Pva

nashton 10,421 views 12 slides Oct 20, 2010
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POLYVINYL ALCOHOL
(POLYETHENOL)
By Manjot, Dilpreet and Benjamin
IUPAC name: poly(l-hydroxyethylene)
(C2 H4 O)n

General information
Polyethenol also known as Polyvinyl Alcohol is
generally known as PVA. It is most commonly used
in adhesive products and for making other
polymers.
Monomer
Polymer
Polyethenol Polymer
O
O O O O

Production
Unlike many vinyl polymers, Polyvinyl Alcohol
is not made via polymerization of the
corresponding monomer.
HydrolysisMethyl
Alcohol+
Vinyl
Alcohol
--------------->
Polyvinyl
Alcohol

Bonding Within Material
The relatively simple molecules of
this material bond using covalent
bonds and hydrogen interactions.
The mixture of these two bonds in
this material give it a relatively
high melting point of 230 °C and
also a relatively high boiling point
as a lot of energy is required to
overcome the large quantity of
bonds within this material.
- Intermolecular bond dissociation
enthalpy: 2366kJ/mol
- Hydrogen bond dissociation
enthalpy: 23kJ/mol
-
-

Other Physical Data
Relative Molecular Mass: 44g/mol
Flash Point: 79.44°c
Specific Gravity: 1.19-1.31
Density: 1.19-1.31 g/cm³
Solubility: Soluble In Cold Water, Hot Water
The material is pretty inert. It is not harmful, does
not react very much/easily and can be contained
with ease.

Some Uses of PVA
Polyvinyl alcohol has excellent film forming,
emulsifying, and adhesive properties.
It is resistant to oil, grease and solvent.
PVA is fully degradable and is a quick dissolver
Used in water transfer printing process
Used in eye drops and hard contact lens solution as
a lubricant
PVA fiber, as reinforcement in concrete

Explanations of Applications
Polyvinyl alcohol is used in eye drops because,
when eyes become dry due to a reduced
production of mucin by the conjunctiva, it reduces
the surface tension of the tears and also has similar
properties to the mucin.

Explanations of Applications 2
It is also used a water soluble film, the degradation of PVOH
is influenced by its crystalline structure and molecular weight.
The Hydrogens present in the Polyvinyl alcohol have a delta
plus charge meaning the delta minus charge on the oxygen
atom in a molecule of water will attract the delta positive
charge and will surround the hydrogen an cause the film to
break down.

Explanations of Applications 3
Polyvinyl alcohol is also used in PET bottles as a
carbon layer, because it helps the bottle when
thrown away, to degrade which means less rubbish
to deal with.

Explanations of Applications 4
When PVA is added to a Borax a bond between
the oxygen of the borax and the hydrogen of the
PVA forms (a hydrogen bond) this new formation
links the two substances together, forming a slime.
The slime is vicious because the hydrogen bonds let
the molecules slide over each other but the covalent
bonds within the molecules holds the solid together.

THANKS FOR VIEWING

Sources
http://www.jtbaker.com/msds/englishhtml/P5282.htm
http://en.wikipedia.org/wiki/Polyvinyl_alcohol
http://www.druginfo.co.kr/drugimg/30059.gif
http://www.lddiscounts.co.uk/images/products/PVA-980ml.jpg
http://www.solufilm.com/images/solufilm/high50.jpg
http://en.wikipedia.org/wiki/File:Lilit.jpg
http://en.wikipedia.org/wiki/File:Contactlenzen_Confortissimo.JPG
http://www.netdoctor.co.uk/eyes/medicines/100001515.html
http://www.adhesivesmag.com/Articles/Feature_Article/BNP_GUID_9-5-2006_A_10000000000000112679
http://www.articlesbase.com/online-business-articles/plastic-moulded-bodieshard-candies-in-innovative-plastic-moulds-1758253.html
http://en.wikipedia.org/wiki/Polyethylene_terephthalate
http://www.practicalchemistry.org/experiments/pva-polymer-slime,153,EX.html
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