Solution manual chemical reaction engineering, 3rd edition Octave levenspiel

annaLuHdzChavaRRiia 268,667 views 146 slides Nov 23, 2015
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About This Presentation

Solution manual... Complete


Slide Content

SOLUTIONS MANUAL

fo accompany

CHEMICAL REACTION ENGINEERING

THIRD EDITION

[includes Solutions to All 228 Odd-Numbered Problems ]

OCTAVE LEVENSPIEL

Telephone 541-737-3618
Fax 5e1.737-4600
Email evenspo @ peskorg

®

JOHN WILEY & SONS, INC.
MEW YORK: CHICHESTER WEINHEN = BRIBBANE-SINGAPORE «TORONTO

Copyright © 1999 by fla Wiley & Sos, In.

Excerps fom his wok may be repradacod by introns
for distribution on a nao pro. ass for testing ot
instructional purposes only students enrolled in courses
for which the textbook has been adopted Any other
‘reproduction or ranlaion ofthis work beyond that
"permi by Sections 107 or 108 ofthe 1976 United States
Copyright dct witout he permission of the copyright
owner santa. Requests fr permission or further
Information shouldbe dresse o the Permisions
Department, John Wiley & Sons, In, 005 Third Avene,
New York, NY 10158-0012.

ISBN 0471314781
Printed in the Unite Stats of America
1987654321

tn yy Pic

CONTENTS

Chapter 1. i en sl
Chapter 2

Chapter 4 o - 0
Chapter 5 19
Chapter 6 2%
Chapter? en se mass 34
Chapter 8 a
Chapter 9 “1
Chapter 10 ; si
Chapter 11 sas ananas
Chapter 12 A 38
Chapter 13 sl
Chapter co een 68
Chapter 15 7 ee cs Th
Chapter 17 ee
Chapter 18 E s m
Chapter 19 se ...86
Chapter 20

Chapter 21

Chapter 22...

Chapler 23 nennen ee
Chapter 24 Be nu 14
Chapter 25 ove 124
Chapter 26. : 127
is 120
Chapter 29 one BBB

Chapter 30 i 139

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8

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Divide Gr kei gues bee pee

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anal fat un fet de
Tale express.

ve reactant À rege
stat parias

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en ae

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à sucio a sduation Eg, (5) wll Feduce to

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«der rein

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4 more and mora, Mechanism predicts that

a point

be veo whee the reactor order ul ches

nt ER
ring from One, and ait agg

wand erentuaiu, brume

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3 an unstable
reins

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cie) (tes
&

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end ity the dan gen

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de vate oque

la pressure vats:

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ren Weitz

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an palm

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tel

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aged

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1

as tbm Imin beranse

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pe Yeally vecded in ee coctel dera Eos

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the genen For E

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rate equalin te repre the dab. At order, pers at,

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avd then régie 7

Leger 3 mil Fir the date,

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E El 3 5 3
oceciueas. bel os ce tis,

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we have

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ie

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AS

Blom the blast Au

Fiem the corretaten By one

ser stile, Bg

ess yenolly cue stacy different, tb auld be Berne of
Sn the bolas Brenn, amant ey dhe
Zas oud

the seee by

ho sole chernsheg of He ges

Fiore
eyed:

Hora cateytate de,

mat, pera,

st fe thin Fou

heavier

stort acme that Pelee,
DR RL

AE Fa Fonos
an ue Gt:

ne nes

eee:

thal bee que) °

malte Faw model (dou

A ag (distance, from À

Boca cursa pet of mah
Lo from A Covet
Feadiag

ná {ron tive Porkensah
reads, 5

Achtand

Horgen een

his sehn atomes thot a flame matrice ef the Ohio

a
have the same flows & dispersión character

5 {a rensorable

Hat no suspect iria üben

reste a,

urstresen from Cineman {a jor o
locedin, of Charleston Wa. One Kanamah.)

FU Feb callate k assume plo Shon, ther, gesund for

ON

A) Find & ansoming play Pew
Yor a À onder reachin, &

in e ti ol

ho
[7 “pia

=

hed)

nd ko accuunting for deviation free plo El
para model

Fran the convent ET we fia for
Bei tus D uns
ee ud,

ine sie robo of real tp plug A
the ratio of the corra: ending € Coke repstonts is found e:
Fig 4 oc from 8422 1 the k ratio

Ying reactor, or hab is equvelent

or the L veto te ol

Use 24.22. Then,

Fs Brag we hae) =
Nota Direct ase of Ep Gilat Levene onfertomately’y malt que
e mota cesorabe ans ~
one gps sore Hak Re 7K

