Solid State Lasers and Applns_RK.pdf

lasers

1. CSIR -Central Scientific Instruments Organisation,
Chandigarh
Dr Raj Kumar

2. Overview
Introduction to basics of laser physics
•Working principle of a Laser
•Main components of a Laser
•Lasers based on number of energy levels
•Lasers modes
•Main properties of a Laser
•Types of Lasers
Solid State Lasers
•Ruby Laser: the first laser
•Nd: YAG & Nd: Glass Lasers
•Tunable Solid State Lasers
•Alexandrite Laser
•Ti: Sapphire Laser
•ColourCenter Lasers
•Fiber Lasers
Applications of Solid State Lasers

3. What is a Laser ?
Light Amplification by Stimulated Emission of Radiation
Spontaneous emission Stimulated emission

4. Absorption
Spontaneous
emission
Stimulated
emission
h h
h
E
1
E
2
E
1
E
2
h=E
2-E
1
Working principle of a Laser

5. Working principle of a Laser
Let n
1be number of atoms in E
1state and n
2be number of
atoms in E
2then
Ifn
1> n
2
•radiation is mostly absorbed
•spontaneous radiation dominates
•most atoms occupy level E
2, weak absorption
•stimulatedemission dominates
•light is amplified
If n
2>> n
1
Necessary condition:population inversion
E
1
E
2
For stimulated emission to dominate, there must be more atoms in
excited states than in ground state. Such a configuration of atoms is
called a population inversion.

6. Main components of a Laser
All the lasers comprise of three basic components
Lasers differ only in terms of Active medium or Excitation process.
•Active medium,
•Excitation
source/pump
•Reflecting mirrors/
resonator

7. Lasers based on number of energy levels
Three-level laser
•No lasing action in two level system : no population inversion
•Three level system: lasing possible but require high pump energy than
four level system
•Example: Ruby Laser (three level)

8. Lasers based on number of energy levels
Four-level laser
•Number of thermally excited ions in the lower laser level is small
•Easy to achieve population inversion even by pumping a relatively
small number of ions into the upper laser level
•Lower threshold compared to a three-level system
•Example: Nd: YAG Laser

9. Lasers modes
•Laser oscillates in a number of transverse and longitudinal modes
•Transverse mode is selected by using mechanical apertures in the cavity
to allow only selected mode and suppress other oscillating modes
•Longitudinal mode is selected by using Fabry-Perot Etalon in the cavity
•TEM
00is preferred for most of the applications
Longitudinal mode
frequency separation

10. Main properties of a Laser
Coherence: from phase correlation
Directionality
High intensity: results from directionality
Monochromaticity: results in high temporal coherence
Short pulse duration

11. Types of Lasers
Severalwaystoclassifylasers
Classificationmaybedoneonbasisofotherparameters
Gainofthelasermedium
Powerdeliveredbylaser
Efficiencyor
Applications
Activemedium:
-Solidlasers
-Gaslasers
-Liquidlasers
-Semiconductorlasers
Modeofoperation:
ContinuousWave(CW)orPulsed

12. Solid State Laser
•For historical reasons, solid-state lasers are lasers in which
active ions in crystal or glass host materials are optically
pumped to create a population inversion
•Other types of lasers that employ solid-state gain media are
semiconductor lasers and optical fiber lasers and amplifiers.
Since these lasers employ very specialized technologies and
design principles, they are usually treated separately from
conventional bulk solid-state lasers
•Semiconductor or diode lasers are mostly electrically
pumped (though in principle, optical pumping may be
possible with some)

13. Are versatile and provide a large range of average and peak power,
pulse width, pulse repetition rate, and wavelength
The flexibility of solid-state lasers stems from the fact that:
• The size and shape of the active material can be chosen to achieve
a particular performance
• Different active materials can be selected with different gain,
energy storage, and wavelength properties
• Output energy can be increased by adding amplifiers
• A large number of passive and active components are available to
shape the spectral, temporal and spatial profile of the output beam
Solid State Laser

