Modern Engineering materials for engineers.ppt

PugazhVadivu 60 views 70 slides Apr 24, 2024
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About This Presentation

education


Slide Content

Unit –V
Modern Engineering Materials

Categories
MetallicGlasses
Shapememoryalloys
Nanomaterials
Biomaterials

Properties of Modern materials
Large optical nonlinearities
Optoelectronic property
High sensitivity to light
Large thermal and electrical conductivities
Good mechanical strength
Toughness
Ductility
lightness

Applications of Modern materials
Electronics
Photonics
Photoelasticity
Fibreoptics
Laser technology
Supersonic airplanes
Magnetic alloys for computer discs
Special ceramic for the heat shield of space shuttle

Properties of Metals
Crystalline in nature
ductile (strong in nature)
Non Transparent
Good conductors
Malleable

Properties of Glasses
Amorphous in nature
Brittle (weak)
Transparent
Bad conductors
Non-Malleable

Properties of Metallic glasses
Properties
of Metals
Properties
of Glass
Properties
of metallic
glass

Definition
Metallicglassesarenewtypeofmaterials
whichpossessboththepropertiesofmetalsand
glasses.

Properties of Metallic glasses
They have high strength
Good magnetic properties
High corrosion resistance
It will have both the properties of metals and
glasses

Glass transition temperature

Preparation of Metallic glasses
Melt spinning system (Quenching)
Twin roller system
Melt extraction system
Sputtering

Melt Spinning technique
(Quenching)

Types of Metallic glasses
Metal-metalloid glasses
Metals (Fe, Co, Ni) –Metalloid (Ge, Si, B, C)
Metal-metal glasses
Metal (Ni, Mg, Cu) –Metal (Nb, Zn, Zr)

Properties of Metallic glasses
Structural properties
Theydonothaveanycrystaldefectsand
dislocation
Metallicglasseshavetetrahedralclose
packingstructure

Properties of Metallic glasses
Mechanical properties
Theyhavehighstrength
Theyhavehighelasticity
Highlyductile

Properties of Metallic glasses
Electrical properties
Electricalresistivityishigh
Eddycurrentlossisverysmall
Thetemperaturecoefficientiszero

Properties of Metallic glasses
Magnetic properties
Ithasbothsoftandhardmagneticproperties
Theyexhibithighsaturationmagnetization
Theyhavelesscorelosses
Itexhibitsnarrowhysteresisloop

Properties of Metallic glasses
Chemical properties
Highlyresistanttocorrosion
Highlyreactiveandstable
Theycanactasacatalyst.Theamorphous
stateismoreactivethanthecrystallinestate
fromthecatalyticpointofview

Applications of Metallic glasses
Core transformers
Pressure vessels
very strong springs
tape recorders
computer memories
nuclear reactors
Surgical clips
Marine cables

In transformers

In Nuclear reactors

In springs

In computer memories

In marine cables

Modern materials
(Shape memory alloys)

Shape memory alloys
Shape–structure
Memory–recollectthepast
Alloys–collectionoftwoormore
elements

Shape memory alloys
Definition
Shapememoryalloysarethealloyswhich
changesitsshapefromoriginalshapetonew
shapewhileheatingorcoolingagainthematerial
willreturnbacktoitsoriginalshape.

Transformation temperature
Definition
Transformationtemperatureisthe
temperatureatwhichshapememoryalloys
changesfromnewshapetoitsoriginalshape.

Structures of SMA
SMA
Martensite
Twinned
martensite
Deformed
martensite
Austenite

S.noMartensite Austenite
I Martensiteis softby
nature
Austenite is hardby
nature
II It can be easily
deformable from one
shape toanother
shape
It is not so easy to
deform
IIIMartensiteexist only
at low temperature
Austenite exist onlyat
high temperature
IV It belongsto
monoclinic in
structure
It belongs tocubic in
structure

Structures of SMA

Processing of SMA

Macroscopic view of SMA

Microscopic view of SMA

Characteristics of SMA -pseudoelasticity

Characteristics of SMA -Hysteresis

Types of SMA
SMA
One way SMA
Two way SMA

Properties of SMA
Ithashighshapememorystrain
Thedensityishigh
Itismoreflexible
Ithashighmeltingpoint
Ithashighthermalstability
Ithashighcorrosionresistance

SMA in Eye glass frames

SMA in toys

SMA in helicopter blades

SMA in blood clot filter

SMA in coffee maker

SMA in teeth

Advantages of SMA
Very compact in nature
It is safe and smart
They are more flexible
They are non-corrosive

Disadvantages of SMA
Cost is high
Efficiency is low
Transformation occurs over range of
temperature

Biomaterials
Anymaterialswhichareincontactwithtissues,
cellsandfluidsoflivingbodyisknownas
biomaterials.

