Topics what is hardness of water? reaction of soap with water hard water vs soft water –comparison types of water hardness & removal method determination of hardness Hardness units & conversion table
What is hardness of water? As per chemistry, the amount of calcium & magnesium ions present in water. In other words hardness of water means the lather producing capacity of water. Hard water contains more calcium & magnesium ions & produces less lather with soap Soft water contains less calcium & magnesium ions & produces more lather with soap
Reaction of soap with water Soap contains long chain fatty acids of sodium salt.when soap react with water calcium & magnesium ions present in water is converted to corresponding calcium & magnesium salts & it is precipitate as scum. This scum is sticks on the surface to be cleaned so that cleaning capacity of soap is reduced
Hard water vs soft water Hard water More calcium & magnesium ions are present Produces less lather with soap Total hardness value is >60ppm as caco3 softwater Less calcium & magnesium ions are present Produces more lather with soap Total hardness value is < 60ppm as caco3
Carbonate hardness or temporary hardness Hardness present in water is due to carbonate(CO3) & Bicarbonate(HCO3) ions is called Carbonate or Temporary Hardness of water It is called temporary hardness because it is removed when we boil the water
Non-carbonate hardness or permanent hardness Hardness present in water is due to Chloride(CI) &Sulfate(SO 4) ions is called Non-Carbonate or Permanent Hardness of water It is called Permanent Hardness of water It is called permanent hardness because it is not removed when we boil the water It is removed by softening or demineralization process
Water hardness analysis overview
Determination of total hardness
Determination of calcium hardness
Determination of magnesium hardness Magnesiunm hardness is determined by subtracting calcium hardness value from total hardness calculation: magnesium hardness=total hardness-calcium hardness ppm as caco3