14. Active centers are fixed /doped (~ 1%) in a dielectric crystal or
glassy material
Electrically non-conducting
also called Doped-insulator lasers.
Solid State Laser: basics
•Crystal atoms act as host lattice to active centers
•Crystal usually shaped as rod
•Pumping: Flash lamp or diode laser
•Active centers are from the rare earth, transition metals, or actinides
•Water cooled

15. Solid State Laser: schematic
Mirrors on both sides of laser rod form a resonant cavity

16. Requirements for Host material:
•Should not absorb light at laser wavelength
•Must possess sharp fluorescent lines, strong absorption
bands, and high quantum efficiency
•Crystal should have good thermal conductivity
Active centresare ions from:
Chromium (Cr), Neodymium (Nd), Titanium (Ti), Cerium (Ce),
Erbium (Er), Holmium (Ho) and Cobalt (Co)
Chromium is active centre in Ruby and Alexandrite lasers
Neodymium is active centre in commonly used Nd: YAG laser
Solid State Laser: requirements
Problems with Host material:
oMost of excitation energy ends up as heat rather than light
oExcess heat damages the laser crystal

17. •Ruby Laser
•Nd:YAGLaser
•Nd:GlassLaser
Tunable Solid State Lasers
•Alexandrite Laser
•Titanium-Sapphire Laser
•Colour-Centre Laser
Fiber Lasers
•Erbium in a Glass host
Representative Solid State Laser

18. First Laser developed in 1960 (TH Maiman)
Ruby laser rod:
A synthetic pink Ruby crystal (Al
2O
3doped with Cr
3+
ions)
Cr
3+
ions concentration: 0.05%, Approx 1.610
25
ions per cubic
meter.
Ruby Laser: the first laser
The Al
2O
3(sapphire) host is hard, with high thermal conductivity, and
transition metals can readily be incorporated substitutionallyfor the Al
•Active Centres(Cr
3+
ions)
have a set of three energy
•Aluminum & Oxygen
ions are inert
•Ruby crystal as cylindrical
rod (4cm length 0.5 cm in
diameter)
•Helical photographic flash
lamp filled with Xenon.

19. A typical Ruby laser (a) with internal mirrors (b) with external mirrors
Ruby Laser: the first laser

20. End faces grounded and polished
Mostly silvered faces (100% & 90 % reflection)
Febry-Perot Resonator
•System is cooled with the help of a
coolant circulating around the ruby rod
Ruby Laser: commercial
In practical lasers flash lamps of helical
design no longer used
Most commonly used are linear lamps

21. Ruby Laser : energy levels
Energy levels of chromium ions is Ruby laser

22. A Three level laser system
E
2-metastable state (3ms)
•Ruby rod pumped with an intense Xenon flash lamp
•Ground state of Cr
3+
ions absorb light at pump bands
550nm
400nm
•Non-radiativetransitions to E
2
•Population Inversion at E
2
Radiativetransitions from E
2to E
1Red wavelength at 694.3 nm
Under intense excitation: Pumping > Critical threshold
A spontaneous fluorescent photon (red) acts as input and trigger
Stimulated emission; SYSTEM LASES
Ruby Laser : working principle

23. Laser Output:Pulsed with low repetition rate (1 to 2 per sec)
Ruby Laser: output
Ruby laser light pulses
•Series of irregular spikes stretching over the duration of pump pulse
•Q-switching concentrates output into a single pulse

24. Next pulse will arrive only after P.I. is restored
High energy storage capability due to long upper laser level
lifetime
Pulse energy upto100J
Relatively inefficient; 0.1 to 1%
Variety of applications: Plasma diagnostics; Holography.
•Stimulated transitions faster than rate at which population
inversion is maintained
•Once stimulated emission commence, the metastablestate E
2,
depopulate very rapidly
•At the end of each pulse, population at E
2falls below the
threshold value required for sustaining emission of light
•Lasing ceases & Laser becomes inactive
Ruby Laser: output