Berar in assomng flag Faw a

sku

Ena the are & tee à

am EIS

Het “Tre analogy

do ie te identity toe various quanties. Vaters

ns shout be exelent Ay

Vero duce

Cara of

Less ote
a

E Ra =toini no of bie
Nouher ah €
his m
ena

FSO) Hoo many e ete will be à arca dió ab any Hine y 7
feevtued

a

A
by he wonicer of

in coreviation wine ave over 2

Quen by the ELO Foratin. Thus

ose tHE

os gor Ha ROP Lace we assure
> rexpuueus encincohon nf ages

Bae da Gah these at so

Fer pue Hu
RE of

En eat deis

Furt cotewtate

feud then Brom tig "al

Tren fom

IT rey
oes
Eure

ire

a ga

he haut >

“a

bocata othe va mie

Weil
VAE} sh 9 de
Ko

ey A scher ith came seeds and a Keon aus seh From En Bi

Ar eb bc

Nein he
fe
RCE

wird half,
27 abs

raortor deine Vas
modes, o

of the permet
proper Y. to om dre heverss
Y vewe +

ose br tha. ta
madet

200 wage lay materia the espérait
LALA the

race, cue, vith tha ty of

diepersion modas) se id Fig 2 Cor Seis sede!)
Of dy clearing GZ and Gam thar Wat er 3,

Let us una de lanes prmedure: Do Piesr
Baba wäh, bas. In and 12

Mola the oven under the Ceorue urb,

OF an coi in Sample 4

Ser
i mo alcala À

Hlatucoitg the deck use af the à wer he weet
doe rene, Im Hm prbiern the

Vara bd es peek

ner curve

en RTE cone For the
ab he

hegersion modal uth Baa.

evs YO pasto ay and #3 chaold agree

Fak fod whe cage agains À

EAS

pues criada

in he mtermahuhe
Leg Water the ture,
2 hope sande.

Éd)

POTTS

Coss

FLE For de eras

FN

pr LS as
or ne rene

For the naface lostasaon th

Sucrvondña hau
4

(EAM id mos tere

caf

Pomona dy dh A, s

on

Sg

aaa for sunny rence

[Bi We compet tea

carmen

oot she pecador thee you ave

EE, %
D ROME à chewing
ag

gout thes Yoo Vase an Wibegral
e walten ef larva yoo ave: taking Pas vate,
y 3

un -

CRE

he ete ef rat ot Lava
sega of the curse

A co
Agsııne
The Kan ï
Se. use have à effet
hace qa ala ie de slope of de curve

ly For Thos to ES
the faa

Anker into:
tee,

oe ie

ETES
rotonda à 1e

Co

= 00707

grok

Now ftom the performane ex;

Bom these & quachihias de cho fold arabe eue

the

dete gute Ca

i bg ia de
Hal: War a it le
take Forms. FO tile cote plot ty! ex Cay as ahr Leid

We ques a goes Satin $e
Gh sige 10. 8

eye is

=i IC —
m:
ungut | EE vise
vo
FEINE ty ect
E dor os E ue

e

Senn Bol der

ES

neh ee

dos or a

The oh JE

Tos pg enw

This does not change the cate apater

ora pelfrinance, erat + taf

Those ada era notes the rectos Kpger à
p

+ dices nat <

werde À

aga the eg

LE pers

ist

4, 26mm

Byron Bag

pe 100 wel Ju

oie wowed oy ALE su

evden vas

For oriente a,

ARAS dies cme oo

Cada Wl 2 mg et von ws made tu the rage dt

de akthe came “fg. lie are alsa tid
yee cake ie high enough to have waned Bow
Brena hut Tos changing MR vela caja from toed it

from var G4 th na change in rate skews hat Ahm reutence
ows iat mfvence the rote

E

Mast, P the parties were mon pocoss then the emailer a
trons T&R} shavld have double he vate of the jagen age (rime
2.84). The is nt bat is meaner

À hence the rasulls ose
et consistent with the ques of

partidas.
Alrght, lab os 20e if be re
Ascamghiin of

mas partición

Ea wege of Ng pre son resghance the rakes.
u imge S

should be es E A pellera

wig in the rege of strona” pore cif Pues te robe kid halve
a) x A
PaO qua ts D lagos patos

Dor wscts cue lues bahween Huse tao
must Le Opersäng under coucitues where pee chffosin ys
quel Leanna Ellos the rote

is ee

watrenas , heee ive,

Teas

So

Femmes parties,
Fessstane gie vegenng M mirada £affed the raie

win

For muved flow the reactor performance

and swice tha dats chum that the robe.

mérité progartionai in pellet ©
gare diffusion conheais in anit. ro
En ; LE

D ras vend by élmmath pare fos
a A Lis Cy u
+ run Bos we con get © ot

ES © ss
vi E mesa
we swaher gales la a purkad & we ao.
chest be able te aémeve mo hgh as a cm

ns pote eff pian

e that la dee resume nf oe 3 GOVE Aun restants

& haves

re. constant

Aaehng the. petiet

Far Gram pea
ym pel

flora, See

uh A
PA

Sat ed

de Bras patio

Res Ja

re À
20 Bocked hal Clay mil unes dy

nemis tose

DR,

grd bad better bécane
TE reeds only BEN of tha pacas bad cata

es |

Lown arms

vendas
bide

grat aña
the angel rec

Pen

rosé be se Walent tn
Ayempaake (uke cetvechin, So what ue are quien ds à
dato. de aide we Know Ka ab tendus Va/tiys 302 creta.

