The IAPD Plastics Primer, Module 2 Understanding the Basics of Plastic Materials and the IAPD Thermoplastics Rectangle Prepared by the IAPD Education Committee (Module 2) Presented courtesy of Modern Plastics, Inc.
The IAPD Plastics Primer, Module 2
The IAPD Plastics Primer, Module 2 Definitions Thermoplastic Thermoset
The IAPD Plastics Primer, Module 2 Types of Thermoplastics Imidized materials Amorphous plastics High performance Engineering Commodity Semi-crystalline plastics High performance Engineering Commodity
The IAPD Plastics Primer, Module 2 Amorphous vs. Crystalline Thermoplastics Amorphous (a-morphous = without shape) - The polymer chains are in random arrangement. Molecular structure is incapable of forming regular order (crystallizing) with molecules or portions of molecules regularly stacked in crystal-like fashion. Molecular arrangement is randomly twisted, kinked and coiled. Crystalline - The polymer chains form a regular pattern. Molecular structure forms regular order (crystals) with molecules or portions of molecules regularly stacked in crystal-like fashion. Molecular arrangement is arranged in an ordered fashion.
The IAPD Plastics Primer, Module 2 Amorphous Commodity Thermoplastics Key Characteristics Low cost, temperature resistance and strength Good dimensional stability Bonds well Typically, but not always, transparent
The IAPD Plastics Primer, Module 2 Amorphous Engineering Thermoplastics Key Characteristics Moderate cost Moderate temperature resistance Moderate strength Good to excellent impact resistance Good dimensional stability Not true in all cases: Translucency
The IAPD Plastics Primer, Module 2 Amorphous High Performance Thermoplastics Key Characteristics High cost High temperature High strength and good stiffness Good chemical resistance Transparency Hot water and steam resistance
The IAPD Plastics Primer, Module 2 Amorphous High Performance Thermoplastics Materials Polysulfone (PS) Polyetherimide (PEI) Polyethersulfone (PES) Polyarylsulfone (PAS)
The IAPD Plastics Primer, Module 2 Semi-Crystalline Commodity Thermoplastics Key Characteristics Low cost, temperature resistance and strength Excellent chemical resistance Low COF Near zero moisture absorption Very good electrical properties Good toughness
The IAPD Plastics Primer, Module 2 Semi-Crystalline Commodity Thermoplastics Materials Polyethylene (PE) High Density Polyethylene (HDPE) Low Density Polyethylene (LDPE) Polypropylene (PP) Polymethylpentene (PMP)
The IAPD Plastics Primer, Module 2 Semi-Crystalline Engineering Thermoplastics Key Characteristics Moderate cost, temperature resistance and strength Good chemical resistance Good bearing and wear properties Low COF Difficult to bond
The IAPD Plastics Primer, Module 2 Semi-Crystalline Engineering Thermoplastics Materials Nylon (PA) Acetal (POM) Polyethylene Terepthalate (PET) Polybutylene Terepthalate (PBT) Ultra High Molecular Weight Polyethylene (UHMW-PE)
The IAPD Plastics Primer, Module 2 Semi-Crystalline High Performance Thermoplastics Key Characteristics Temperature resistance Good electrical properties and toughness Outstanding chemical resistance Low coefficient of friction (COF) High cost
The IAPD Plastics Primer, Module 2 Imidized Materials Key Characteristics Very high cost per pound Excellent properties above 204°C/400° F Excellent electrical properties Excellent dimensional stability Low coefficient of friction (COF) Very low thermal expansion Good wear characteristics
The IAPD Plastics Primer, Module 2 Imidized Materials Materials Polyimide (PI) Polyamide-imide (PAI) Polybenzimidazole (PBI)