REACTION INTERMEDIATE NET PYQ_c6226316-d373-4760-851c-0d8a9f908155.pdf

TecnoQB7 89 views 73 slides Jul 08, 2024
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About This Presentation

CSIR-NET PREVIOUS YEAR SOLUTION
(Reaction Intermediate)


Slide Content

CSIR-NET PREVIOUS YEAR SOLUTION
(Reaction Intermediate)
1. The correct order of the carbocation's A –C is. [NET –2020]

2. The major product formed in the following reaction is[NET –2020]

3. The major product formed in the following reaction is[DEC –2019]

4. The major product formed in the following reaction is[DEC –2019]

5. The major product formed in the following reaction is[DEC –2019]

6. The major product formed in the following reaction is[DEC –2019]

7. The major product formed in the following reaction is[DEC –2019]

8.ProductsAandBformedintheFollowingTransformationofAlkylideneCarbenesare[DEC-2019]

9. The major product formed in the following reaction is[JUNE –2019]

10. The major product formed in the following reaction is[JUNE –2019]

11. Structures of A and B in the following reaction is
[JUNE –2019]

12. The major products A and b in the following reaction sequence are: [JUNE –2019]

13. The major product A and b formed in the following reaction sequence are
. [JUNE –2019]

14. The major product formed in the following reaction is
[DEC -2018]

15. The intermediate (s) involved in the following reaction is (are)
. [DEC -2018]

16. The major product formed in the following reaction is
[DEC -2018]

17. The correct order of rate of Solvolysisin 80% ethanol at 25
o
C is [JUNE –2018]

18. The major product A and b formed in the following reaction sequence are
[JUNE –2018]

19. The major product A and b formed in the following reaction sequence
are [JUNE –2018]

20. The correct order of stability of the following carbocation is [DEC –2017]

21. The major product formed in the following reaction is
[DEC -2017]

22. The major products A and B of the following reaction sequence are [DEC-2017]

23. The major product formed in the following reaction is
[JUNE-2017]

24. The major product formed in the following reaction is
[JUNE-2017]

25. The intermediate A and product B formed in the following reaction sequence are
. [JUNE-2017]

(a)π c₌c
(c)π c₌c (d) π c₌c
26. Molecular orbital interaction involved in the first step of the of
the following reaction is [DEC-2016]

27. The major product formed in the following reaction is
[DEC-2016]

28. The major product formed in the following reaction is
[DEC-2016]

29. The major product formed in the following reaction is
[DEC-2016]

30.Thefrontierorbitalinteractionsinvolvedintheformationof
thecarbocationintermediateinthereactionofbutylenewithHCl
are. [JUNE-2016]

31. The major product A and B in the following reaction sequence are [JUNE-2016]

32.StructureoftheintermediateAandBmajorproductBinthe
followingreactionsequenceare [JUNE-2016]

33. The major product formed in the following reaction is
[JUNE-2016]

34. The major product formed in the following reaction is
[DEC-2015]

35. The major product formed in the following reaction is
[DEC-2015]

36. The correct statement about the following reaction is that [DEC-2015]

37. Following reaction goes through [JUNE-2015]

38. The major product formed in the following reaction sequence is [JUNE-2015]

39. The correct statement about the following reaction is that [JUNE-2015]
(a)Theproductis2-fluoropyridine-3-amineandreaction
involvesnitreneintermediate.
(b)Theproductis2-fluoropyridine-3-amineandreaction
involvesradicalintermediate.
(c)Theproductis2-hydroxynicotinamideandreaction
involvesbenzynelikeintermediate.
(d)Theproductis2-hydroxynicotinamideandreaction
involvesaddition-eliminationmechanism.

40. In the following reaction, the ratio of A: B: C is (* indicates labelled carbon) [JUNE-2015]
(a) 1:1:1 (b) 1:2:1 (c) 2:1:1 (d) 3:2:1

41.Thereactionof1-bromo-2-fluorobenzenewithfuraninthepresence
ofoneequivalentofMggiven [DEC-2014]

42. The product of B in the following reaction sequence is [DEC-2014]

43. The major product of the following reaction is[DEC-2014]

44. The reactive intermediate and the product formed in the
following reaction are [DEC-2014]
(a) Free radical and 4-iodomethyloxepan-2-one
(b) Free radical and 5-iodooxacan-2-one
(c) Carbeneand 3-oxabicyclo [5, 1, 0] octane -2-one
(d) Carbine and (E)-5-iodopent-3-en-1-ylacetate

45. The major product formed in the following reaction is
. [JUNE-2014]

46. Consider the following reaction [JUNE-2014]
The appropriate intermediate involved in this reaction is.

47.Anthranilicacid,ontreatmentwithiso-amylnitrite
furnishesaproductwhichdisplaysastrongpeakat76(m/e)in
itsmassspectrum.Thestructureoftheproductis [JUNE-2014]

48.Themajorproductformedinthefollowingreactionsequenceis[DEC-2014]

49.Inthefollowingreaction,theintermediateandthemajorproductAare [DEC-2013]

50.Themajorproductformedinthesulphuricacidmediated
rearrangementofthesesquiterpenesaritonin. [DEC-2013]

51.Themajorproductformedinthefollowingreactionsequenceis [DEC-2013]

52. The major product formed in the following reaction sequence is[DEC-2013]

53. The major product formed in the following reactionSequence is
. [DEC-2013]

54.Themajorproductformedinthefollowingreactionsequenceis[DEC-2013]

55.Themajorproductformedinthefollowingreactionsequenceis[JUNE-2013]

56.Themajorproductformedinthefollowingreactionsequenceis[JUNE-2013]

57.Themajorproductformedinthefollowingreactionsequenceis [DEC-2012]

58.Themajorproductformedinthefollowingreactionsequenceis[DEC-2012]

59.Themajorproductformedinthefollowingreactionsequenceis[DEC-2012]

60.TheintermediateAandthemajorproductsBinthefollowingreactionare [JUNE-2021]

61.Themajorproductformedinthefollowingreactionsequenceis[JUNE-2012]

62.ThereagentArequired,andthemajorproductsBformedinthefollowing
reactionsequenceare [JUNE-2012]

63.Thereactiongivenbelowproceedsthrough [DEC-2011]

64.InthefollowingMarkownikovadditionreactiontheproducts
AandBare [DEC-2011]
(a)Homomers (b)Enantionmers
(c)Diastereomers (d)Regioisomers

65.ThemajorproductsAandBinthefollowingreactionsequenceare. [DEC-2011]

66.Themajorproductformedinthereactiongivenbelowis
. [JUNE-2011]

67.Theintermediateinvolvedinthereactiongivenbelowis
. [JUNE-2011]
(a)Freeradical(b)Carbocation(c)Carbanion(d)Carbene

68.TheintermediateAandmajorproductBinthefollowingconversionare[JUNE-2011]

69.Themajorproductformedinthefollowingtransformationis[JUNE-2011]

70.Themajorproductformedinthereactiongivenbelowis
. [JUNE-2019]

71.Themajorproductinthefollowingoxidationreactionis.
. [JUNE-2018]

72.TheIntermediateAandthemajorproductBinthefollowing
reactionare [DEC-2017]

72.ThemajorproductsAandBinthefollowingreactionsequenceare
[JUNE-2015]
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