Fak Par 20 mm, Le this aus le BIT serbions

be ten ats

“Thos the areuaat of Catalyst needed ir Be astead of tm. tod all

aise unchanged? Yate (892

je Sh on? of cobalt bab mam $)

Optimal temperature progression

2120) 2024 lg

Heat added ahead of the reactor

Sur Re Gp ar = one men) mare
eat removed from she reactor

Oa lala + quan

jones) (85006) + (ee) 126 159
= Ra nots

20k ak,
Seek tee Re
ze ma
Sante

20% À 80% inert, adrabatic reactor

Fin this graph we can ses tat rece
Flow is best end

oA
we fa, Bl foovas)ntsyia2)
e
“nk

alr

= Bt man)

(t9o}eeyigas-200) (20M: 76 Evo)

Rates 76 of
that oem in
de cho

QUE S/S Cheating)

1447

drones)

L cf cechnagts où late
Le qe

Rnd tego à

E ge

gr prie

Rat 178 Ni

204 A- MB, Ya

tous ot

slope = <a> = “Sais = wae

Plug flow sith recycle ix best

2

so

rareai LO

Reaction rate 35 Ye of that
ws the chart.

AA
Re

= 2.85
Wa Fa area2te0d(5) .
ent E 62 04 Jos] os
= x
Heat dat us : i, oats
4 ë bn obs

= aC (aT)= (20)!2009¢50~306)
= sio by (nesting?

Ftp lar) = 201200) 10-080)
OB oF /s (seg)

Note thet thes Solution was obtained ”

after à few trials

ass)

2

2000

Fraction of Seed A dut
goes te the first reactor

WL Roy areo = (54018300 88)
Wee fay arene =(500221) anosig

= fau: SPOT) (sx 183190800) (690-20:

fran E el

seek POT

unir

Keg arse

A va

wow fes sed) OF

bio
.

Cue reaniga rau ma. eu we
an Gang BRE à ib we
E const

Leni deny =:

rias Aie

CODE TT ES ES

ve the waren ty

bas Oye argent à

A m Que sa anal = LE

$ loo ma 8007

[ias any/eg

pom = Gras

(«ono

Fama

¿dor
fox Gents

$

Feoutagy à ~

Euren:

aa 92 = natur

%

Le exon

rn me

Estudos restée

Kan are

x
fe
“aus Mpa dn ott

Tr rg

pa hno ZAR

36
de finos has de

a
ss
ke

competa site ayy jb
a ere ©

Ale r (Fax gas Y
4,7 One 2.2064

Phe rancia che BEE

(ays ent

Bete Compare HS catediaied Ya date only that fn

patas of Matin. de

br Fhoutaad Las
rend > 0

Ken ort En rere ens

LOGS

Essent

dant .
Rad some other y

#1 mias mode of one concetiarión, va dret tah we

nan avcther
sida oa op

Bay bath ome we find



ar Ca, Ye

Baa, ® j

2102 he se

A se shut by gu
TES er reaction, ara Dit ene
Ta 20 rate fr, as ston <a

Frey cient

Eo our
Stay dk ques wn,
“soez,

ope 5

in hake

ly Megane any!

ere. De et
Er, >

ey tokaag the simplen vat

AA

niza hom. Stock
Feral wader coven

invegrabia de avd replacing va

da

and an srparahion of vorvebtes

BAG Mew ab dem Min ong,

Le nt

$

Bis in the equation, awd tp test the lux

ob as dy amies
we o atea batch rewdor fiw this rad os, Eve wale

and then pot

’ $ Faut
aa pa

Blow plot ant ene oP you get

à te

Inteieepi no =. ei
+ nu

un Slopes ste we

ES

in ste

ana

Gk ta:

at ru amd:
in the diffusive retrasa Ree reg

& heit ques
bung eu at

AS
Con Je

gti

Goo. à

Tes the,

o

Usa the pseudo sheaduystale
mm. Usera pseodo sha Sydal
changes ina
AR Aatough the

sine th

3 wie, obtain

eae
hese the censor sepa is vetated
to al cia va the areas

Rew the pean cone

Nea tine aura Go

Edo or

a the añora urger

O

Ordás tech E deochvatey bob wh à

is

ee peje

ty, Ina i

+ We got
20
Jen

Marce = 04
eus etn
ans

Sage ei

a

Nur ion tee

ee agé Em

I Deca à
co NE
3 pesa

this vides thet e ave

Fopprse me men base camas ab the clit that oe were
in the rimes pare Alain torbe came. ded gat à
Mage onthe graph, vepeeseating Ge 4%

2a pepe ”

Sole repas me
dr, Wat is

De

Dur Orginal Singen. of s¥oag

pre An tee

Phase an Agent ur and ug u © onen

nah répécants pea:

ilega.