Classification of Biomaterials
Metalsandalloysofbiomaterials
Polymersbiomaterials
Ceramicsbiomaterials
Biopolymers

Application of Biomaterials
Metalsandalloysofbiomaterials
i)stainlesssteel–tomakebonescrews
ii)Ti-Al-Valloy–usedinimplantdevices
iii)Co-Cr-Mo–tomakestem

Application of Biomaterials
Polymerbiomaterials
i)Polyethylene–jointreplacement
ii)methylmethacrylate–bonecements
iii)Porouspolysulfone–orthopaedicimplants
iv)highdensitypolyethylene–dentalimplants

Application of Biomaterials
Biopolymers
i)Proteins
ii)polysaccrides
iii)nucleicacids
During the
growth of all
living
organisms

Bone screws

Bone cements

Dental implants

PMMA
Transparentthermoplastic,oftenusedasalight
weightshatterresistantalternativetoglass.
Syntheticpolymer

Properties of PMMA
Itisstrongandlightweightmaterial
Densityis1.17to1.20g/cm
Goodimpactstrengthhigherthanbothglassandpolystyrene
Transmitsupto92%ofvisiblelight
Filtersultravioletlightatwavelengthsbelow300nm.
Poorresistance
Ithasmaximumwaterabsorptionratioof0.3to0.4%

Uses -PMMA
Lensesforglasses
Instrumentclustersforvehicles
Shatterresistantpanelsforbuildingwindows,skylights,bulletproof
securitybarriers,furnitureandmanyotherapplications
Coatingpolymers

Medical applications -PMMA
Inorthopedicsurgery,PMMAbonecementisusedtoaffiximplants
andtoremodellostbone.
DenturesareoftenmadeofPMMA,canbecolormatchedtothe
patient’steethandgumtissue.
Incosmeticsurgery,tinyPMMAmicrospheressuspendedinsome
biologicalfluidareinjectedtoreducewrinklesorscarspermanently

Technical applications -PMMA
PMMAisusedinlaseddiscopticalmedia
ItisusedaslightguideforthebacklightsinTFT-LCDs
Plasticopticalfiberusedforshortdistancecommunication
Usedasmatrixinlaserdye
Usedtostopbetaradiationemittedfromradioisotopes
PMMAareusedasdosimeterdevicesduringthegammaradiationprocess.
PMMAusedasahybridrocketfuel.

Hydroxyapatite
(Ca
5(PO
4)
3OH) or
Ca
10(PO
4)
6(OH)
2
OHcanbereplacedbyfluoride,chloride
producingfluorapatiteorchrolorapatite.
Hexagonalcrystalsystem

Medical applications -hydroxyapatite
Canbefoundinteethandboneswithinthehumanbody.
Coreskeletoncanbetransformedintohydroxyapatitebyhigh
temperatures
Itburnsawayanyorganicmoleculessuchproteins,preventingan
immuneresponseandrejection
Usedforlocaldrugdeliveryinbone
Hipreplacements,dentalimplantsandboneconductionimplants

Ceramic materials -
compounds of metallic and non-metallic elements
Traditional ceramics –clay products (bricks, tiles, porcelain)
china ceramics –firing clay products

Introduction -Ceramics
Advancedceramicsaredevelopedforuseastools,rockets,missile
applications
Theseceramicspossesshighyoung’smodulus,highstrength,high
fracturetoughness
Furnaces,ovensasinsulators,crockeries,etc.,
Inartificiallimbsandteeth
Assuperconductingmaterials
Insonardevices,memorycoresoftransformer

Types -Ceramics
Naturalceramics–traditionalceramics
SiC,Al2O3,Si3N4andmanyvarietiesofoxides,carbides,nitrides,boridesand
morecomplexceramics
Functionalceramics
Abrasives–Alumina,Carborundum
Pureoxideceramics–MgO,Al2O3,SiO2,Zirconia
Fireclayproducts–bricks,tiles,porcelain
Inorganicglasses–windowglass,leadglass
Cementingmaterials–lime,portlandcements
Rocks–Granites,sandstones,etc
Minerals–calcite,quartz

Applications -Ceramics
Whitewares(olderceramics)
Tiles,sanitarywares,lowandhighvoltageinsulators,crucibles,jarandburners
Newerceramics
Borides,carbides,nitrides,singleoxides,silicates,metalloidandintermetallic
compounds
AdvancedCeramics
Internalcombustionengines,turbines
Electronicpackaging
Cuttingtools
Energyconversion

Advantages -Ceramics
Ceramicsarehard,stronganddense
Highresistancetothereactionofchemicalsandtotheweathering
Highcompressionstrength
Highfusionpoints
Excellentdielectricproperties
Goodthermalinsulators
Resistanttohightemperaturecreep
Cheaplyavailable
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