Course Contents Week Topics Wise Course Contents 6 The Third Law of Thermodynamics: Statement of the Third Law, Corollaries to the Third law, Absolute Entropies, Molecular interpretation. 7 Enthalpy and Gibbs Energy Changes : Standard states, heat of formation, heat of reaction, adiabatic flame temperature, Gibb’s energy changes. 8 Behavior of Gases : Ideal gases, Real gases and Fugacity. Classical and Statistical Applications 9 Reaction Equilibria : Equilibrium constants, Criteria of reaction equilibrium, Effect of temperature and pressure on equilibrium constant. 10 Le Chatelier’s Principle, alternative standard states, interaction coefficients, Ellingham diagram, Absorption equilibria. 11 Ideal gases, Gibbs energy of mixing, Entropy of mixing and Enthalpy of mixing, Real gases and fugacity, compressibility factor, vander Walls equation, Thermodynamic functions of Mixing, fugacity for condensed phase (liquid and solid), activity, molar Gibbs energy. 12 Activity coefficient, Partial properties, partial molar volume. Reaction Equilibria, Equilibrium constant, Effect of temperature on Equilibrium constant, Van’t Hoff equation, 5