reversible process workdone111111111.pptx

NilaySarkar5 3 views 15 slides Mar 09, 2025
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Air enters a compressor at 10 5 Pa and 25 ° C having volume of 1.8 m3/kg and is compressed to 5 × 10 5 Pa isothermally . Determine : ( i ) Work done ; ( ii ) Change in internal energy ; and ( iii ) Heat transferred

Q = ( u 2 – u 1) + W

APPLICATION OF FIRST LAW OF THERMODYNAMICS TO NON-FLOW OR CLOSED SYSTEM Reversible Constant Volume (or Isochoric) Process ( v = constant) :

Work done and Heat input Q = ( u 2 – u 1) + W The work done W = = 0 as dv = 0. Q = ( u 2 – u 1) = cv ( T 2 – T 1) where cv = Specific heat at constant volume. For mass, m , of working substance Q = U 2 – U 1 = mcv ( T 2 – T 1)  

Reversible Constant Pressure (or Isobaric) Process ( p = constant).

Work done and heat input Considering unit mass of working substance and applying first law of thermodynamics to the process Q = (u2 – u1) + W The work done, W = = p(v2 – v1) ∴ Q = (u2 – u1) + p(v2 – v1) = u2 – u1 + pv2 – pv1  

Work done and heat input cont.. = ( u 2 + pv 2) – ( u 1 + pv 1) = h 2 – h 1 Q = h 2 – h 1 = c p ( T 2 – T 1) h = Enthalpy (specific), and c p = Specific heat at constant pressure. For mass, m , of working substance Q = H 2 – H 1 = m c p ( T 2 – T 1)

Enthalpy One of the fundamental quantities which occur invariably in thermodynamics is the sum of internal energy (u) and pressure volume product ( pv ). This sum is called Enthalpy (h). i.e., h = u + pv

For a perfect gas, h = u + pv = c vT + RT as [ pv = RT ] = ( c v + R ) T = c pT as [ c p = c v + R ] i.e. , h = c pT and H = m c pT .

Reversible Temperature (or Isothermal) Process ( pv = constant, T = constant) : A process at a constant temperature is called an isothermal process. When a working substance in a cylinder behind a piston expands from a high pressure to a low pressure there is a tendency for the temperature to fall. In an isothermal expansion heat must be added continuously in order to keep the temperature at the initial value. Similarly in an isothermal compression heat must be removed from the working substance continuously during the process

Workdone ? Heat input?

Reversible Adiabatic Process ( pv γ = constant) : An adiabatic process is one in which no heat is transferred to or from the fluid during the process. Such a process can be reversible or irreversible. The reversible adiabatic non-flow, process will be considered in this section. Considering unit mass of working substance and applying first law to the process Q = ( u 2 – u 1) + W O = ( u 2 – u 1) + W or W = ( u 1 – u 2) for any adiabatic process

Workdone ? Heat input?

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