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CHAPTER-2
Zinc (Zn)
2.1Introduction
Zinc is a metallic chemical element with the symbol Zn and atomic number 30. In
nonscientific context it is sometimes called spelter. Commercially pure zinc is known as Special
High Grade, often abbreviatedSHG, and is 99.995% pure.
Zinc is found in the earth’s crust primarily as zinc sulfide (ZnS). Zinc (Zn) is a metallic
element of hexagonal close-packed (hcp) crystal structure anda density of 7.13 grams per cubic
centimeter. It has only moderate hardness and can be made ductile and easily worked at
temperatures slightly above the ambient. In solid form it is grayish white, owing to the formation
of an oxide film on its surface, butwhen freshly cast or cut it has a bright, silvery appearance.
It’s most important use, as a protective coating for iron known as galvanizing, derives from two
of its outstanding characteristics: it is highly resistant to corrosion, and, in contact with iron, it
provides sacrificial protection by corroding in place of the iron.
Zinc ores typically may contain from 3 to 11 percent zinc, along with cadmium, copper,
lead, silver, and iron. Beneficiation, or the concentration of the zinc in the recovered ore,is
accomplished at or near the mine by crushing, grinding, and flotation process. Once
concentrated, the zinc ore is transferred to smelters for the production of zinc or zinc oxide. The
primary product of most zinccompanies is slab zinc, which is produced in 5 grades: special high
grade, high grade, intermediate, brass special and prime western. The primary smelters also
produce sulfuric acid as a byproduct.
With its low melting point of 420° C (788° F), unalloyed zinc has poor engineering
properties, butin alloyed form the metal is used extensively. The addition of up to 45 percent
zinc to copper forms the series of brass alloys, while, with additions of aluminum, zinc forms
commercially significant pressure die-casting and gravity-casting alloys. Primary uses for zinc
include galvanizing of all forms of steel, as a constituent of brass, for electrical conductors,
vulcanization of rubber and in primers and paints. Most of these applications are highly
dependent upon zinc’s resistance to corrosion and itslight weight characteristics. The annual
production volume has remained constant since the 1980s.India is a leading exporter of zinc
concentrates as well as the world’s largest importer of refined zinc.