25. •Yttrium Aluminum Garnet (YAG) Y
3Al
5O
12 best choice of a host for
neodymium ions (Nd)
•YAG offers low threshold and high gain
•YAG is a very hard, isotropic crystal
•good thermal and mechanical properties
•can be grown and fabricated in rods of high optical quality
•Operation: CW and pulsed mode (high repetition rate)
•Efficiency about 10 times as compared to ruby
•Drastic weight reduction
•Replaced ruby in military Rangefinders, other applications
•Used in the semiconductor industry for resistor trimming, silicon
scribing, and marking
Nd: YAG Laser
For continuous or very high repetition-rate operation, crystalline
materials provide higher gain and greater thermal conductivity

26. Active center: Neodymium (Nd) ion-a rare earth metallic ion
Host: YAG
Emission at 1.064m
Nd: YAG rod & a linear flash lamp housed in an elliptical cavity
In practice, external mirrors (100% , 99% reflectivity) used
System cooled by water circulation
Nd: YAG Laser
•In Nd:YAGlaser, Nd
3+
ions take place of yttrium ions
•Doping conc. ; 0.72% by weight corresponds to1.410
26
atoms/m
3
•Rod: 10cm in length, 12mm in diameter

27. Nd: YAG Laser

28. Nd: YAG Laser
Energy levels of Nd–ions in a crystal
lifetime
230 μs

29. A Four level laser system:Require lower pump energy
•Terminal laser level sufficiently far from ground state
•E
3 –metastablelevel (lifetime 230 μs)
•Two pump bands: 700 nm & 800nm
•Pump: intense Xenon flash lamp
•Nd
3+
ions level E
4,decays to upper laser level at E
3
•Population inversion easily achieved between E
3and E
2levels.
•Stimulated to emit 1064 nm laser transition.
From E
2level, Nd
3+
ions quickly drop to E
1by transferring energy to crystal
Nd: YAG Laser

30. Many other transitions in near IR region; all weaker than 1064 nm
•Only 1318 nm transition produces 20% power as that of 1064 nm
Useful in Fiber Optic Transmission.
Laser Output:
•In the form of pulses of variable repetition high rate
•Overall efficiency 0.1 to 1% range
•Xenon flash lamps : Pulsed output
•Tungsten halide incandescent lamps ; CW output
CW output power of over 1 kW obtainable.
Can be pumped by a diode laser (GaAs) for high efficiency
2
nd
harmonic generation results in half the wavelength (532 nm)
Nd: YAG Laser

31. •Glasses are more suitable for high-energy pulsed operation because of
their large size, flexibility in their physical parameters, and the
broadened fluorescent line
•Can deliver much higher energies
•Can be doped at very high concentrations with excellent uniformity
•Practical doping limit is determined by the fact that the fluorescence
lifetime and therefore the efficiency of stimulated emission, decreases
with higher concentrations
•Can be made in a variety of shapes and sizes, from fibers a few
micrometers in diameter to rods 2m long and 7.5 cm in diameter and
disks up to 90 cm in diameter and 5 cm thick
Nd: Glass Laser
The major disadvantage of glass is a low thermal conductivity

32. Glass: An excellent host material for Nd
Attraction for Glass: well developed technology for making
large size glass (laser) with good optical quality
While Nd: YAG laser can be operated in CW mode; Nd: glass laser
only operate in pulsed mode because of low thermal conductivity of
glass
Nd:glasslaser very high output energy per unit volume of material
Nd: Glass Laser
•High energy in short pulses can heat matter to thermonuclear
temperatures, thus generating energy in small controlled explosions
(inertial fusion)
•NOVA lasers developed for Nuclear Fusion by Lawrence Livermore
National Lab. (USA) –employed a large number of Nd: glass amplifiers
to produce 100 kJ of energy in a 2.5 ns pulse.

33. An inertial confinement
fusion implosion on the
NOVA lasercreates
"microsun" conditions of
tremendously high density
and temperature rivaling
even those found at the
core of our Sun.
Nd: Glass Laser

34. Produce output over a range of tunable wavelengths
Tunability:existence of a cluster of vibrationallyexcited terminal
levels near the ground state –Vibronicstates
laser transitions take place between coupled vibrationaland electronic
states
Dye lasers, though tunable, but
suffer from dye degradation and
other limitations
Solid state tunable lasers have long
self and operational life
Tunable Solid State Lasers
Applications: Remote sensing, space, spectroscopy

