Elements are arranged according to their
increasing atomic number and atomic mass
in the Periodic Table.
Elements with similar properties are arranged
in vertical & horizontal groups or families.
Vertical columns are called Groups
Horizontal rows are called Periods
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Periodic means ‘recurring at regular intervals’.
Periodic Table means that the atoms are arranged in
the table in a manner that recurs regularly.
This refers to the outer energy level electron
structure of each of the elements in a particular
Group.
Group 1 elements all have 1ē in the outer energy
level.
Group 2 have 2ē , Group 3 have 3ē , Group 4 have 4ē
etc.
This means that the elements in a particular Group
will all have similar properties – same ē structure.
2
The periodic table
Non-
metals
Metals
3
The periodic table
Groups
Transition elements
Inner transition
elements
1
2
3
4
5
6
7
Groups
Periods
Periodic tableSummary of periodic table
4
5
G roups 1 & 2: s-block.
Groups 3 – 8: p-block.
Transition elements: d-block.
Inner transition elements: f-block.
fill up:
2s
3s
7s
5s
6s
4s
1s
1s
2p
3p
4p
5p
6p
3d
4d
5d
6d
4f
5f
Groups 1 &
2
Groups 3 - 8
Transition elements
Inner transition elements
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Consider the Group 1 elements from H to K:
H
Li Na K
The above diagrams show the similarities
between the Group 1 elements – their 1ē in
the outer energy levels.
Discuss the differences between these
elements.
Periodicity
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In general, atoms decrease in size across the
periods from Left to Right as a result of increased
attraction between outer energy level ē & the
nucleus.
Atoms increase in size down the groups as a
result of having an extra energy level
Decreasing size
Increasing size
Sizes of atoms
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When Group 1 elements react with oxygen
they form the oxides – each with a similar
formula: H
2O Li
2O Na
2O K
2O etc.
Similarly when elements combine with the
halides (Group 7), they also form similar
formulae: NaCl MgCl
2 KF CaCl
2 LiBr etc
Forming compounds
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When considering the bonding process as molecules
are formed, we need to consider the following
concepts:
Ionisation energy
Electronegativity
Electron affinity
Ionisation energy: the energy required to remove an ē
from an isolated, neutral gaseous atom. Unit: kJ.mol
-1
Ionisation energy increases from from left to right in a
period and it decreases from top to bottom in a group.
Ionisation Energy:Ionization energy
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Electronegativity: The measure of the force of
attraction exerted by an atom when sharing an ē
pair with another atom.
Electronegativity increases from left to right in a
period and decreases from top to bottom in a
group.
Electronegativity
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Electron affinity: The energy
released when an ē is added to an
isolated, neutral, gaseous atom.
Electron affinity increases across
the period and increases down a
group
Electron affinity
Trends in periodic table
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Since metallic (& often reactivity) properties
increase from right to left & down the groups in
the metals, Na is thus more metallic than Mg & yet
K is more metallic than Na.
In the non-metals, the non-metallic properties
increase from left to right and up the Groups. O is
thus more non-metallic than N and S.
Determine the most metallic of the metals.
Which is the most non-metallic of all non-metals?
Metallic properties
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Li, Na, K, Rb, Cs & Fr
1.Soft
2.Low densities
3.Float on water
4.Silvery surfaces when cut
5.Good conductors of heat & electricity
6.Burn in air to form metal oxides
7.Metal oxides dissolve in water to form
akalis
8.React vigorously with water to form H
2 gas
9.Form cations with charge of +1 – lose ē
YouTube - Brainiac Alkali Metals
Flame tests
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Group 2 – the alkali earth metals Be, Mg, Ca, St,
Ba, & Ra are:
1.Silvery in colour
2.Form cations with charge +2
3.React slowly with water
4.Good conductors of heat & electricity
5.Burn in air to form metal oxides that dissolve in water
to form the hydroxides
Group 1 & 2 metals
Ca
Mg burning in air
Calcium reacting with
water
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The halogens are the non-metals in Group 7
They:
1.Form diatomic molecules F
2
, Cl
2
, Br
2
, I
2
, At
2
2.Form anions with a charge of -1.
3.Have low melting and boiling points.
Halogens
Iodin
e
Chlorin
e
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Group 8 are the noble gases: He, Ne, Ar, Kr, Xe
& Rn.
They:
1.Are extremely unreactive – full outer energy
levels- this can be useful.
2.Low M.P. & B. P.
He balloon taking pictures of
Earth
He
Ar
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H He
Li BB
e
CNO FN
e
NaMgAlSiP SClAr
KCa
Fill in the symbol of each of the first 20
elements in their correct order.
Give yourself 1 point for each correct answer.
Now check your answers.
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