GLOSSARY Alloy Amorphous Ceramic Cross linking Crystalline Dislocation Intermetallic compound Metal metallic bond Modulus of elasticity Polymer Stress raiser Water absorption 4
BASIC CLASSIFICATION 5 A tree diagram classifying the three basic materials.
6 Predicted strength Actual strength 1 million to 3 million pounds per square inch (psi) or about 7 to 21 GPa . Actual strengths of most materials are ten to 100 times lower.
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CERAMICS 8
9 The groove or other irregularity is called a stress raiser
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Clinical applications of ceramics 11 must not be subjected to large tensile stresses
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METALS 13
14 In a ductile material, something happens before the theoretical strength of the material is reached at the tip of the stress raiser
Mechanism of ductile behavior 15
16 This ripple in the lattice structure is called a dislocation , and it is responsible for the ductile behavior of metals.
Clinical applications of metals This ductility allows the margins of castings to be burnished, orthodontic wires to be bent, and partial denture clasps to be adjusted. 19
POLYMERS 20
Modulus of elasticity 21
Thermal expansion 22 When strong bonds are present between atoms, the atoms vibrate over a small amplitude Eg. Ceramics and Metals When weak bonds are present, the atoms vibrate over a large amplitude. Eg. Polymers
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Compensates for 0.5% processing shrinkage that occurs during the fabrication of heat-cured denture bases Water absorption Because of the weak secondary bonds in polymer materials, water molecules are able to penetrate between the polymer chains in a process called water absorption . 24 Water is responsible for the hydrolytic degradation of polymers break down more quickly or to become stained or malodorous.
Effect of cross-linking A way to improve weak bonds between polymer chains would be to link chains together with primary chemical bonds. This method, called cross-linking. Improve strength, resistance to water absorption, abrasion resistance, and other properties of polymers. 25
26 Alloy Amorphous Cross linking Crystalline Dislocation Intermetallic compound metallic bond Modulus of elasticity Stress raiser Water absorption
SUMMARY 27 A comparison of the properties of metals, ceramics, and polymers Metals Ceramics Polymers Properties Alloys Intermetallic compounds Inorganic salts Crystalline Glasses Rigid Rubbers Hardness Medium to hard Hard Medium Hard Hard Soft Very soft Strength Medium to high Medium Medium High High Low Low Toughness High Low Low Most low, some high Low Low Medium Elastic modulus High High High High High Low Very low Electrical conductivity High High Low Low Low Low Low Thermal conductivity High High Low Low Low Low Low Thermal expansion Low Low Low Low Low High High Density High High Medium Medium Medium Low Low Translucency None None Medium High High High Low Examples Gold-copper Amalgam phases Gypsum, zinc phosphate SiO 2 , Al 2 O 3 Dental porcelain Poly (methyl methacrylate) (PMMA) Impression materials
REFERENCE Dental Materials and Their Selection - 3rd Ed. (2002) by William J. O'Brien 28