35. Tunable Solid State Lasers: Alexandrite Laser
•Alexandrite (BeAl
2O
4: Cr
3+
) is the common name for chromium-doped
chrysoberyl
•Tunabilityis due to band of vibrationallevels which are a result of
strong coupling between Cr
3+
ion and the lattice vibrations
•Doping ~ about 0.1% (density~310
25
ions /m
3
); Rod shaped ; 10cm
long, 6mm in diameter
•Pump levels at 380 nm & 630 nm; flash lamp pumped
•Cr
3+
levels in Alexandrite form upper and lower vibronicbands
Electronic levels of Cr
3+
and vibrationallevels of crystal lattice
Vibronictransitions can occur over a range of energies; excited ion can
drop from upper level to anywhere in lower vibronicband –Gain
Bandwidth
Tunable to any desired wavelength within its emission spectrum
Can operates in a pulsed or CW mode
Widely used in cancer therapy, kidney stone removal and pollution
detection

36. Tunable Solid State Lasers: Alexandrite Laser
Can laseboth as a four-level vibroniclaser and as a three-level
Energy level diagram for chromium ions in alexandrite
Absorption bands are very
similar to those of ruby

37. Tunable Solid State Lasers: Alexandrite Laser
•In three level mode laser transition is from
2
E state, which is coupled
to
4
T
2, down to ground state
4
A
2.
•High threshold, fixed output wavelength (680.4nm at room
temperature) and relatively low efficiency
•In four level mode
4
T
2is the absorption state continuum
•Lasing occurs between
4
T
2 state to excited vibronicstates within
4
A
2
(ground state)
•Laser wavelength depends on vibrationallyexcited terminal
•Any energy not released as laser photon will be carried off by a
vibrationalphonon, leaving the chromium ion at its ground state
(system comes in equilibrium)

38. Tunable Solid State Lasers: Ti: Sapphire Laser
•Titanium-Sapphire (Ti : Al
2O
3) laser is widely used tunable
•Broad vibronicfluorescence band allows tunable laser output between
670–1070 nm, with the peak of the gain curve around 800 nm
•Relatively large gain cross section (half of Nd:YAG at the peak of its
tuning range)
•The energy level structure of the Ti
3+
ion is unique among transition-
metal laser ions in that there are no d state energy levels above the
upper laser level
Ti
3+
ions replace some of Al
3+
ions
Doping concentration 0.1% by weight
Operation: Pulsed or CW modes

39. Tunable Solid State Lasers: Ti: Sapphire Laser
The broad, widely separated absorption and fluorescence bands are
caused by the strong coupling between the ion and host lattice and are
the key to broadly tunable laser operation

40. Most widely used in laser radar (LIDAR), range finders, remote sensing
and spectroscopy
Tunable Solid State Lasers: Ti: Sapphire Laser
Energy level scheme
•Pumping with other lasers like
argon and copper vapor lasers,
frequency doubled Nd:YAG and
Nd: YLF lasers due to short
lifetime of upper laser level (3.8s)
•Flash lamp pumping is inefficient
and requires very high pump flux is
required.

41. Broadly tunable SSLs–operates in wavelength range of 800-4000nm
Tuning achieved using different colour-centre crystals in sequence.
Typical CCL consist of an alkali halide crystalthat contains point
defects known as F-centre ColourCentres
Usually produced when crystal irradiated with X-rays.
Colourcentresremain in crystals for duration ranging few days to
many years.
Absorb and emit light as the atoms at the defect site change position.
CCLs must be pumped with other laser & maintained at very low temperatures.
Need for a pump lasers & Cryogenic cooling limits the use of CCLs in
practical application.
ColourCenter Lasers

42. CCLs must be pumped with other laser & maintained at very low
temperatures
ColourCenter Lasers: Energy Levels

43. Erbiumin a glass host –forms a three level laser with wavelength
centered around 1550nm (range: 1520-1560nm).
1550 nm is important operational window in OFC technology
Highly useful in undersea and long haul OFC links
Fiber Lasers
EDFA is used as an optical amplifier in DWDM technology

44. Fiber Lasers: Energy Levels
•Needs lasers for pumping to get desired output.
•Output transitions in the range from 1520-1560nm