Fiat les us we if aither extreme wih bs complificcatins apply
Serie Jar
u. AOS
HT der 7

28e

| Euen up lo est we haverhe
Stet Cg Hoo nthe? À treme woe OgPCK Loot sie

{

3

the coxpuecsios. fos tas anflewe, Dit

ges pS Ah Gs thee, check af the and

ao wah fado
Exaivebe quedes needed to Led the vate

OG fut

+ + de
CA ET)

= 00%

Ape mein cecstunce

consta qu Éarengheit dhe tele bed and ni she rare
tedepeaaent 2 Ce the matercal balance becomes very amigo, as ud

amd las teacher. Thos

79.4 This venetiim ism mmed fro 2e evaluate, core

akon candi, dla toapacd to Ay or
ee

e

Teo tos 46e
woe 605 as 5
iho adn weg

abe 5 i
abe or even Lera achetez

ze Bre mach

balas e

IDE)

Eu tet ve see Kf ether echene agplies
A usa"

ass) :
. ey Coman, we saa shat
Cag = 897 Mad Carr Ca

Rend apron Gag = WAT mar À Menage ate ven

pases

Dse He equals for he GC eoliano

sooo,

ETUC SCE AY

Lo (8585) BOTH MEALS
“yn en 087 en? rascher.

sue these terms to whegrahe

SS (OMIT _ iy weg à

= Bhe 28 a

ges go

al vote depend

that dre trat

feo cit rabo in the tragos

De atar

ed

Hehe that she pass seed

reacia Mak af roca IBIS, tu oor raval à

Wpavfad. Continue, wth she pelar ser

02 nor)

m. LE re seine

und

we: Sin Cd e
253 Au

ae de hank

ES

at Aramaper

qo — as
=
©

the tore

rag Re pure

FR ar uta, Gove Bad

ir

5 Hind tae tarte

405

as Fe Mona
hd uns
Gm parte, rap de don, ve de av

and Gro. the var

de cere tn e gas Man y

sia

curas

woe Rage os

Uae Fae, Ch tnt

“Pai

and apr me the chart

rs

née recitar

Test the 3 posable shrink ng-<ore mechamoma fe see which is

consistent wth the Flog raperted daha

Y =0875 at }
Got Bee

mor kee ot Leos

Yg =1.000 at tried) Ca ae

Side the shape of the golds is net specified assume to start
ua that they are aphandal. Then from Table 1

if Elm alos

Lot from the data: os 2088 ... this doesdt agree, so
we reed tad
mehdi

tral)

1-3(4y% 420%) = OS de

à
contmls: À exe

Y ash diffuse controls: À
again from the data oS

Now before we feel that ali is solved let us try the Hurd
Trechansm, the kus, maybe Wt fos will fit,

We surface ven.
4 again from the data ant = (ey? =. rere this also

ON

So here we have à comadee where both)
reachin & ash dffosión x se data |

~ Fg shows that the data were taken at
the precise pour uheve the ach dffosiin conve
evosses the readım ce ny curva

IP we try the equatións for Flat plate or cylindrica
petlets we find that neither will fit the data

Here we

Elvin

ovine
venstances, im Aljosión

gn

urfarz reackon.
Fold teat we con ignore Liew Affen we a

ace we. core
fe uch

axe

resto covtrtth

ing alone. So saya for th.

From

3 Sueras Teachade, no

tool reaction,

Frown Ha air pal

For pit un

converse

san the pousse fe as o
Zoom oe 2

Zum bie, ae ann. ban namen

: fe Bemepte à ase hase

20008 ¿a Maid lnea

“pol

Pots quae Coen FO

De à EE

pee à
Emi

Y
z
x

rencia tre ss

base nu

late

> tapes

tine Sepeecdona o, bugher ovdey tons thal afk

m keep Foi hgh cn

at the 6 kate ne tee Roe

eye
rare pote ER
a +

ne fenrtusn u

een

SEE mer CE

fo Fier seve

N
dat

Le

3 hin .
her) a
Kun ‘
Pere me nant be aman où 4) ne

Erna Le such

alante the ft

+ Sige 2

ere

ape die de

But this de Tata

maria Gaal no

wth gata oo

be vencer 2,

The fom

at ened Hoa

20.4

a antler prime Hr cu poe

EOS
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