PraveenKumar3078
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May 15, 2016
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About This Presentation
A Presentation summarizing the final year thesis on water quality index.
Size: 131.25 KB
Language: en
Added: May 15, 2016
Slides: 41 pages
Slide Content
PRESENTATION ON Measuring Water Quality Index of surface water of Agartala & Determination of Iron by UV spectroscopy method (Phenanthroline method) Guided by- Dr. Ajay Kumar Manna
Introduction The quality of surface water depends primarily on geological formation of a particular region .Tripura , situated in the North eastern region of India, is industrially underdeveloped. Other factors such as leachate from a solid waste dumping sites dumping of industrial waste and municipal solid waste etc. may have an effect on surface water quality here . From health point of view it is therefore, becomes imperative to regularly monitor the quality of surface water and to device ways and means to protect it.
Water Quality Index Surface water samples were collected from 23 locations . Samples were collected in pre cleaned plastic polyethylene bottles for physicochemical analysis of sample . Prior to sampling, all the sampling containers were washed and rinsed thoroughly with the distilled water for analysis. Each of the surface water samples was analyzed for 10 parameters including pH, EC, turbidity, TDS, Fe, Ca, Mg, K, Cu, Zn and total hardness (TH ). Water quality index is an important tool for checking the quality of water, whether it is fit for drinking or not.
DETERMINATION OF IRON BY UV SPECTROSCOPY ...
Importance of iron for our body The transportation of oxygen around your body Iron is required for the production of red blood cells Iron is also involved in the conversion of blood sugar to energy.
Side Effect Of Excess Iron In Water Corrosion Toxic Clogs
Iron is an an abundant element in the earth’s crust and generally exists in minor concentration in natural water system. The form & solubility of iron in natural waters are strongly dependent upon pH & oxidation reduction potential of water . Iron is found in the +2 &+3 oxidation states. An increase in the oxidation-reduction potential of the water readily converts ferrous ions to ferric(+3) & allows ferric iron to hydrolyse & precipitate as hydrated ferric oxide. Consequently ferric iron is found in solution only at a pH less than 3.
Surface water in a normal pH range of 6 to 9 rarely carry more than 1 mg of dissolved iron per litre. Formation of hydrated ferric oxide makes iron-laden water objectionable. This ferric precipitate imparts an orange stain. Colloidal suspensions of the ferric precipitate imparts can give the water a uniformly yellow-orange , murky cast. This colouration along with associated tastes & odour make the water undesirable when the level exceeds 0.3mg/L . The UNITED NATIONS FAO (food and agriculture organization of the united nations) recommended level for irrigation water is 5mg/L The BIS STANDARD desirable limit for drinking is 0.3mg/L.
Method for analysis The reference method of analysis is a photometric method ( also known as phenanthroline method ) in which iron is bound into a colour forming complex with 1,10-phenanthroline.
Sample handling In the sampling & storage process, iron in solution may undergo changes in oxidation form and it can readily precipitate on the sample container walls or as a a partially settleable solid suspensions. For total iron measurements precipitation can be controlled in the sample containers by the addition of 1.5-2.0 ml of concentrated HNO3 per litre of sample immediately after collection . If the pH is not less than 2 after the addition of acid, more HNO3 should be added.
PRINCIPLE For total iron determination, precipitated iron is brought into solution by boiling with acid. Ferric iron is reduced to the ferrous state by the addition of hydroxylamine hydrochloride. Ferrous iron is chelated with 1,10-phenanthroline to form orange-red complex . Colour intensity is proportional to iron concentration. Absorbance can be measured spectrophotometrically at 510 nm . For cell lengths of 1 cm, Beer’s law is obeyed in iron solution containing 0.1-5 mg/l. The most colour development occurs between pH 2.9-3.5 .