45. •Parametric oscillators based on lithium niobateintroduced in 1971
•Discovery of damage-resistant nonlinear crystals with large nonlinear
coefficients in the early 1990s revived interest in OPOs
•OPO can provide tunable range through UV-visible-IR
Optical Parametric Oscillator
•OPO works on the principle of non-linear harmonic generation
•In the parametric process, a nonlinear medium (usually a crystal)
converts the high energy photon (the pump wave) into two lower
energy photons (the signal and idler waves)
•Wavelengths of signal and idler beams are determined by the angle that
pump wave-vector makes with crystal axis
•Energy can be transferred efficiently to the parametric waves if all three
waves are traveling at the same velocity (phase matching condition)
•Variation in index of refraction with crystal angle and wavelength
allows "phase matching“ condition to be met only for a single set of
wavelengths for a given crystal angle and pump wavelength
•Thus as the crystal rotates, different wavelengths of light are produced

46. Optical Parametric Oscillator
Signal and Idler beam generated in a non-linear crystal
pump energy = signal energy + idler energy

47. Optical Parametric Oscillator
Variation of OPO output energy (signal and idler) with wavelength

48. •As diode lasers became less expensive, these are being used as optical
pump in solid-state lasers
•Diode pumping offers significant improvements in overall system
efficiency, reliability, and compactness
•Radiation from laser diodes can be collimated providing great
flexibility of designing solid-state lasers with regard to shape of laser
medium and orientation of pump beam
Diode Laser as optical pumping source
•In end-pumped lasers, pump beam and resonator axis are collinear
which led to highly efficient lasers with excellent beam quality
•A number of solid-state lasers with outputs up to 20 W are pumped with
diode arrays
•Lasers at multi-hundred watt level are pumped by arc lamps because of
high cost of laser diode arrays

49. Solid State Lasers have a wide spectrum of applications
•Materials processing (cutting, drilling, welding, marking, heat
treating, etc.),
•Semiconductor fabrication (wafer cutting, IC trimming),
•Graphic arts (high-end printing and copying),
•Medicalandsurgical(Weldingofdetachedretinas,correctionof
visiondefects,surgery,treatmentofskincancer)
•Defence(ranging,anti-missileshield,laserdetonators,instruments,
spyingandinwartime)
•A high energy pulsed YAG laser has even been used in rocket
propulsion experiments
•The largest lasers (with the highest peak power) in the world are solid
state lasers
•Space, remote sensing, spectroscopy, holography
Applications of Solid State Lasers

50. INDUSTRIAL APPLICATIONS
Laser for Cutting Fabric in a Clothing Factory
Laser in Material Processing
LASER APPLICATION EXAMPLES

51. Laser at
War time
LASER APPLICATION EXAMPLES

52. Laser
fusion
LASER APPLICATION EXAMPLES

53. HOLOGRAPHY
LASER APPLICATION EXAMPLES

54. Solid State Laser Engineering , W. Koechner
Principles of Lasers, O. Svelto
Lasers and Non-linear Optics, B. B. Laud
Laser Fundamentals, W. T. Silfvast
References / suggested books

55. Thank you

56. Why Alexandrite is tunable and Ruby not?
•Equilibrium coordinate for both the
4
T
2and
4
T
1states, due to their
symmetry, is shifted to a larger value than that of
4
A
2and
2
E states
•As in other Cr
3+
-doped hosts, the decay between the
4
T
2and
2
E states
is via a fast internal conversion (decay-time of less than 1 ps) probably
due to the level-crossing which occurs between the two states.
•These two states can be considered to be in thermal equilibrium at all
times, and, since the energy difference between the bottom vibrational
levels of
4
T
2and
2
E states in alexandrite is only a few kT, an
appreciable population will be present in vibrationalmanifold of
4
T
2
state when
2
E state has been populated.
•Invoking the Franck-Condon principle, one sees that the vibronic
transitions from the
4
T
2state end in empty vibrationallevels of the
4
A
2
state, thus becoming the preferred laser transition.
•Because there is a very large number of vibrationallevels involved,
the resulting emission is in the form of a broad continuous band