coal – 35% efficient due to heat loss when burning fuel C(s) + O 2(g) CO 2(g) Δ H = -32kJ g -1
Electricity production Electricity from natural gas CH 4(g) + 2O 2(g) 2H 2 O (l) + CO 2(g) Δ H = -55.6kJg -1 Approx 40% efficient Fewer particulate emissions Less CO 2 per unit of energy
Electricity production Electricity from Biogas – works the same way as natural gas but biogas has less energy released as it has a smaller % of methane in the fuel Often found in small scale generators instead of large power plants
Fuel for transport Most fuel for transport is derived from crude oil Liquid petroleum gas – LPG Petrol Kerosene Petrodiesel
Petrol Petrol is s mixture of hydrocarbons including octane C 8 H 18 (l) + 25/2 O 2 (g) 8CO 2 (g) + 9 H 2 O (l) Δ H = -2450 kJ mol -1 or 47.8 kJg -1 Efficiency is approx. 25%
LPG LPG is s mixture of hydrocarbons including propane C 3 H 8 (g) + 5 O 2 (g) 3CO 2 (g) + 4 H 2 O (l) Δ H = -2220 kJ mol -1 or 50.5 kJg -1 Conversion to use LPG is expensive and the canister to store it under pressure takes up space
Bioethanol Ethanol can be blended in cars to make up to 10% of the petrol (E10) C 2 H 5 OH (l) + 3O 2 (g) 2CO 2 (g) + 3H 2 O (g) Δ H = -1367 kJmol -1 or 29.7 kJg -1 Energy content is approx. 62% of petrol so a larger mass or greater volume of fuel is needed to provide the same energy
Environmental impact Emissions from fuel combustion Other emissions Environmental impact of sourcing fuels