Reagents required Hydrochloric acid, HCl concentrated Hydroxylamine hydrochloride, NH 2 OH.HCl Ammonium acetate buffer solution Ammonium acetate, NH 4 C 2 H 3 O 2 Concentrated (glacial) acetic acid Phenanthroline solution 1,10- Phenanthroline monohydrate, C 12 H 8 N 2 H 2 O concentrated HCl Stock iron solution- Ferrous Ammonium Sulphate salt conc. H 2 SO 4 Fe(NH 4 ) 2 (SO 4 ) 2 6H 2 O Potassium permanganate (KMnO 4 ) Standard solutions- prepare daily
Procedure Mix the sample thoroughly & measure out a volume solution containing not more than 0.5 mg of iron into a 125 ml flask. If necessary dilute to 50 ml & add 2ml of conc. HCl & 1 ml of hydroxylamine hydrochloride solution Boil the solution until the volume is reduced to 10-20 ml and cool at room tempt. Transfer to a 50 ml or 100 ml volumetric flask , add 10 ml of ammonium acetate buffer solution & 2 ml of Phenanthroline solution and dilute to the mark with distilled water, mix thoroughly and set aside for 10-15 minutes for full colour development. Measure the colour intensity spectrometrically at 510 nm.
Methods for estimating the physico-chemical parameters ...
Parameters Methods /Instruments pH Electronic pH meter Total dissolved solid(TDS) TDS/Conductivity meter Conductivity TDS/Conductivity meter Total hardness(TH) IS-10500-91 Ca, Mg, chloride Atomic absorption spectrophotometer Total alkalinity Titration Dissolved oxygen(DO) Titration Turbidity Turbidity meter
Finding the Water Quality Index using the concept of “Information Entropy”...
Formulas used for calculating the Water Quality Index by “ INFORMATION ENTROPY CONCEPT ”...
Suppose there are m water samples taken to evaluate the water quality ( i =1,2,…,m). Each sample has ‘n’ evaluated parameters (j = 1, 2,…,n). According to real data, eigen value matrix X can be constructed. X = For the efficiency type, the construction function of normalization, y =
the ratio of index value of the j index and in i sample is given by eqn. Pij = yij / The information entropy is expressed by the formula below equation ej = Then the entropy weight wj can be calculated as wj =
Next step for calculating WQI is to assign a quality rating scale j q for each parameter. The qj is calculated by the following formula qj = Where C j is the concentration of the physicochemical parameters in each sample in mg/L, S j is the standard for each of the parameter in mg/L according to IS 1050091 water quality. The WQI of the sample of water is calculated by the following formula : WQI =
Assessment of water quality index and its ranking...
Classification standards of surface water quality according to WQI Rank Water Quality WQI RANK WATER QUALITY <50 1 Excellent water quality 50 - 100 2 Good water quality 100 - 150 3 Medium water quality 150-200 4 Poor water quality >200 5 Extremely poor water quality
Fe content present in samples...
SAMPLE AREA Fe Content (mg/l) Sample 1 Kamarpukur 20.25 Sample 2 M.B.B. College lake 13.4 Sample 3 Golbazar 22.1 Sample 4 Bodhjung dighi 15.25 Sample 5 Ginger Hotel Surrounding 11.7 Sample 6 Fishery college 14.75 Sample 7 ICFAI college surrounding 13.65 Sample 8 Airport 11.25 Sample 9 T.I.T. Narshinghgarh 12.35 Sample 10 Durga chowmuhani 24.85 Sample 11 Melarmath 10.45 Sample 12 Howrah river ( Battala ) 26.55
SAMPLE AREA Fe Content(mg/l) Sample 13 Arundhuti nagar 21.7 Sample 14 Badarghat Railway station 16.65 Sample 15 Khayerpur 12 Sample 16 Bodhjung Nagar 9.05 Sample 17 Ranirbazar 11.5 Sample 18 Khumlung Park 14.05 Sample 19 Champaknagar 15.7 Sample 20 Laxmi Narayan Bari extension 14.7 Sample 21 Mandai TSR camp 14.1 Sample 22 Rajbari 11.9 Sample 23 Howrah River (Kalyani) 16.9
Methods for removal of iron...
. Water Softener Aeration Oxidizing Filter Chemical Oxidation
CONCLUSION Hence from the above observations we found that the Howrah river has the most polluted water having the WATER QUALITY INDEX of 1227.727 & has the highest Fe content of 26.55 mg/l which is a matter of serious concern since inhabitants are totally dependent on that water .
Thank you... Samadrita Lodh Biprojit Roy Shalini Singh Praveen Kumar