Sri Chaitanya IIT Academy.A.P. 4 :: IIT JEE 2011 Paper - I ::
Sri Chaitanya “IIT” Academy, Plot No 512, Ayyappa Society, Madhapur, Hyderabad - 500081
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Sri Chaitanya IIT Academy
6.Geometrical shapes of the complexes formed by the reaction of Ni
2+
with ,Cl CN
and
H
2
O, respectively, are
a) octahedral, tetrahedral and square planar
b) tetrahedral, square planar and octahedral
c) square planar, tetrahedral and octahedral
d) octahedral, square planr and octahedral
Ans: B
Sol:
2 8 3
4
[ ]NiCl d Sp Tetrahedral
2 8 2
4
[ ]NiCN d dsp Square planar
2 8 3 2
26
[ ]Ni H O d sp d Octahedral Shape
7.Bombardement of aluminum by particle leads to its artifical disintegration in two ways,
(i) and (II) as shown. Products X, Y and Z respectively are,
30
14Si Z
30
15P Y
27
13Al
(ii)
30
14
Si X
(i)
a) proton, neutron, positron
b) neutron, positron, proton
c) proton, positron, neutron
d) positron, proton, neutro
Ans: A
Sol:
1
1
X= H,
1
0
Y= n,
0
+1
Z= e